Citation: Quan-xing Zhang, Zheng-pu Zhang, Ai-min Li, Bing-cai Pan, Xiao-lin Zhang. Advance in Ion Exchange and Adsorption Resins in China[J]. Acta Polymerica Sinica, ;2018, 0(7): 814-828. doi: 10.11777/j.issn1000-3304.2018.17317 shu

Advance in Ion Exchange and Adsorption Resins in China

1.
School of the Environment, National Engineering Research Center for Organic Pollution Control and Resource, Nanjing University, Nanjing 210023
2.
Key Laboratory of Functional Polymer Materials of Ministry of Education, Institute of Polymer Chemistry, Nankai University, Tianjin 300071

Corresponding author: Quan-xing Zhang, zhqx@nju.edu.cn
Received Date: 22 November 2017
Revised Date: 30 November 2017
Available Online: 1 March 2018

Since 1949, China has been witnessing a rapid development in ion exchange and adsorption technology. Up to date, at least five generations of polymeric resins have been developed, including gel-type resin, macroporous resin, hyper-cross-linked resin, bifunctional resin and resin-based composite adsorbent. These resin-based materials have been widely utilized in various industries, including military defense, medical and health, fine chemicals, hydrometallurgy, environmental protection, making considerable contributions to the modernization of China. In brief, gel-type resin, characterized by non-porous nature, was first developed for uranium extraction and later expanded to other fields such as water softening. Due to abundant porous structure, macroporous resin exhibited faster ion exchange rate and higher mechanical strength over the gel-type one. A variety of macroporous adsorption resins were developed and widely utilized in separation and/or purification in the industries of food, chemicals, rare elements, drugs, toxins, and environmental remediation. Hyper-cross-linked resin was mainly prepared via Friedel-Crafts reaction, possessing ultra-high specific surface area (usually high than 800 m²/g) and abundant microporous structure. Hyper-cross-linked resins have been successfully applied for hemoperfusion purpose, representing one of the most promising adsorbents for organic pollutants in chemical industry effluents. Bifunctional resins were designed for adsorptive removal of highly water-soluble organic pollutants from industrial effluents, because they could offer multiple interactions with target pollutants such as π-π interaction, electrostatic attraction, hydrophobic interaction and hydrogen bonds. In the past decade, resin-based composite adsorbents, including resin-supported nanocomposite and magnetic resin, were obtained by integrating resin hosts with inorganic (nano) particles for advanced (waste) water treatment. The present review summarizes the development of ion exchange and adsorption resins in China since its foundation, particularly focusing on the historic contributions of Prof. Binglin He, the father of China’s ion exchange resins, to the progress of ion exchange and adsorption technology in China. Also, it provides an outlook of the perspective of ion exchange and adsorption resins in emerging applications.
- Ion exchange and adsorption resin,
- Gel-type resin,
- Macroporous resin,
- Hyper-cross-linked resin,
- Bifunctional resin,
- Resin-based composite adsorbent
1. [1]
  Zhang Quanxing(张全兴). Modern Ion Exchange and Adsorption Technology Preface(现代离子交换与吸附技术序). Beijing(北京): Tsinghua University Press(清华大学). 2015
2. [2]
  Xu Jiami(徐家鼏). Chemical World(化学世界), 1954, 9(8):339 – 341
3. [3]
  Xu Jiami(徐家鼏).Chin Pharm Bull(药学通报), 1954, 2(10): 420-422
4. [4]
  Xu Jiami(徐家鼏). Chemical World(化学世界), 1955, 10(4): 158-161
5. [5]
  He Binglin(何炳林), Qian Tingbao(钱庭宝). Polymer Communications(高分子通讯), 1957, 1(4): 195-209
6. [6]
  He Binglin(何炳林). Chemistry(化学通报), 1957, (5): 4-12
7. [7]
  Ion Exchange Resin Research Center Liaison Station(离子交换树脂研究中心联络站). Polymer Communications(高分子通讯), 1958, 2(3): 197-200
8. [8]
  Kunin R, Myers R J. Ion Exchange Resins. New York: John Wiley & Sons, 1951
9. [9]
  Kunin R, Myers R J. Ion Exchange Resins. Translated by Zhu Xiuchang(朱秀昌). Beijing(北京): Science Press(科学出版社), 1960
10. [10]
  Rao Guoxuan(饶国宣). Chemical World(化学世界), 1981, (5): 133-135
11. [11]
  Chen Yiyong(陈义镛), Xu Chengwei(许承威). Polymer Communications(高分子通讯), 1980, 4: 254
12. [12]
  He Binglin(何炳林). Polymer Communications(高分子通讯), 1959, 3(5): 219 – 224
13. [13]
  He Binglin(何炳林), Qian Tingbao(钱庭宝). Journal of Chemistry(化学学报), 1959, 25(6): 360 – 365
14. [14]
  He Binglin(何炳林), Qian Tingbao(钱庭宝), Zhang Quanxing(张全兴), Lin Xiaoyuan(林孝元). Journal of Nankai University (Natural Science)(南开大学学报(自然科学)), 1964, 5(2): 103-118
15. [15]
  He Binglin(何炳林), Qian Tingbao(钱庭宝), Chen Weizhu(陈伟朱). Atomic Energy Science and Technology(原子能科学技术), 1964, 5: 515-522
16. [16]
  He Binglin(何炳林), Zhang Zhenpu(张政朴), Qian Tingbao(钱庭宝), Chen Hongbin(陈洪彬), Guo Xianquan(郭贤权), Shi Zuoqing(史作清), Pei Guangwen(裴广文). Polymer Communications(高分子通讯), 1982, 4: 278-283
17. [17]
  He Binglin(何炳林), Zhang Zhengpu(张政朴), Qian Tingbao(钱庭宝), Shi Zuoqing(史作清), Guo Xianquan(郭贤权), Chen Hongbin(陈洪彬). Polymer Communications(高分子通讯), 1983, (5): 351-355
18. [18]
  Zhang Quanxing(张全兴), Li Aimin(李爱民), Pan Bingcai(潘丙才). Polymer Bulletin(高分子通报), 2015, (9): 21 – 43
19. [19]
  Yan Husheng(阎虎生), Cheng Xiaohui(程晓辉), Ni Aiguo(倪爱国), He Binglin(何炳林). Weakly Acidic Cation Exchange Resin(弱酸性阳离子交换树脂). China patent, CN93105858.9. 1993-05-27
20. [20]
  Yan Husheng(阎虎生), Cheng Xiaohui(程晓辉), Ni Aiguo(倪爱国), He Binglin(何炳林). Production Technology of Weak Acidic Cation Exchange Resin(弱酸性阳离子交换树脂生产工艺). China patent, CN92114550.0. 1992-12-19
21. [21]
  Nankai University(南开大学). Synthetic Materials(合成材料), 1976, (4): 13
22. [22]
  Shenyang Institute of Chemical Engineering and Technical Information(沈阳市化工研究所技术情报窒). Shenyang Chemical Industry(沈阳化工), 1976, (6): 42-50
23. [23]
  North China Pharmaceutical Factory(华北制药厂). Pharmaceutical Industry(医药工业), 1976, (3): 28
24. [24]
  Yuan Zhi(袁直), Yang Defu(杨德富), Shen Lihua(申丽华), He Binglin(何炳林). Science Bulletin(科学通报), 1996, 41(21): 1957-195
25. [25]
  Yuan Zhi(袁直), Yang Defu(杨德富), Shen Lihua(申丽华), He Binglin(何炳林). Ion Exchange and Adsorption(离子交换与吸附), 1996, 12(1): 56-60
26. [26]
  Shi Zuoqing(史作清). Journal of Henan University (Medical Edition)(河南大学学报(医学版)), 2007, 26(1): 1-5
27. [27]
  Merrifield R B. J Am Chem Soc, 1963, 85: 2149 – 2154
28. [28]
  Chen Zhenbo(陈振波). Amino Acid Communication(氨基酸通讯), 1977, (8): 34-83
29. [29]
  Fed R. Proc., 1962, 21: 412
30. [30]
  Miertus S, Fassina G. Combinatorial Chemistry and Technology. New York: Marcel Dekker, Inc., 1999
31. [31]
  He Binglin(何炳林), Chen Weizhu(陈伟朱), Liu Keliang(刘克良), Zong Jianchao(宗建超), Li Naihong(李乃宏). Chinese Science B Series(中国科学B辑), 1985, (12): 1071-1080
32. [32]
  Jiang Ying(蒋英), Liang Xun(梁逊), Chen Weizhu(陈伟朱), He Binglin(何炳林). Journal of Chemistry(化学学报), 1987, (11): 1112-1118
33. [33]
  Ren Qisheng(任启生), Huang Wenqiang(黄文强), He Binglin(何炳林). Ion Exchange and Adsorption(离子交换与吸附), 1989, (3): 203-205
34. [34]
  Liu Keliang(刘克良), He Binglin(何炳林), Xiao Shaobo(萧绍博), Xia Qiming(夏启明), Fang Xi(方溪), Wang Zhongyi(王忠义). Chinese Science B Series(中国科学B辑), 1990, (2): 163-169
35. [35]
  He Binglin(何炳林), Zhang Quanxing(张全兴), Li Xiaobai(李效白), Shi Rongfu(施荣富), Wang Jianying(王建英). Journal of Chemistry in Colleges and Universities(高等学校化学学报), 1981, 2(3): 397-399
36. [36]
  He Binglin(何炳林), Zhang Quanxing(张全兴), Li Xiaobai(李效白), Chen Changzhi(陈长治), Shi Rongfu(施荣富), Wang Jianying(王建英). Polymer Communications(高分子通讯), 1980, (6): 328-334
37. [37]
  He Binglin(何炳林), Zhang Quanxing(张全兴), Li Xiaobai(李效白), Shi Rongfu(施荣富), Shi Zuoqing(史作清), Guo Xianquan(郭贤权), Zhu Xiaolun(朱孝伦), Wang Jianying(王建英). Polymer Communications(高分子通讯), 1986, (5): 353-359
38. [38]
  He B L, Zhang Q X, Li X B, Shi R F, Shi Z Q, Guo X Q, Zhu X L, Wang J Y. Chinese J Polym Sci, 1986, (3): 220-228
39. [39]
  Zhang Quanxing(张全兴), Shi Rongfu(施荣富), Zhu Xiaolun(朱孝伦), Cui Futong(崔福通), He Binglin(何炳林). Ion Exchange and Adsorption(离子交换与吸附), 1986, 2(1): 26-33
40. [40]
  Zhang Quanxing(张全兴), Yan Husheng(阎虎生), He Binglin(何炳林). Ion Exchange and Adsorption(离子交换与吸附), 1986, 2(3): 8-17
41. [41]
  Zhang Quanxing(张全兴), Yan Husheng(阎虎生), He Binglin(何炳林). Journal of Chemistry in Colleges and Universities(高等学校化学学报), 1987, 8(10): 946-951
42. [42]
  Yan Husheng(阎虎生), Zhang Quanxing(张全兴), He Binglin(何炳林). Ion Exchange and Adsorption(离子交换与吸附), 1988, 4(3): 167-171
43. [43]
  Zhang Quanxing(张全兴), Chen Jinlong(陈金龙), Xu Zhaoyi(许昭怡), Pan Bingcai(潘丙才), Li Aimin(李爱民), Zhang Weiming(张炜铭), Han Yongzhong(韩永忠). Polymer Bulletin(高分子通报), 2005, (4): 116-121
44. [44]
  Fei Zhenghao(费正皓), Chen Jinlong(陈金龙), Li Aimin(李爱民), Liu Fuqiang(刘福强), Zhang Quanxing(张全兴). Applied Chemistry(应用化学), 2003, 20(11): 1062-1065
45. [45]
  Zhang W M, Xu Z W, Pan B C, Lv L, Zhang Q J, Zhang Q R, Du W, Pan B J, Zhang Q X. J Colloid Interface Sci., 2007, 311 (2): 382-390 doi: 10.1016/j.jcis.2007.03.005
46. [46]
  Pan B C, Du W, Zhang W M, Zhang X, Zhang Q R, Pan B J, Lv L, Zhang Q X, Chen J L. Environ Sci Technol, 2007, 41 (14): 5057-5062 doi: 10.1021/es070134d
47. [47]
  Davankov V, Tsyurupa M. Pure Appl Chem, 1989, 11(61): 1881-1888
48. [48]
  Technical information station of Shanghai Pharmaceutical Industry Research Institute(上海医药工业研究院技术情报站). Pharmaceutical Industry(医药工业), 1975, (6): 65-66
49. [49]
  Chen C Z, Zhang Q X, Yu Y T, He B L, Qian S C, Chang H Z, Song J C. In: Proceedings of the fifth International Symposium on Hemoperfusion and Artificial Organs. China Academic Publishers.1985. 350
50. [50]
  Qian Shaocheng(钱绍诚), Song Jichang(宋继昌), Chen Changzhi(陈长治), Yang Xiaoming(杨晓明), Yu Yaoting(俞耀庭). Chinese Journal of Internal Medicine(中华内科杂志), 1985, 24(5): 296 – 298
51. [51]
  Yu Jie(于杰), Guo Xianquan(郭贤权). Ion Exchange and Adsorption(离子交换与吸附), 2013, 29(3): 262-269
52. [52]
  Yu Jie(于杰), Guo Xianquan(郭贤权). Ion Exchange and Adsorption(离子交换与吸附), 2013, 29(4): 370-376
53. [53]
  Yu Jie(于杰), Guo Xianquan(郭贤权). Ion Exchange and Adsorption(离子交换与吸附), 2013, 29(5): 468-472
54. [54]
  Zhang Quanxing(张全兴), Xu Wei(徐伟), Jing Xiang(荆和祥), Zhou Xisheng(周希圣), Cai Jianguo(蔡建国), Liu Shiyou(刘世友), He Binglin(何炳林), Xu Hulong(徐虎龙), Fan Xiaolan(范晓兰). Journal of Jiangsu Institute of Chemical Technology(江苏化工学院学报), 1989, 1(3): 74-83
55. [55]
  Zhang Quanxing(张全兴), Xu Wei(徐伟), Jing Hexiang(荆和祥), Zhou Xisheng(周希圣), Fan Zhengming(范正明), Xu Hulong(徐虎龙), Fan Xiaolan(范晓兰), Kuang Monan(匡墨南), Zhu Wei(朱伟), Li Ming(李明). Pollution Control Technology(污染防治技术), 1992, 5(3): 35-39
56. [56]
  Zhang Quanxing(张全兴), Zhou Xisheng(周希圣), Yan Wenyao(严文瑶), Zhou Qingrong(周庆荣), Zhang Dianlan(张殿兰), Tu Yaoqing(屠尧卿), Hu Jiaxian(胡家先). Jiangsu Chemical Industry(江苏化工), 1989, (1): 41-43
57. [57]
  Zhang Quanxing(张全兴), Qiu Zhaorong(裘兆蓉), Zhou Xisheng(周希圣), Yan Wenyao(严文瑶), Jing Hexiang(荆和祥), Tan Hong(谈红), Liu Jianping(刘建平), Song Changgen(宋长根), He Binglin(何炳林), Yang Hengfu(杨恒富), Xue Xinmei(薛新美). Ion Exchange and Adsorption(离子交换与吸附), 1989, 5(2): 95-101
58. [58]
  Feng W G, Zhang Q X, Chen J L, Xu Z Y, Pan B C, Su X. Chinese Journal of Reactive Polymers, 1999, 8(1-2): 68-75
59. [59]
  Cheng Ling(承玲), Xu Zhengwen(许正文), Han Qing(韩青), Shi Jing(史静), Lu Jiangang(陆建刚), Zhao Yunlong(赵云龙), Li Fengying(李凤英), Chen Mindong(陈敏东). Polymer Bulletin(高分子通报), 2014, (3): 23-29
60. [60]
  Li Aimin(李爱民), Zhang Quanxing(张全兴), Liu Fuqiang(刘福强), Fei Zhenghao(费正皓), Wang Xuejiang(王学江), Chen Jinlong(陈金龙). Ion Exchange and Adsorption(离子交换与吸附), 2001, 17(6): 515-525
61. [61]
  Fei Zhenghao(费正皓), Chen Jinlong(陈金龙), Cai Jianguo(蔡建国), Li Aimin(李爱民), Zhang Quanxing(张全兴). Technology and Equipment for Environmental Pollution Control(环境污染治理技术与设备), 2003, 4(12): 17-22
62. [62]
  Li A M, Zhang Q X, Wu H S, Zhai Z C, Liu F Q, Fei Z H, Long C, Zhu Z L, Chen J L. Adsorpt Sci Technol, 2004, 22 (10): 807-819 doi: 10.1260/0263617053499005
63. [63]
  Sun Y, Li X T, Xu C, Chen J L, Li A M, Zhang Q X. J Environ Sci-China, 2005, 17 (4): 584-588
64. [64]
  Pan B C, Zhang Q X, Meng F W, Li X T, Zhang X, Zheng J Z, Zhang W M, Pan B J, Chen J L. Environ Sci Technol, 2005, 39 (9): 3308-3313 doi: 10.1021/es048548j
65. [65]
  Xu C, Long C, Li A M, Liu F Q, Yang W B, Zhang Q X. Adsorpt Sci Technol, 2006, 24 (1): 65-77 doi: 10.1260/026361706778062559
66. [66]
  Zhang Quanxing(张全兴), Chen Jinlong(陈金龙) , Li Aimin(李爱民), Yang Weiben(杨维本). Acta Polymerica Sinica(高分子学报), 2008, (7): 651-655
67. [67]
  Zhang Quanxing(张全兴), Li Aimin(李爱民), Liu Fuqiang(刘福强), Fei Zhenghao(费正皓), Pan Bingcai(潘丙才), Long Chao(龙超), Chen Jinlong(陈金龙). Synthesis of Super Crosslinked Weakly Basic Anion Exchange Resin With Double Functions(具有双重功能的超高交联弱碱阴离子交换树脂的合成方法). China patent, ZL 01134143.2. 2001-11-05
68. [68]
  Zhang L D, Fang M. Nano Today, 2010, 5 (2): 128-142 doi: 10.1016/j.nantod.2010.03.002
69. [69]
  Masciangioli T M, Zhang W X. Abstr Pap Am Chem S, 2003, 225: U952-U952
70. [70]
  Colvin V L. Nat Biotechnol, 2003, 21 (10): 1166-1170 doi: 10.1038/nbt875
71. [71]
  Zhao X, Lv L, Pan B C, Zhang W M, Zhang S J, Zhang Q X. Chem Eng J, 2011, 170 (2-3): 381-394 doi: 10.1016/j.cej.2011.02.071
72. [72]
  Zhang Q J, Pan B C, Chen X Q, Zhang W M, Pan B J, Zhang Q X, Lü L, Zha X S. Sci China Ser B, 2008, 51(4): 379-385
73. [73]
  Pan B C, Pan B J, Chen X Q, Zhang W M, Zhang X, Zhang Q J, Zhang Q X, Chen J L. Water Res, 2006, 40 (15): 2938-2946 doi: 10.1016/j.watres.2006.05.028
74. [74]
  Pan B J, Wu J, Pan B C, Lv L, Zhang W M, Xiao L L, Wang X S, Tao X C, Zheng S R. Water Res, 2009, 43 (17): 4421-4429 doi: 10.1016/j.watres.2009.06.055
75. [75]
  Hua M, Xiao L L, Pan B C, Zhang Q X. Front Environ Sci Eng, 2013, 7 (3): 435-441 doi: 10.1007/s11783-013-0508-1
76. [76]
  Jiang Z M, Lv L, Zhang W M, Du Q O, Pan B C, Yang L, Zhang Q X. Water Res, 2011, 45 (6): 2191-2198 doi: 10.1016/j.watres.2011.01.005
77. [77]
  Pan B C, Xu J S, Wu B, Li Z G, Liu X T. Environ. Sci. Technol., 2013, 47 (16): 9347-9354 doi: 10.1021/es401710q
78. [78]
  Pan B C, Li Z G, Zhang Y Y, Xu J S, Chen L, Dong H J, Zhang W M. Chem Eng J, 2014, 248: 290-296 doi: 10.1016/j.cej.2014.02.093
79. [79]
  Bolto B, Dixon D, Eldridge R, King S, Linge K. Water Res, 2002, 36 (20): 5057-5065 doi: 10.1016/S0043-1354(02)00231-2
80. [80]
  Bolto B, Dixon D, Eldridge R. React Funct Polym, 2004, 60: 171-182 doi: 10.1016/j.reactfunctpolym.2004.02.021
81. [81]
  Drikas M, Dixon M, Morran J. Water Res, 2011, 45 (4): 1539-1548 doi: 10.1016/j.watres.2010.11.024
82. [82]
  Gan X J, Karanfil T, Bekaroglu S S K, Shan J H. Water Res, 2013, 47 (3): 1344-1352 doi: 10.1016/j.watres.2012.11.049
83. [83]
  Shuang C D, Pan F, Zhou Q, Li A M, Li P H, Yang W B., Ind Eng Chem Res, 2012, 51 (11): 4380-4387 doi: 10.1021/ie201488g
84. [84]
  Shuang C D, Li P H, Li A M, Zhou Q, Zhang M C, Thou Y. Water Res, 2012, 46 (14): 4417-4426 doi: 10.1016/j.watres.2012.05.052
85. [85]
  Wang Q J, Li A M, Wang J N, Shuang C D. J Environ. Sci China, 2012, 24 (11): 1891-1899 doi: 10.1016/S1001-0742(11)61066-8
86. [86]
  Wang Q J, Shi P, Ma Y, Li A M, Wang J N, Ma R, Chen X. Chem. Eng. J., 2014, 254: 230-236 doi: 10.1016/j.cej.2014.03.103
87. [87]
  Shi P, Ma R, Zhou Q, Li A M, Wu B, Miao Y, Chen X, Zhang X X. J. Hazard Mater, 2015, 285: 53-60 doi: 10.1016/j.jhazmat.2014.09.047
88. [88]
  Wang J, Li H B, Li A M, Shuang C D, Zhou Q. Chem. Eng. J., 2014, 253: 237-242 doi: 10.1016/j.cej.2014.05.060
89. [89]
  Zhang M C, Zhou Q, Zhou Y, Li A M, Shuang C D. Chin. Chem. Lett., 2012, 23 (11): 1267-1270 doi: 10.1016/j.cclet.2012.09.007
90. [90]
  Zhang X L, Cheng C, Qian J S, Lu Z D, Pan S Y, Pan B C. Environ. Sci. Technol., 2017, 51(16): 9210-9218 doi: 10.1021/acs.est.7b01608
91. [91]
  Chen Qun(陈群), He Mingyang(何明阳), Zhang Wenwen(张文雯), Zhang Weihong(张卫红). Bisphenol A Synthesis Catalyst and Its Preparation Method(双酚A合成催化剂及其制备方法). China patent, CN03113425.4. 2003-05-09
92. [92]
  Chen Qun(陈群), He Mingyang(何明阳), Zhang Weihong(张卫红), Zhang Wenwen(张文雯). Storage Method of Catalyst for Bisphenol A Synthesis(双酚A合成催化剂贮存方法). China patent, CN03113424.6. 2003-05-09
93. [93]
  He Mingyang(何明阳), He Hongyi(何洪一), Chen Qun(陈群), Qin Jinlai(秦金来). Macroporous Cation Exchange Resin and Preparation Method and Application in the Synthesis of Bisphenol A in Catalyst(大孔阳离子交换树脂及制备方法以及在合成双酚A催化剂中的用途). China patent, CN200410044962.3. 2004-06-07
94. [94]
  Jiang W, Huang W, Chang N, Qi Y B, Zong X P, Li H, Zhang Q X. Polymer, 2012, 53: 5476-5479 doi: 10.1016/j.polymer.2012.09.044
95. [95]
  Huang W, Cheng N, Qi Y B, Zhang T R, Jiang W, Li H, Zhang Q X. Polymer, 2014, 55: 1491-1496 doi: 10.1016/j.polymer.2014.01.054
1. [1]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
2. [2]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
3. [3]
  Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068
4. [4]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
5. [5]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
6. [6]
  Yihan Xue , Xue Han , Jie Zhang , Xiaoru Wen . NCQDs修饰FeOOH基复合材料的制备及其电容脱盐性能. Acta Physico-Chimica Sinica, 2025, 41(7): 100072-. doi: 10.1016/j.actphy.2025.100072
7. [7]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
8. [8]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
9. [9]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
10. [10]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
11. [11]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
12. [12]
  Dong-Bing Cheng , Junxin Duan , Haiyu Gao . Experimental Teaching Design on Chitosan Extraction and Preparation of Antibacterial Gel. University Chemistry, 2024, 39(2): 330-339. doi: 10.3866/PKU.DXHX202308053
13. [13]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
14. [14]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
15. [15]
  Zhangshu Wang , Xin Zhang , Jixin Han , Xuebing Fang , Xiufeng Zhao , Zeyu Gu , Jinjun Deng . Exploration and Design of Experimental Teaching on Ultrasonic-Enhanced Synergistic Treatment of Ternary Composite Flooding Produced Water. University Chemistry, 2024, 39(5): 116-124. doi: 10.3866/PKU.DXHX202310056
16. [16]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
17. [17]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
18. [18]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
19. [19]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
20. [20]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . 超高比能电池高锰富锂层状氧化物正极材料面临的挑战与解决策略. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-. doi: 10.1016/j.actphy.2025.100085

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(120)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142