Citation: Xinhui Fan, Yonghao Fan, Yuli Dang, Puhui Xie, Xin Li, Zhanqi Cao, Song Jiang, Lijie Liu, Xin Zheng, Lixia Xie, Caoyuan Niu, Guoxing Liu, Yong Chen. Logically ordered control of organic room-temperature long-lived supramolecular luminophors[J]. Chinese Chemical Letters, ;2025, 36(8): 110648. doi: 10.1016/j.cclet.2024.110648 shu

Logically ordered control of organic room-temperature long-lived supramolecular luminophors

Xinhui Fan ^a ,
Yonghao Fan ^a ,
Yuli Dang ^a ,
Puhui Xie ^a ,
Xin Li ^a ,
Zhanqi Cao ^a ,
Song Jiang ^a ,
Lijie Liu ^a ,
Xin Zheng ^a ,
Lixia Xie ^a ,
Caoyuan Niu ^a ,
Guoxing Liu ^{a, *,} ,
Yong Chen ^b

a.
College of Science, Henan Agricultural University, Zhengzhou 450002, China
b.
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

gxliu@henau.edu.cn

Received Date: 1 September 2024
Revised Date: 9 November 2024
Accepted Date: 12 November 2024
Available Online: 13 November 2024

Figures(5)

Herein, a ternary supramolecular assembly (BPP-BQ⊂CB[8]-SCD) is successfully constructed by a bromophenylpyridine-tethered-bromoisoquinoline (BPP-BQ), cucurbit[8]uril (CB[8]) and sulfonated β-cyclodextrin (SCD) via successive assembling way, exhibiting progressively enhanced green room-temperature phosphorescence (RTP). The self-aggregates of BPP-BQ⊂CB[8]-SCD accommodate an energy acceptor rhodamine B (RhB) to form a light-harvesting system (BPP-BQ⊂CB[8]-SCD@RhB) with further enhanced yellow long-lifetime luminescence with large Stokes shift based on triplet-singlet Förster resonance energy transfer (TS-FRET). Crucially, the introduction of a photoactive diarylethene achieves the long-lived photoluminescence of BPP-BQ⊂CB[8]-SCD@RhB to be switched with the efficiency of up to 98% through logically ordered lowering/enhancing RTP performance of the energy donor and intercepting/restoring TS-FRET pathway, when stimulated by host-guest competition and light illumination in sequence. Moreover, BPP-BQ⊂CB[8]-SCD@RhB is evenly doped into polyvinyl alcohol or polyacrylamide to obtain high-performance luminescent films with long afterglow. The abovementioned logically ordered stimulus-switched long-lived emission enables the light-harvesting system in both solution and solid state to be applied in high-security-level information encryption and transformation, and anti-counterfeiting.
- Supramolecular chemistry,
- Logically ordered control,
- Long-lived luminescent switch,
- TS-FRET,
- Stepwise assembly,
- RTP
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