Citation: Wen-Wen Xu, Yue-Xiu Qin, Xiao-Yong Yu, Lin-Nan Jiang, Heng-Yi Zhang, Yong Chen, Yu Liu. Multipath cascade light harvesting for multicolor luminescence based on macrocyclic sulfonatocalix[4]arene[J]. Chinese Chemical Letters, ;2025, 36(11): 111068. doi: 10.1016/j.cclet.2025.111068 shu

Multipath cascade light harvesting for multicolor luminescence based on macrocyclic sulfonatocalix[4]arene

College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

yuliu@nankai.edu.cn

Received Date: 14 December 2024
Revised Date: 8 March 2025
Accepted Date: 11 March 2025
Available Online: 12 March 2025

Figures(5)

Herein, anthracene-pyridinium derivative (A1) is synthesized to assemble with amphiphilic sulfonatocalix[4]arene (SC4AD) with a porous cavity through electrostatic interaction, exhibiting enhanced fluorescence emission and multipath fluorescence resonance energy transfer (FRET) with organic dyes (EY, NiR or Cy5.5). In this nanoassembly, A1/SC4AD first transfers the energy to dye EY (first acceptor), and then delivers it to NiR (second acceptor), which further transfers the energy to Cy5.5 (third acceptor), accompanying with an emission ranging from 535 nm to 570 nm, then to 638 nm, and finally to near-infrared emission at 717 nm. Compared to one-step FRET (43.0%), the three-step FRET system shows higher energy transfer efficiency (FRET Ⅰ: 84.9%, FRET Ⅱ: 81.4%, FRET Ⅲ: 66.9%). The donor/acceptor ratio is 3000 (A1): 20 (EY): 8 (NiR): 5 (Cy5.5), together with an antenna effect of 2.3. Additionally, diverse two-step cascade light-harvesting systems are successfully fabricated via tuning combination of dye acceptors. We believe that this multipath light-harvesting assembly will provide a direction for designing multiple sequential FRET and artificial light-harvesting systems.
- Multipath FRET,
- Cascade energy transfer,
- Light-harvesting,
- Supramolecular assembly,
- Calixarene
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