Citation: Jia-wei Zhang, Zhi-yuan Ma, Chuan-zhuang Zhao, Jin-ying Yuan, Xiao-xia Zhu. Porphyrin-based Derivatives and Polymeric Materials[J]. Acta Polymerica Sinica, ;2018, 0(7): 864-877. doi: 10.11777/j.issn1000-3304.2018.18023 shu

Porphyrin-based Derivatives and Polymeric Materials

1.
Ningbo Institute of Material Technology and Engineering, Chinese Academia of Sciences, Ningbo 315201
2.
Department of Chemistry, Université de Montréal, Montreal, QC, H3C3J7, Canada
3.
College of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211
4.
Department of Chemistry, Tsinghua University, Beijing 100084

Corresponding author: Jia-wei Zhang, zhangjiawei@nimte.ac.cn Xiao-xia Zhu, julian.zhu@umontreal.ca
Received Date: 21 January 2018
Revised Date: 16 March 2018
Available Online: 3 May 2018

Porphyrins are naturally occurring macrocyclic compounds containing four pyrroles connected through four methine carbons at their α-positions. Porphyrins and their derivatives are widely found in biological systems and they engage in many essential processes that sustain living systems, such as enzyme catalysis, oxygen transportation and photosynthesis. The unique biological functions and physiochemical properties of porphyrin and its derivatives have made them interesting candidates in the preparation of functional materials for various applications. The recent progress on the synthesis and application of porphyrin derivatives and particularly the related macromolecular and supramolecular structures, is summarized in this review. Following a brief introduction on porphyrin and its derivatives in nature and on the binding and adsorption studies on porphyrin-related bile pigments such as bilirubin, the strategies for the preparation of porphyrin-based polymers are reviewed, including the covalent polymerization and supramolecular self-assembly of linear polymers based on porphyrin, as well as two- and three-dimensional porphyrin assemblies and frameworks. The applications of porphyrin-based polymers and supramolecular-structures are also covered, which include: artificial enzymes, photo-dynamic therapy, chemical sensors, light-energy harvesting and medical imaging. These versatile functions are a synergetic result of porphyrin and its conjunct polymers: the porphyrin has unique photo-physical properties, and the polymers manifested porphyrin moieties stable and switchable chemical environment. Despite the progress having been made, the great potential as functional materials of porphyrin and its derivatives has not been fully exploited. In the future, tailoring the molecular topology of porphyrins-based polymer is believed to be an effective strategy of obtaining functional materials with controlled self-assembly structure. Constructing higher-ordered structure with supramolecular self-assembled porphyrin derivatives is a promising field, because the hierarchical structure would bring more interesting functions that cannot be realized with single molecules. Combination of porphyrin with other biomolecules is worthwhile to pay attention to. With covalent or supramolecular conjunction of porphyrin and biomolecules, functional materials with novel properties that even do not exist in nature might be created.
- Porphyrin,
- Porphyrin derivatives,
- Functional polymers
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