Citation: Ting Zhang, Baojing Huang, Hong Huang, Ailing Yan, Shiqiang Lu, Xufang Qian. Visible light boosted Fenton-like reaction of carbon dot-Fe(Ⅲ) complex: Kinetics and mechanism insights[J]. Chinese Chemical Letters, ;2025, 36(11): 110885. doi: 10.1016/j.cclet.2025.110885 shu

Visible light boosted Fenton-like reaction of carbon dot-Fe(Ⅲ) complex: Kinetics and mechanism insights

Ting Zhang ^{a, 1} ,
Baojing Huang ^{a, c, 1} ,
Hong Huang ^a ,
Ailing Yan ^b ,
Shiqiang Lu ^{b, *,} ,
Xufang Qian ^{a, *,}

a.
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
b.
Shanghai Engineering Research Center of Water Environment Simulation and Ecological Restoration, Shanghai Academy of Environment Sciences, Shanghai 200233, China
c.
Yazhou Bay Institute of Deepsea Technology, Shanghai Jiao Tong University, Sanya 572000, China

Lushiqiang2007@qq.com

qianxufang@sjtu.edu.cn

Received Date: 26 September 2024
Revised Date: 11 December 2024
Accepted Date: 19 January 2025
Available Online: 20 January 2025

Figures(6)

Carbon dot (CD) is an edge-bound, nanometer-sized carbon material possessing unique optical and electronic properties, making it promising metal-free, environmentally benign. In this study, we identified a highly hydrophilic CD complexed with Fe(Ⅲ) via carboxyl groups to form CD-COOFe^Ⅲ, which exhibited remarkably enhanced Fenton-like reaction performance boosted by visible light irradiation. CD-COOFe^Ⅲ enabled high activity in the visible region beyond λ > 420 nm, and maintained stable oxidation efficiency in the presence of H₂O₂ over at least ten cycles. The capacity of electrons transferred from photo-excited CD to reduce Fe(Ⅲ) was calculated to be 1.1 mmol/g of CD. Furthermore, the quantum yield (QY) of solar-to-Fe(Ⅱ) conversion reached an impressive 87.7%. These findings not only suggest a viable strategy for efficient conversion of solar-to-chemical using a CD-COOFe^Ⅲ complex in visible light boosted Fenton-like oxidation reaction, but also provide insight for understanding the effect of nanosized artificial and/or natural carbon materials in iron recycling in a natural surface environment.
- CD-COOFe^Ⅲ complex,
- Fenton-like reaction,
- Visible light,
- Organic pollutants,
- Carbon dot
1. [1]
  M.J.F. Calvete, G. Piccirillo, C.S. Vinagreiro, M.M. Pereira, Coord. Chem. Rev. 395 (2019) 63–85. doi: 10.1016/j.ccr.2019.05.004
2. [2]
  S. Garcia-Segura, E. Brillas, J. Photoch. Photobio. C 31 (2017) 1–35. doi: 10.1016/j.jphotochemrev.2017.01.005
3. [3]
  J. Deng, Y. Zeng, E. Almatrafi, et al., Coord. Chem. Rev. 505 (2024) 215693–215715. doi: 10.1016/j.ccr.2024.215693
4. [4]
  L. Qin, C. Ma, J. Zhang, T. Zhou, Adv. Funct. Mater. 34 (2024) 2401562–2401602. doi: 10.1002/adfm.202401562
5. [5]
  Q. Zhang, S. Gao, Y. Guo, et al., Nat. Commun. 14 (2023) 1147–1157. doi: 10.1038/s41467-023-36779-4
6. [6]
  X. Li, Q. Dong, Q. Tian, et al., Mater. Today Chem. 26 (2022) 101037–101057. doi: 10.1016/j.mtchem.2022.101037
7. [7]
  Z.L. Shaw, S. Kuriakose, S. Cheeseman, et al., Nat. Commun. 12 (2021) 3879–7606. doi: 10.1038/s41467-021-24185-7
8. [8]
  B. Zhao, D. Shen, Z. Zhang, et al., Adv. Funct. Mater. 31 (2021) 2105132–2105167. doi: 10.1002/adfm.202105132
9. [9]
  S. Deshmukh, A. Deore, S. Mondal, ACS Appl. Nano Mater. 4 (2021) 7587–7606. doi: 10.1021/acsanm.1c01880
10. [10]
  J.E. Ulloa Rojas, V.L. de Oliveira, D.R. de Araujo, et al., ACS Biomater. Sci. Eng. 8 (2022) 128–139. doi: 10.1021/acsbiomaterials.1c00913
11. [11]
  L. Dordevic, F. Arcudi, M. Cacioppo, M. Prato, Nat. Nanotechnol. 17 (2022) 112–130. doi: 10.1038/s41565-021-01051-7
12. [12]
  Z.A. Qureshi, H. Dabash, D. Ponnamma, M.K.G. Abbas, Heliyon 10 (2024) e31634-31657.
13. [13]
  H. Wang, L. Ai, Z. Song, et al., Chem. Eur. J. 29 (2023) e202302383. doi: 10.1002/chem.202302383
14. [14]
  G.A.M. Hutton, B. Reuillard, B.C.M. Martindale, et al., J. Am. Chem. Soc. 138 (2016) 16722–16730. doi: 10.1021/jacs.6b10146
15. [15]
  H. Yang, Y. Liu, Z. Guo, et al., Nat. Commun. 10 (2019) 1789–1799. doi: 10.1038/s41467-019-09830-6
16. [16]
  F. Zhao, X. Li, M. Zuo, et al., J. Environ. Chem. Eng. 11 (2023) 109487–109511. doi: 10.1016/j.jece.2023.109487
17. [17]
  K.A.S. Fernando, S. Sahu, Y. Liu, et al., ACS Appl. Mater. Interfaces 7 (2015) 8363–8376. doi: 10.1021/acsami.5b00448
18. [18]
  J. Peng, W. Gao, B.K. Gupta, et al., Nano Lett. 12 (2012) 844–849. doi: 10.1021/nl2038979
19. [19]
  L.A. Ponomarenko, F. Schedin, M.I. Katsnelson, et al., Science 320 (2008) 356–358. doi: 10.1126/science.1154663
20. [20]
  C. Su, M. Acik, K. Takai, et al., Nat. Commun. 3 (2012) 2315–2323.
21. [21]
  Z. Lin, W. Xue, H. Chen, J.-M. Lin, Chem. Commun. 48 (2012) 1051–1053. doi: 10.1039/C1CC15290D
22. [22]
  S. Ghosh, K. Chakraborty, T. Pal, S. Ghosh, Sci. Rep. 13 (2023) 19028–19040. doi: 10.1038/s41598-023-46120-0
23. [23]
  Y. Li, P. Li, J. Wang, et al., Appl. Catal. B 225 (2018) 519–529. doi: 10.1016/j.apcatb.2017.12.017
24. [24]
  R. Gogoi, S.K. Jena, A. Singh, et al., J. Environ. Chem. Eng. 12 (2024) 112006–112019. doi: 10.1016/j.jece.2024.112006
25. [25]
  O.A. Yildirim, H. Arslan, S. Sonmezoglu, Appl. Surf. Sci. 390 (2016) 111–121. doi: 10.17131/milelnihal.88630
26. [26]
  H. Ming, Z. Ma, Y. Liu, et al., Dalton Trans. 41 (2012) 9526–9531. doi: 10.1039/c2dt30985h
27. [27]
  M.M. Bello, A.A.A. Raman, A. Asghar, Process Saf. Environ. Protect. 126 (2019) 119–140. doi: 10.1016/j.psep.2019.03.028
28. [28]
  C. Zhang, N. Ding, Y. Pan, L. Fu, Y. Zhang, Chin. Chem. Lett. 35 (2024) 109579–109590. doi: 10.1016/j.cclet.2024.109579
29. [29]
  C. Dong, J. Ji, B. Shen, M. Xing, J. Zhang, Environ. Sci. Technol. 52 (2018) 11297–11308. doi: 10.1021/acs.est.8b02403
30. [30]
  T. Zhang, Y. Wen, Z. Pan, et al., Environ. Sci. Technol. 56 (2022) 2617–2625. doi: 10.1021/acs.est.1c06276
31. [31]
  M. Xing, W. Xu, C. Dong, et al., Chem 4 (2018) 1359–1372. doi: 10.1016/j.chempr.2018.03.002
32. [32]
  S. Xiao, C. Zhou, X. Ye, et al., ACS Appl. Mater. Interfaces 12 (2020) 32604–32614. doi: 10.1021/acsami.0c06373
33. [33]
  M. Sudolska, M. Dubecky, S. Sarkar, et al., J. Phys. Chem. C 119 (2015) 13369–13373. doi: 10.1021/acs.jpcc.5b04080
1. [1]
  Siyuan You , Rui Li , Haoyun Lu , Lifei Hou , Xing Xu , Yanan Shang . Modulation of the structures and properties of iron-carbon composites by different small molecular carbon sources for Fenton-like reactions. Chinese Chemical Letters, 2025, 36(9): 110955-. doi: 10.1016/j.cclet.2025.110955
2. [2]
  Kexin Yin , Jingren Yang , Yanwei Li , Qian Li , Xing Xu . Metal-free diatomaceous carbon-based catalyst for ultrafast and anti-interference Fenton-like oxidation. Chinese Chemical Letters, 2024, 35(12): 109847-. doi: 10.1016/j.cclet.2024.109847
3. [3]
  Quan Zhang , Shunjie Xing , Jingqian Han , Li Feng , Jianchun Li , Zhaosheng Qian , Jin Zhou . Organic pollutant sensing for human health based on carbon dots. Chinese Chemical Letters, 2025, 36(1): 110117-. doi: 10.1016/j.cclet.2024.110117
4. [4]
  Xiang Li , Beibei Zhang , Zhixiang Wang , Xiangyu Chen . Organocatalyzed iodine-mediated reversible-deactivation radical polymerization via photoinduced charge transfer complex catalysis. Chinese Chemical Letters, 2025, 36(6): 110383-. doi: 10.1016/j.cclet.2024.110383
5. [5]
  Qingbai Tian , BingLiang Yu , Zhihao Li , Wei Hong , Qian Li , Xing Xu . Versatile catalytic membranes anchored with metal-nitrogen based metal oxides for ultrafast Fenton-like oxidation. Chinese Chemical Letters, 2025, 36(6): 110322-. doi: 10.1016/j.cclet.2024.110322
6. [6]
  Lang Gao , Cen Zhou , Rui Wang , Feng Lan , Bohang An , Xiaozhou Huang , Xiao Zhang . Unveiling inverse vulcanized polymers as metal-free, visible-light-driven photocatalysts for cross-coupling reactions. Chinese Chemical Letters, 2024, 35(4): 108832-. doi: 10.1016/j.cclet.2023.108832
7. [7]
  Liangbo Zhang , Jun Cheng , Yahui Shi , Kunjie Hou , Qi An , Jingyi Li , Baohui Cui , Fei Chen . Efficient removal of tetracycline hydrochloride by ZnO/HNTs composites under visible light: Kinetics, degradation pathways and mechanism. Chinese Chemical Letters, 2025, 36(7): 110400-. doi: 10.1016/j.cclet.2024.110400
8. [8]
  Yuqing Zhu , Haohao Chen , Li Wang , Liqun Ye , Houle Zhou , Qintian Peng , Huaiyong Zhu , Yingping Huang . Piezoelectric materials for pollutants degradation: State-of-the-art accomplishments and prospects. Chinese Chemical Letters, 2024, 35(4): 108884-. doi: 10.1016/j.cclet.2023.108884
9. [9]
  Bohan Zhang , Bingzhe Wang , Guichuan Xing , Zikang Tang , Songnan Qu . Regulation of the multi-emission centers in carbon dots via a bottom-up synthesis approach. Chinese Chemical Letters, 2024, 35(9): 109358-. doi: 10.1016/j.cclet.2023.109358
10. [10]
  Jinshu Huang , Zhuochun Huang , Tengyu Liu , Yu Wen , Jili Yuan , Song Yang , Hu Li . Modulating single-atom Co and oxygen vacancy coupled motif for selective photodegradation of glyphosate wastewater to circumvent toxicant residue. Chinese Chemical Letters, 2025, 36(5): 110179-. doi: 10.1016/j.cclet.2024.110179
11. [11]
  Lei Shen , Yang Zhang , Linlin Zhang , Chuanwang Liu , Zhixian Ma , Kangjiang Liang , Chengfeng Xia . Phenylhydrazone anions excitation for the photochemical carbonylation of aryl iodides with aldehydes. Chinese Chemical Letters, 2024, 35(4): 108742-. doi: 10.1016/j.cclet.2023.108742
12. [12]
  Jiayi Guo , Liangxiong Ling , Qinwei Lu , Yi Zhou , Xubiao Luo , Yanbo Zhou . Degradation of chloroxylenol by CoS_x activated peroxomonosulfate: Role of cobalt-sulfur ratio. Chinese Chemical Letters, 2025, 36(4): 110380-. doi: 10.1016/j.cclet.2024.110380
13. [13]
  Hanghang Zhao , Wenbo Qi , Xin Tan , Xing Xu , Fengmin Song , Xianzhao Shao . Metal single-atom catalysts derived from silicon-based materials for advanced oxidation applications. Chinese Chemical Letters, 2025, 36(6): 110898-. doi: 10.1016/j.cclet.2025.110898
14. [14]
  Yanhua Peng , Xin Yu , Ting Wang . Adaptive nanoconfined Fenton-like reactions: Tailoring carbon pathways for sustainable water treatment and energy harvesting. Chinese Chemical Letters, 2024, 35(12): 110198-. doi: 10.1016/j.cclet.2024.110198
15. [15]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
16. [16]
  Xin Wang , Changzhao Chen , Qishen Wang , Kai Dai . Graphene quantum dot modified Bi2MoO6 nanoflower for efficient degradation of BPA under visible light. Chinese Journal of Structural Chemistry, 2024, 43(12): 100473-100473. doi: 10.1016/j.cjsc.2024.100473
17. [17]
  Xuhui Fan , Fan Wang , Mengjiao Li , Faiza Meharban , Yaying Li , Yuanyuan Cui , Xiaopeng Li , Jingsan Xu , Qi Xiao , Wei Luo . Visible light excitation on CuPd/TiN with enhanced chemisorption for catalyzing Heck reaction. Chinese Chemical Letters, 2025, 36(1): 110299-. doi: 10.1016/j.cclet.2024.110299
18. [18]
  Mengmeng Ao , Jian Wei , Chuan-Shu He , Heng Zhang , Zhaokun Xiong , Yonghui Song , Bo Lai . Insight into the activation of peroxymonosulfate by N-doped copper-based carbon for efficient degradation of organic pollutants: Synergy of nonradicals. Chinese Chemical Letters, 2025, 36(1): 109882-. doi: 10.1016/j.cclet.2024.109882
19. [19]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
20. [20]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(22)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142