Citation: Pei-Pei Jia, Yi-Xiong Hu, Zhen-Chen Lou, Xuelei Ji, Xing-Dong Xu, Haitao Sun, Tongxia Jin, Feng Zheng, Lin Xu. Construction of BODIPY-based triangular metallacycles with tunable photosensitization efficiency[J]. Chinese Chemical Letters, ;2025, 36(11): 110835. doi: 10.1016/j.cclet.2025.110835 shu

Construction of BODIPY-based triangular metallacycles with tunable photosensitization efficiency

Pei-Pei Jia ^{a, c} ,
Yi-Xiong Hu ^{b, c, *,} ,
Zhen-Chen Lou ^c ,
Xuelei Ji ^a ,
Xing-Dong Xu ^{d, *,} ,
Haitao Sun ^e ,
Tongxia Jin ^{a, c} ,
Feng Zheng ^{a, *,} ,
Lin Xu ^{a, c, *,}

a.
Wuhu Hospital, East China Normal University (The Second People's Hospital, Wuhu), Wuhu 241001, China
b.
College of New Energy, Yulin University, Yulin 719000, China
c.
State Key Laboratory of Petroleum Molecular & Process Engineering, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Shanghai Frontiers Science Center of Molecule Intelligent Syntheses, Liwa Institute of Skin Health, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China
d.
Key Laboratory of Special Functional Aggregated Materials of Ministry of Education, School of Chemistry and Chemical Engineering, National Engineering Research Center for Colloidal Materials, Shandong University, Ji'nan 250100, China
e.
State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai 200241, China

yxhu@yulinu.edu.cn

xuxd@sdu.edu.cn

fzheng@hsc.ecnu.edu.cn

lxu@chem.ecnu.edu.cn

Received Date: 29 September 2024
Revised Date: 31 December 2024
Accepted Date: 6 January 2025
Available Online: 7 January 2025

Figures(5)

The development of highly effective photosensitizers (PSs) based on supramolecular coordination complexes (SCCs) is highly appealing in supramolecular chemistry, materials science, and biology. SCCs offer promising platforms for incorporating multiple PSs and other functional units into their well-defined structures, allowing for precise control over the number and distribution of these components. In this study, we present an efficient and straightforward method for modulating the photosensitization process of PSs derived from a family of BF₂-chelated dipyrromethene (BODIPY)-containing Pt(Ⅱ) metallacycles by varying pre-designed Pt(Ⅱ) acceptors. By utilizing different Pt(Ⅱ) acceptors with varying Pt atom configurations and degrees of π-conjugated organic moieties, we observed tunable characteristics in the photosensitization process and singlet oxygen (¹O₂) generation efficiency of these targeted metallacycles. Furthermore, we successfully conducted the visible-light-driven oxidative coupling of various amines to imines, catalyzed by the prepared metallacycle PSs. This study offers a novel approach for fabricating efficient PSs based on SCCs, featuring tunable photosensitization efficiency and excellent photocatalytic reactivity, while providing new insights into the preparation of effective PSs.
- Photochemistry,
- Coordination-driven self-assembly,
- Metallacycle,
- Bodipy,
- Photosensitization
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