Citation: Bo Yang, Suqiong Yan, Shirong Ban, Wei Huang. New horizons in phosphorus-based emitters: From circularly polarized fluorescence to room-temperature phosphorescence[J]. Chinese Chemical Letters, ;2025, 36(11): 110837. doi: 10.1016/j.cclet.2025.110837 shu

New horizons in phosphorus-based emitters: From circularly polarized fluorescence to room-temperature phosphorescence

Bo Yang ^a ,
Suqiong Yan ^a ,
Shirong Ban ^a ,
Wei Huang ^{a, b, *,}

a.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
b.
Shenzhen Research Institute of Nanjing University, Shenzhen 518057, China

whuang@nju.edu.cn

Received Date: 2 October 2024
Revised Date: 7 January 2025
Accepted Date: 9 January 2025
Available Online: 9 January 2025

Figures(10)

Phosphorus-based luminescent materials consist of certain phosphorus in the aromatic backbones, endowing a larger nuclear charge (Z, ¹⁵P), rich valence states for the phosphorus core, and various electron geometries. These features enable promising exploitation for luminescent materials with significant quantum efficiencies and tunable singlet and triplet populations. This mini review focuses on the break-throughs of organic and organometallic phosphorus compounds in advanced circularly polarized fluorescence (CPF) and circularly polarized room-temperature phosphorescence (CP-RTP) by unveiling the structure-function relationships, e.g., design concept, charge transfer (CT) type, chiral conformation, and excited state transition configuration, and the recent applications in optical information encryption, lighting-displaying, and organic light emitting diodes (OLEDs). By dedicated analysis of current progresses, we hope this work will throw insights into phosphorus-based CPF and CP-RTP behaviors and provide a reference for the rational design of high-performance phosphorus-based emitters.
- Circularly polarized luminescence,
- Room-temperature phosphorescence,
- Charge transfer,
- Phosphorus-based emitters,
- Organophosphorus complexes
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沈阳化工大学材料科学与工程学院沈阳 110142