Citation: Dan Shao, Yujing Lyu, Chengyuan Liu, Hao Wang, Ning Ma, Hao Xu, Wei Yan, Xiaohua Jia, Haojie Song. Attracting magnetic BDD particles onto Ti/RuO₂-IrO₂ by using a magnet: A novel 2.5-dimensional electrode for electrochemical oxidation wastewater treatment[J]. Chinese Chemical Letters, ;2025, 36(6): 110641. doi: 10.1016/j.cclet.2024.110641 shu

Attracting magnetic BDD particles onto Ti/RuO₂-IrO₂ by using a magnet: A novel 2.5-dimensional electrode for electrochemical oxidation wastewater treatment

Dan Shao ^{a, *,} ,
Yujing Lyu ^a ,
Chengyuan Liu ^b ,
Hao Wang ^a ,
Ning Ma ^a ,
Hao Xu ^{c, *,} ,
Wei Yan ^c ,
Xiaohua Jia ^a ,
Haojie Song ^{a, *,}

a.
School of Materials Science and Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science & Technology, Xi'an 710021, China
b.
Shaanxi Metron Diamond Material Technology Co., Ltd., Yangling 712100, China
c.
Department of Environmental Engineering, Xi'an Jiaotong University, Xi'an 710049, China

shaodan@sust.edu.cn

xuhao@mail.xjtu.edu.cn

songhaojie@sust.edu.cn

Received Date: 7 July 2024
Revised Date: 10 October 2024
Accepted Date: 9 November 2024
Available Online: 10 November 2024

Figures(4)

Boron-doped diamond (BDD) is a well-known anode material with a high pollutant degradation ability for electrochemical oxidation wastewater treatment. Nevertheless, the cost of production and mechanical strength of BDD membranes remain unsatisfactory. Magnetic BDD particles derived from industrial waste may represent a promising alternative to BDD membranes, although the challenge remains in assembling these particles into a usable electrode. In this study, magnetic BDD particles were attracted to a Ti/RuO₂-IrO₂ electrode using a magnet, thus constituting a novel 2.5-dimensional (2.5D) electrode. To ascertain the structure-activity relationship of the novel electrode, essential characterizations, multi-physics simulations, pollutant degradation and electrosynthesis experiments were conducted. The results indicate that an appropriate quantity of BDD particles (0.1 g/cm²) can enhance the number of active sites by approximately 20%. A strong synergistic effect was observed between the Ti/RuO₂-IrO₂ and BDD particles in the degradation of various pollutants, including azo dye, p-benzoquinone, succinic acid and four kinds of real wastewaters, as well as glycerol conversion. The joint active sites on the interface between Ti/RuO₂-IrO₂ and BDD particles, as well as the inner active sites on BDD particles, have been identified as crucial in the mineralization of pollutants and the generation of value-added products. The optimal amount of BDD particles (0.1 g/cm²) is sufficient to preserve the joint active sites and to maintain an adequate polarization on the BDD particles. Nevertheless, the hybrid feature of the 2.5D electrode is diminished when a greater quantity of BDD particles (0.3 g/cm²) is loaded.
- Boron-doped diamond,
- Hybrid electrode,
- Organic wastewater,
- Real wastewater,
- Multi-physics simulation
1. [1]
  Z.H. Zhu, M. Daboczi, M.Z. Chen, et al., Nat. Commun. 15 (2024) 2791. doi: 10.1038/s41467-024-47100-2
2. [2]
  F.C.I. Catalan, L.T. Anh, J. Oh, et al., Adv. Mater. 33 (2021) 2103250. doi: 10.1002/adma.202103250
3. [3]
  L. Fan, L. Constantin, Z.P. Wu, et al., Sci. Adv. 7 (2021) eabc7547. doi: 10.1126/sciadv.abc7547
4. [4]
  Y. Yan, L. Bing, L.H. Zhang, et al., Chem. Eng. J. 487 (2024) 150447. doi: 10.1016/j.cej.2024.150447
5. [5]
  H.C. Li, Z.J. Deng, Z.K. Jiao, et al., Chem. Eng. J. 446 (2022) 136927. doi: 10.1016/j.cej.2022.136927
6. [6]
  L. Saleh, M. Remot, Q.B. Remaury, et al., Chem. Eng. J. 489 (2024) 151355. doi: 10.1016/j.cej.2024.151355
7. [7]
  H.Z. Wu, Z.Z. Hu, R.H. Liang, et al., J. Hazard. Mater. 456 (2023) 131696. doi: 10.1016/j.jhazmat.2023.131696
8. [8]
  D.T. Miao, Z.S. Li, Y.H. Chen, et al., Chem. Eng. J. 429 (2022) 132366. doi: 10.1016/j.cej.2021.132366
9. [9]
  S. Deshmukh, S. Kunuku, P. Jakobczyk, et al., Adv. Funct. Mater. 34 (2024) 2308617. doi: 10.1002/adfm.202308617
10. [10]
  S. Mavrikis, M. Göltz, S.C. Perry, et al., ACS Energy Lett. 6 (2021) 2369-2377. doi: 10.1021/acsenergylett.1c00904
11. [11]
  S. Suman, M. Ficek, K.J. Sankaran, et al., Energy 294 (2024) 130914. doi: 10.1016/j.energy.2024.130914
12. [12]
  J.W. Yin, W.L. Gao, W.J. Yu, et al., Microsyst. Nanoeng. 8 (2022) 39. doi: 10.1038/s41378-022-00359-1
13. [13]
  C.A. Martínez-Huitle, M.A. Rodrigo, I. Sirés, O. Scialdone, Appl. Catal. B: Environ. 328 (2023) 122430. doi: 10.1016/j.apcatb.2023.122430
14. [14]
  Z. Jian, M. Heide, N.J. Yang, C. Engelhard, X. Jiang, Carbon 175 (2021) 36-42. doi: 10.1016/j.carbon.2020.12.066
15. [15]
  C. Terashima, R. Hishinuma, N. Roy, et al., ACS Appl. Mater. Interfaces 8 (2016) 1583-1588. doi: 10.1021/acsami.5b10993
16. [16]
  S.Y. Su, Y.H. Wang, Y.K. Zhou, et al., Sustainable Mater. Technol. 39 (2024) e00869. doi: 10.1016/j.susmat.2024.e00869
17. [17]
  H.T. Ji, G.C. Hu, J.J. Wu, W.H. Ma, J. Environ. Chem. Eng. 12 (2024) 111865. doi: 10.1016/j.jece.2023.111865
18. [18]
  J. Qiu. Ceram. Int. 48 (2022) 24332-24345. doi: 10.1016/j.ceramint.2022.04.327
19. [19]
  Z.Q. Hu, G.L. Wang, J.Y. Li, et al., Waste Manage. 157 (2023) 190-198. doi: 10.1016/j.wasman.2022.12.023
20. [20]
  Y.K. Zhao, W.B. Bi, P.Q. Ge, J. Manuf. Processes 71 (2021) 290-297. doi: 10.1016/j.jmapro.2021.09.041
21. [21]
  D. Shao, X.L. Zhang, W. Lyu, et al., ACS Appl. Mater. Interfaces 10 (2018) 44385-44395. doi: 10.1021/acsami.8b14592
22. [22]
  Y.Y. Zhang, C.P. Zhang, D. Shao, et al., J. Hazard. Mater. 421 (2022) 126803. doi: 10.1016/j.jhazmat.2021.126803
23. [23]
  D. Shao, X.L. Zhang, Z.K. Wang, et al., Appl. Surf. Sci. 515 (2020) 146003. doi: 10.1016/j.apsusc.2020.146003
24. [24]
  D. Shao, Y.R. Wang, P. Li, et al., J. Environ. Chem. Eng. 12 (2024) 111664. doi: 10.1016/j.jece.2023.111664
25. [25]
  D. Shao, Z.K. Wang, C.P. Zhang, et al., Chin. Chem. Lett. 33 (2022) 1288-1292. doi: 10.1016/j.cclet.2021.07.061
26. [26]
  D. Shao, W. Yan, X.L. Li, et al., ACS Sustain. Chem. Eng. 3 (2015) 1777–1785. doi: 10.1021/acssuschemeng.5b00321
27. [27]
  D. Shao, Y.Y. Zhang, W. Lyu, et al., J. Hazard. Mater. 390 (2020) 122174. doi: 10.1016/j.jhazmat.2020.122174
28. [28]
  X.L. Zhang, D. Shao, W. Lyu, et al., Chem. Eng. J. 395 (2020) 125145. doi: 10.1016/j.cej.2020.125145
29. [29]
  D. Shao, W. Lyu, J.Y. Cui, et al., Chemosphere 241 (2020) 125103. doi: 10.1016/j.chemosphere.2019.125103
30. [30]
  D. Shao, W.J. Li, Z.K. Wang, et al., Sep. Purif. Technol. 301 (2022) 122008. doi: 10.1016/j.seppur.2022.122008
31. [31]
  C.A. Yang, W.P. Zhao, Z.K. Wang, et al., J. Water Process Eng. 58 (2024) 104889. doi: 10.1016/j.jwpe.2024.104889
32. [32]
  B.P. Chaplin, Environ. Sci-Proc. Imp. 16 (2014) 1182-1203.
33. [33]
  J. Qiao, Y.Z. Xiong, J. Water Process Eng. 44 (2021) 102308. doi: 10.1016/j.jwpe.2021.102308
34. [34]
  W.J. Li, G. Song, J.L. Sun, M.H. Zhou, Chem. Eng. J. 480 (2023) 148044.
35. [35]
  L. Chen, L.L. Wei, Y.F. Ru, et al., Chin. Chem. Lett. 34 (2023) 108162. doi: 10.1016/j.cclet.2023.108162
36. [36]
  N. Menzel, E. Ortel, K. Mette, R. Kraehnert, P. Strasser, ACS Catal. 3 (2013) 1324-1333. doi: 10.1021/cs4000238
37. [37]
  Y.F. Yang, T.X. Zhou, Z. Zeng, et al., J. Colloid Interface Sci. 659 (2024) 191-202. doi: 10.1016/j.jcis.2023.12.178
38. [38]
  H.J. Xiao, W. Yan, Z.K. Zhao, et al., Water Res. 221 (2022) 118732. doi: 10.1016/j.watres.2022.118732
39. [39]
  E. Brillas, C.A. Martínez-Huitle, Appl. Catal. B: Environ. 166 (2015) 603-643.
40. [40]
  D.B. Miklos, C. Remy, M. Jekel, et al., Water Res. 139 (2018) 118-131. doi: 10.1016/j.watres.2018.03.042
41. [41]
  M. Panizza, G. Cerisola, Chem. Rev. 109 (2009) 6541-6569. doi: 10.1021/cr9001319
42. [42]
  K.Q. Hou, G.W. Zhu, Y.J. Feng, Y.M. Liu, X. Quan, Chin. Chem. Lett. 35 (2024) 108704. doi: 10.1016/j.cclet.2023.108704
43. [43]
  J.N. Jing, X.C. Wang, M.H. Zhou, Water Res. 232 (2023) 119682. doi: 10.1016/j.watres.2023.119682
44. [44]
  X. Zhao, M.S. Chen, D. Wang, et al., Chin. Chem. Lett. 35 (2023) 109327.
45. [45]
  Y.F. Ren, S.J. You, Y. Wang, J.P. Yang, Y.B. Liu, Environ. Sci. Technol. 58 (2024) 2144-2152. doi: 10.1021/acs.est.3c09759
46. [46]
  H.X. Luo, S.J. Li, Z.Y. Wu, et al., Adv. Mater. 35 (2023) 2304695. doi: 10.1002/adma.202304695
47. [47]
  J.J. Zhou, Y.Q. Zhu, K.Y. Wen, et al., Environ. Sci. Technol. 58 (2024) 4824-4836. doi: 10.1021/acs.est.3c10936
48. [48]
  F.Q. Liu, H.Y. Dong, S.F. Zhong, et al., Water Res. 251 (2024) 121106. doi: 10.1016/j.watres.2024.121106
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沈阳化工大学材料科学与工程学院沈阳 110142

Attracting magnetic BDD particles onto Ti/RuO2-IrO2 by using a magnet: A novel 2.5-dimensional electrode for electrochemical oxidation wastewater treatment

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通讯作者: 陈斌, bchen63@163.com

Attracting magnetic BDD particles onto Ti/RuO₂-IrO₂ by using a magnet: A novel 2.5-dimensional electrode for electrochemical oxidation wastewater treatment