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Citation: Xing Wu, Chen Jiang, Na Zhang, Fang Chen, Wei Bai, Ru-ke Bai. Preparation of Few-layered Organic-silica Hybrid Nanomaterials by Two-dimensional Self-assembly and Polymerization[J]. Acta Polymerica Sinica, ;2018, 0(12): 1507-1513. doi: 10.11777/j.issn1000-3304.2018.18104 shu

Preparation of Few-layered Organic-silica Hybrid Nanomaterials by Two-dimensional Self-assembly and Polymerization

  • 1.

    Key Laboratory of Soft Matter Chemistry, Chinese Academy of Sciences; Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026

  • 2.

    Institute of Physical Science and Information Technology，Anhui University, Hefei 230601

  • It is still a challenge to prepare single-layered or few-layered organic-silica hybrid nanomaterials now. In this study, we designed and synthesized an amphiphilic organosilane (PABI) with phenyl urea and carboxyl groups, and investigated its two-dimensional self-assembly and polymerization. The spontaneous formation of few-layered organic-silica hybrid nanomaterials was driven by synergetic association of the hydrophobic interactions, π-π stacking interactions, hydrogen-bond interactions, electrostatic repulsion and hydrolytic condensation of the precursor under the appropriate conditions. The results indicated that the two-dimensional self-assembly and the polymerization were related to the experimental conditions, such as the medium, the type and the content of the base. The structure of the hybrid nanomaterials was demonstrated by nuclear magnetic resonance (1H-NMR), Fourier transform infrared spectroscopy (FTIR) and 29Si cross-polarization magic-angle spinning nuclear magnetic resonance (CP-MAS 29Si-NMR). The morphology of the hybrid nanomaterials was confirmed by electron microscopy. Two or three layered organic-silica hybrid nanomaterials were obtained by two-dimensional self-assembly and polymerization of PABI in water when using 1,1,3,3-tetramethylguanidine (TMG) as a base under suitable condition (mole ratio of TMG to PABI was 1.1:1 or 1.5:1). The laminated sheet of the materials, with lateral size ranging from several hundred nanometers to several micrometers and thickness of 6 – 9 nm, was demonstrated by transmission electron microscopy (TEM) and atomic force microscopy (AFM). However, when the content of TMG (mole ratio of TMG to PABI was 2:1) was too high, irregular aggregates were formed. In addition, irregular hybrid materials were obtained when organic solvents, such as DMF, DMSO, THF and MeOH, were respectively added to water. Moreover, when trimethylamine (TEA) and sodium hydroxide (NaOH) were used as bases, thick laminated sheets were obtained, and the result was consistent with X-ray diffraction spectrogram (XRD). These results are of great significance for preparation of few-layered or single-layered organic-silica hybrid nanomaterials.
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