Citation: Xi Zhang. A Tandem Polymer Solar Cell Based on Non-fullerene-acceptors Yields an Efficiency Approaching 15%[J]. Acta Polymerica Sinica, ;2018, (2): 129-131. doi: 10.11777/j.issn1000-3304.2018.18019 shu

A Tandem Polymer Solar Cell Based on Non-fullerene-acceptors Yields an Efficiency Approaching 15%

Xi Zhang ^,

Department of Chemistry, Tsinghua University, Beijing 100084

Corresponding author: Xi Zhang, xi@mail.tsinghua.edu.cn
Received Date: 15 January 2018

In polymer solar cells (PSCs), the blends of polymer donors and fullerene-based acceptors have been predominantly used for over two decades. This situation has been challenged owing to the rapid progress in non-fullerene (NF) PSCs. Up to now, the power conversion efficiencies (PCEs) of single-junction NF-PSCs have reached over 13% and surpassed that of the fullerene-based counterparts. Tandem double-junction solar cells are intrinsically more potential for enhancing PCE but bring more challenges for material design and device fabrication. Recently, in order to optimize light response spectrum of tandem NF-PSCs and hence to promote PCE, Hou et al. modulated the photoactive layer compositions by adopting a series of polymer donors and NF-acceptors. They found that light response spectrum of the blend of J52-2F:IT-M was well complementary with that of PTB7-Th:IEICO-4F, and as a result, the tandem NF-PSC based on these two blends could offer a broad and strong light response spectra covering 400-1000 nm. After optimizing device fabrication process, they realized a PCE of 14.9%, which is the top value in the field. Herein, by making a brief overview of NF-PSCs and highlighting this outstanding result, this short essay not only aims to attract attention to the rapid progress made by Chinese academic community but also delivers the expectation for the bright future of NF-PSCs.
- Polymer solar cells,
- Non-fullerene polymer solar cells,
- Tandem double-junction solar cells,
1. [1]
  Yu G, Gao J, Hummelen J C, Wudl F, Heeger A J. Science, 1995, 270:1789-1791 doi: 10.1126/science.270.5243.1789
2. [2]
  Lin Y, Wang J, Zhang Z G, Bai H, Li Y, Zhu D, Zhan X. Adv Mater 2015, 27:1170-1174 doi: 10.1002/adma.201404317
3. [3]
  Zhao W, Qian D, Zhang S, Li S, Inganas O, Gao F, Hou J. Adv Mater, 2016, 28:4734-4739 doi: 10.1002/adma.v28.23
4. [4]
  Zhao W, Li S, Yao H, Zhang S, Zhang Y, Yang B, Hou J. J Am Chem Soc, 2017, 139:7148-7151 doi: 10.1021/jacs.7b02677
5. [5]
  Bin H, Yang Y, Zhang Z G, Ye L, Ghasemi M, Chen S, Zhang Y, Zhang C, Sun C, Xue L, Yang C, Ade H, Li Y. J Am Chem Soc, 2017, 139:5085-5094 doi: 10.1021/jacs.6b12826
6. [6]
  Zhang Z G, Yang Y, Yao J, Xue L, Chen S, Li X, Morrison W, Yang C, Li Y. Angew Chem Int Ed, 2017, 56:13503-13507
7. [7]
  Cui Y, Yao H, Gao B, Qin Y, Zhang S, Yang B, He C, Xu B, Hou J. J Am Chem Soc, 2017, 139:7302-7309 doi: 10.1021/jacs.7b01493
8. [8]
  Cui Yong, Yao Huifeng, Yang Chenyi, Zhang Shaoqing, Hou Jianhui. Acta Polymerica Sinica, 2018, (2):223-230
1. [1]
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2. [2]
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3. [3]
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4. [4]
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5. [5]
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6. [6]
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7. [7]
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8. [8]
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9. [9]
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13. [13]
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14. [14]
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15. [15]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . 超高比能电池高锰富锂层状氧化物正极材料面临的挑战与解决策略. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-. doi: 10.1016/j.actphy.2025.100085
16. [16]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
17. [17]
  Wenqi Gao , Xiaoyan Fan , Feixiang Wang , Zhuojun Fu , Jing Zhang , Enlai Hu , Peijun Gong . Exploring Nernst Equation Factors and Applications of Solid Zinc-Air Battery. University Chemistry, 2024, 39(5): 98-107. doi: 10.3866/PKU.DXHX202310026
18. [18]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
19. [19]
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20. [20]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021

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