Citation: An-qi Tang, Jing-yu Lu, Wei-lin Feng, Pei-bin Zhang, Li-ping Zhu. Performance Control of Polydopamine Compsite Nanofiltration Membranes Fabricated by Interfacial Crosslinking[J]. Acta Polymerica Sinica, ;2018, 0(12): 1524-1531. doi: 10.11777/j.issn1000-3304.2018.18109 shu

Performance Control of Polydopamine Compsite Nanofiltration Membranes Fabricated by Interfacial Crosslinking

Ministry of Education Key Laboratory of Macromolecule Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027

Corresponding author: Li-ping Zhu, lpzhu@zju.edu.cn
Received Date: 20 April 2018
Revised Date: 22 May 2018
Available Online: 4 July 2018

Composite nanofiltration membranes with tunable permeation and separation properties were prepared by interfacial crosslinking reaction between polydopamine (PDA) and trimesoyl chloride (TMC). Dopamine was first allowed to self-polymerize into oligomers or nanoaggregates in its aqueous solution at room temperature. As the size of PDA aggregates was readily modulated by measuring the pH of water phase, the separation precision of composite membranes could then be controlled. Ultraviolet spectra and dynamic light scattering ensured that the size of PDA nanoaggregates varied with pH values of aqueous solution. Attenuated total reflectance Fourier transform infrared spectroscopy, scanning electronic microscopy and contact angle measurement were employed to characterize the surface chemistry and morphology of the obtained composite membranes. It was found that, when the pH value of aqeuous phase increased from 6 to 12, the separation scale of composite membranes became progressively smaller and reached its highest selectivity at pH = 12, with rejection of Na₂SO₄ and sunset yellow being 90% and 97% respectively, flux reaching 64 L m⁻² h⁻¹ under 0.4 MPa. Increasing pH value to 13 caused a decline of separation properties, probably owing to a decomposition of PDA aggregates under strongly alkaline condition. Compared with PDA deposition method, which had been reported before, this work has considerably reduced the deposition time and produced a denser top layer, improving both preparation and separation efficiencies. By adjusting the size of the reactants before interfacial crosslinking, this study facilitated the regulation of separation precision of nanofiltration membranes.
- Polydopamine,
- Interfacial crosslinking,
- Nanofiltration,
- Separation precision
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