Citation: Yan Liu, Yang Gao, Xin Zhao, Chao Shan, Xiao-lin Zhang, Bing-cai Pan. A Gel Resin-supported Nano-hydrated Iron Oxide for Arsenate Sorption from Water[J]. Acta Polymerica Sinica, ;2018, 0(7): 939-948. doi: 10.11777/j.issn1000-3304.2018.18056 shu

A Gel Resin-supported Nano-hydrated Iron Oxide for Arsenate Sorption from Water

State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023

Corresponding author: Xiao-lin Zhang, xlzhang@nju.edu.cn
Received Date: 10 February 2018
Revised Date: 26 March 2018
Available Online: 7 May 2018

Nano-scale hydrated ferric oxide (HFO) of high specific surface area and reactivity exhibits specific affinity toward arsenate owing to the abundant surface hydroxyl groups. Nevertheless, the ultrafine particle of nano-HFO tend to agglomerate and thereafter significantly limits its large-scale application in water treatment due to the excessive hydraulic pressure drop and difficult operation from the reaction systems. In comparison with macroporous ion exchangers, gel-type ones are more cost effective, though their utilization as hosts to support nanoparticles is intensively compromised by relatively poor pore structure, high swelling rate and weak mechanical strength. In this study we prepared a nanocomposite adsorbent HFO-201 × 4 via ion exchange/in situ deposition method by using a gel resin-201 × 4 as the host of nano-HFO. The main objective of this study is to compare the structural features, physical and chemical properties of the nanocomposite to a macroporous resin-based nanocomposite HFO-201, and to evaluate their different adsorption property toward As(V). The results indicate that nano-HFO immobilized in HFO-201 × 4 was acicular, quite different from the spherical particles in HFO-201. Other structure properties of both composites, such as crystal form, pore structure, mechanical strength and swelling ratio, are quite similar. The maximum adsorption capacity of HFO-201 × 4 was slightly higher than that of HFO-201, while HFO-201 × 4 exhibited superior adsorption toward trace As(V) over HFO-201 in terms of adsorption capacity and kinetics, possibly arising from higher site density of HFO-201 × 4 (1.47 mmol/g) than HFO-201 (0.88 mmol/g). From the breakthrough curves of two separate fixed beds packed with both composites, the effective working capacity of HFO-201 × 4 was nearly twice of HFO-201. The exhausted HFO-201 × 4 could be efficiently regenerated for cyclic runs. This study demonstrates that gel-type anion exchange resins could serve as promising hosts for fabrication of similar nanocomposite for water decontamination.
- Gel anion exchanger,
- Hydrated ferric oxide,
- Arsenate,
- Nanocomposite,
- Selective adsorption
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