Citation: Ruey-Chorng Lin, Shiao-Wei Kuo. Hydrogen Bonding Interactions Mediated Self-assembly Structures of Multicomponent Block Copolymer Mixtures[J]. Acta Polymerica Sinica, ;2018, 0(8): 1016-1032. doi: 10.11777/j.issn1000-3304.2018.18020 shu

Hydrogen Bonding Interactions Mediated Self-assembly Structures of Multicomponent Block Copolymer Mixtures

Ruey-Chorng Lin ,
Shiao-Wei Kuo ^,

Department of Materials and Optoelectronic Science, Center for Functional Polymers and Supramolecular Materials, Taiwan Sun Yat-Sen University, Kaohsiung 80424

Corresponding author: Shiao-Wei Kuo, kuosw@faculty.nsysu.edu.tw
Received Date: 16 January 2018
Revised Date: 23 February 2018
Available Online: 1 March 2018

Self-assembly from block copolymers is a bottom-up process, a relatively inexpensive and simple approach for the preparation of large-scale nano-patterns. This self-assembly from diblock copolymers is driven by the combination of repulsive and attractive interactions due to the covalent bond linkage. The intrinsic immiscibility or incompatibility among the A or B block segments possesses the repulsive force and then confines into nanoscaled domain through the microphase separation because of the attractive force from the covalent bond linkage of A and B block segments. In general, these diblock copolymers can form different well-defined nanostructures in the bulk state including alternative lamellae, bicontinuous double gyroid, hexagonally packed cylinder, and body-centered cubic (BCC) structures, depending on the relative volume fractions of the block copolymer segments, interaction parameters (χ), and degrees of polymerization (N). However, the preparation of block copolymers with controlled volume fraction would be complicated and time-consuming; thus the diblock copolymers (A-b-B) blending with their homopolymer or low-molecular-weight compound would be an easier method for preparing different self-assembled nanostructures. Therefore, self-assembly nanostructures of block copolymer mixtures through mediated hydrogen bonding interactions have attracted much interest in polymer science because of their potential applications in photonic, electronic and biomedical fields, which could offer the unique possibility to create new functional polymeric materials with tunable and responsive behaviors. In this review article, we describe the self-assembly nanostructure of the block copolymer mixtures including block copolymer/low molecular weight compound, block copolymer/homopolymer, and block copolymer/block copolymer mixtures in bulk and solution states by mediated hydrogen bonding strength. Mediated strength of hydrogen bonding in block copolymer blending with homopolymer or block copolymer could provide order-order phase transition from typical lamellar, double gyroid, cylinder, and BCC spherical structure, even various hierarchical self-assembly structures such as three-phase lamellae, core-shell cylinder, and cylinder in lamellae structures in bulk state. Furthermore, it also possesses the different micellar structures of block copolymer mixtures such as spheres, rods, vesicles, and even large compound micelles in solution state.
- Hydrogen bonding,
- Block copolymer,
- Polymer blend,
- Self-assembly structures
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