Citation: Xin Zhang, Tongxia Jin, Changyin Yang, Dezheng Xu, Haidong Jia, Lin Xu. Azobenzene-containing photoresponsive metal-organic cages[J]. Chinese Chemical Letters, ;2025, 36(12): 111135. doi: 10.1016/j.cclet.2025.111135 shu

Azobenzene-containing photoresponsive metal-organic cages

Xin Zhang ^a ,
Tongxia Jin ^{a, b} ,
Changyin Yang ^a ,
Dezheng Xu ^{c, *,} ,
Haidong Jia ^{c, *,} ,
Lin Xu ^{a, b, *,}

a.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China
b.
Wuhu Hospital Affiliated to East China Normal University (The Second People's Hospital of Wuhu), Wuhu 241001, China
c.
Shanghai Jahwa United Co., Ltd., Shanghai 200082, China

xudezheng1@jahwa.com.cn

jiahaidong@jahwa.com.cn

lxu@chem.ecnu.edu.cn

Received Date: 26 February 2025
Revised Date: 19 March 2025
Accepted Date: 20 March 2025
Available Online: 21 March 2025

Figures(12)

In recent years, stimulus-responsive metal-organic cages (MOCs) have attracted significant attention due to their dynamic structures and properties, which greatly enhance the structural diversity and functional adaptability of these supramolecular assemblies. Among various external stimuli, light stands out as a straightforward and efficient means of modulating MOCs through the incorporation of photoresponsive units, such as azobenzene, thereby enabling precise photoresponsive behavior. Substantial progress has been made in the development of azobenzene-containing MOCs, underscoring their research significance and broad application potential across multiple fields. Given these advancements, it is timely to provide a comprehensive summary of the latest progress in azophenyl-based MOCs. This review will highlight key developments and explore their functional applications.
- Metal-organic cage,
- Azobenzene,
- Photoresponsive,
- Supramolecular chemistry,
- Host-guest chemistry
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