Citation:
Rakesh Kumar Gupta, Zhi Wang, Di Sun. Shining bright: Revolutionary near-unity NIR phosphorescent metal nanoclusters[J]. Chinese Journal of Structural Chemistry,
;2024, 43(11): 100417.
doi:
10.1016/j.cjsc.2024.100417
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This work presents a significant advancement in the development of highly efficient NIR-emissive materials. By strategically doping gold nanoclusters with copper, the researchers achieved a near-unity PLQY in the NIR region at room temperature. The comprehensive analysis of structural, photophysical, and excited-state dynamics provides valuable insights into the mechanisms driving this enhanced luminescence. The findings highlight the potential of these nanoclusters for applications in biological imaging and optical communication. However, challenges such as ensuring long-term stability, scalable synthesis, and seamless integration into existing technologies must be addressed, while future exploration of other dopants and synthetic strategies could further enhance their optical properties, paving the way for exciting advancements in nanomaterials.
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[1]
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-
[2]
Yuyang Zhou , Ziwang Mao , Jing-Juan Xu . Recent advances in near infrared (NIR) electrochemiluminescence luminophores. Chinese Chemical Letters, 2024, 35(11): 109622-. doi: 10.1016/j.cclet.2024.109622
-
[3]
Ziyi Liu , Xunying Liu , Lubing Qin , Haozheng Chen , Ruikai Li , Zhenghua Tang . Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement. Chinese Journal of Structural Chemistry, 2024, 43(11): 100405-100405. doi: 10.1016/j.cjsc.2024.100405
-
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Qian Ren , Xue Dai , Ran Cen , Yang Luo , Mingyang Li , Ziyun Zhang , Qinghong Bai , Zhu Tao , Xin Xiao . A cucurbit[8]uril-based supramolecular phosphorescent assembly: Cell imaging and sensing of amino acids in aqueous solution. Chinese Chemical Letters, 2024, 35(12): 110022-. doi: 10.1016/j.cclet.2024.110022
-
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-
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Luyao Lu , Chen Zhu , Fei Li , Pu Wang , Xi Kang , Yong Pei , Manzhou Zhu . Ligand effects on geometric structures and catalytic activities of atomically precise copper nanoclusters. Chinese Journal of Structural Chemistry, 2024, 43(10): 100411-100411. doi: 10.1016/j.cjsc.2024.100411
-
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Jun-Jie Fang , Yun-Peng Xie , Xing Lu . Organooxotin and cobalt/manganese heterometallic nanoclusters exhibiting single-molecule magnetism. Chinese Journal of Structural Chemistry, 2025, 44(4): 100515-100515. doi: 10.1016/j.cjsc.2025.100515
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-
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-
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-
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-
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-
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-
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-
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-
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-
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