Citation: Pan-Pan Hua, Hui-Jun Feng, Shu-Ning Lan, Francisco Aznarez, Li-Fang Zhang. Post-modification-induced supramolecular transformation of Hopf link to macrocycle[J]. Chinese Chemical Letters, ;2025, 36(6): 110684. doi: 10.1016/j.cclet.2024.110684 shu

Post-modification-induced supramolecular transformation of Hopf link to macrocycle

a.
Key Laboratory of Magnetic Molecules and Magnetic Information Materials of the Ministry of Education, School of Chemistry and Material Science, Shanxi Normal University, Taiyuan 030031, China
b.
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, Shanghai 200438, China

17110220045@fudan.edu.cn

zhanglf705@163.com

Received Date: 14 October 2024
Revised Date: 15 November 2024
Accepted Date: 26 November 2024
Available Online: 27 November 2024

Figures(7)

Although supramolecular transformations have been emerged as a potent strategy for transitioning between various topologies, post-modification induced topological transformations have never been explored in the context of [2]catenane topologies. In this study, we present a novel supramolecular transformation between a Hopf link and a macrocycle, induced by the Diels–Alder click reaction. By strategically selecting the half-sandwich ruthenium binuclear fragment B as a rigid capping agent, we successfully integrated tetrazine moieties into the metalla[2]catenane structure. We demonstrated that the introduction of 2,5-norbornadiene (NBD) as an external stimulus allows for the transformation of the novel metalla[2]catenane, featuring reactive tetrazine sites, into the corresponding monomeric ring through post-modification for the first time. The synthetic results are corroborated by single-crystal X-ray diffraction analysis, ESI-TOF/MS, elemental analysis, and detailed solution-state NMR techniques.
- Diels–Alder reaction,
- Half-sandwich ruthenium acceptor,
- Hopf link,
- Post-modification,
- Supramolecular transformation
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