Citation: Hong-Guang Fu, Xuan Wu, Hui-Juan Wang, Fanjun Zhang, Yong Chen, Jing Xu. Color-tunable multi-stimuli-responsive luminescent system based on diarylethene and photoacid[J]. Chinese Chemical Letters, ;2025, 36(8): 110741. doi: 10.1016/j.cclet.2024.110741 shu

Color-tunable multi-stimuli-responsive luminescent system based on diarylethene and photoacid

Hong-Guang Fu ^{a, b, *,} ,
Xuan Wu ^a ,
Hui-Juan Wang ^d ,
Fanjun Zhang ^c ,
Yong Chen ^{e, *,} ,
Jing Xu ^{a, *,}

a.
College of Chemistry and Material Science, Shandong Agricultural University, Tai'an 271018, China
b.
College of Forestry, Shandong Agricultural University, Tai'an 271018, China
c.
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China
d.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China
e.
College of Chemistry, State Key Laboratory of Elemento–Organic Chemistry, Nankai University, Tianjin 300071, China

fuhongguang1990@163.com

chenyong@nankai.edu.cn

jiaxu@sdau.edu.cn

Received Date: 11 November 2024
Revised Date: 27 November 2024
Accepted Date: 9 December 2024
Available Online: 9 December 2024

Figures(6)

The development of multi-stimuli-responsive luminescent system to address emerging demands is essential in anti-counterfeiting field. Herein, a photoswitchable system was reported, which was constructed from photoacid sulfonato-merocyanine (MEH-D) serving as H⁺ donor and diarylethene derivative (DAE-A1) as acceptor. After capturing 2 equiv. HCl, the obtained fluorescent molecule DAE-A1-H showed solvatochromic property. Further on, benefiting from that MEH-D released protons and became a ring-closed isomer spiropyran (SP-D) under 440 nm irradiation, DAE-A1 was protonated, turning on fluorescence effect was realized in DAE-A1/MEH-D. In dark, a photo-activated reversible process was realized with SP-D changed to MEH-D in situ system. In addition, the OF-DAE-A1-H/SP-D could efficiently and reversibly switch on/off its luminescence upon irradiation by UV–vis light. Significantly, the multi-stimuli-responsive system was successfully applied in logic gate and fluorescence ink, making it an efficient strategy for information encryption and decryption with higher security requirements.
- Multi-stimuli-responsive luminescent system,
- Diarylethene photoacid,
- Logic gate,
- Anti-counterfeiting
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