Citation: Junhua Li, Tianci Shen, Yahui Zhuang, Yu Fu, Yian Shi. Pd-Catalyzed highly regioselective migratory hydroesterification of internal olefins with formates[J]. Chinese Chemical Letters, ;2025, 36(7): 110599. doi: 10.1016/j.cclet.2024.110599 shu

Pd-Catalyzed highly regioselective migratory hydroesterification of internal olefins with formates

Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Institute of Natural and Synthetic Organic Chemistry, Changzhou University, Changzhou 213164, China

shiyian@cczu.edu.cn

Received Date: 29 July 2024
Revised Date: 23 October 2024
Accepted Date: 30 October 2024
Available Online: 2 November 2024

Figures(6)

Double bonds of internal olefins can be efficiently migrated to the terminal carbons and regioselectively hydroesterified with formates in the presence of Pd(OAc)₂ and 1,2-DTBPMB under mild reaction conditions, providing a wide variety of corresponding linear carboxylic esters bearing various functional groups in good yields and > 20:1 linear/branch ratios. The reaction is optionally simple and does not need to use CO gas and acid co-catalysts.
- Pd-Catalyzed,
- Migratory hydroesterification,
- Internal olefins,
- Olefin isomerization,
- Formates
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