Citation: Qiang Feng, Jindong Hao, Ya Hu, Rong Fu, Wei Wei, Dong Yi. Photocatalytic multi-component synthesis of ester-containing quinoxalin-2(1H)-ones using water as the hydrogen donor[J]. Chinese Chemical Letters, ;2025, 36(6): 110582. doi: 10.1016/j.cclet.2024.110582 shu

Photocatalytic multi-component synthesis of ester-containing quinoxalin-2(1H)-ones using water as the hydrogen donor

Qiang Feng ^a ,
Jindong Hao ^b ,
Ya Hu ^a ,
Rong Fu ^a ,
Wei Wei ^{b, *,} ,
Dong Yi ^{c, *,}

a.
College of Chemistry and Life Science, Institute of Functional Molecules, Chengdu Normal University, Chengdu 611130, China
b.
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China
c.
Green Pharmaceutical Technology Key Laboratory of Luzhou City, School of Pharmacy, Southwest Medical University, Luzhou 646000, China

weiweiqfnu@163.com

yidong@swmu.edu.cn

Received Date: 25 August 2024
Revised Date: 9 October 2024
Accepted Date: 23 October 2024
Available Online: 1 November 2024

Figures(7)

A convenient photocatalytic multi-component reaction of alkenes, quinoxalin-2(1H)-ones, and diazo compounds has been developed in the presence of water. A number of ester-containing quinoxalin-2(1H)-ones could be efficiently obtained in moderate to good yields at room temperature. This metal-free visible-light-driven tandem reaction was conducted through proton-coupled electron transfer (PCET) process using water as the hydrogen donor and 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) as the photocatalyst.
- Photocatalytic,
- Multi-component synthesis,
- Diazo compounds,
- Radical reaction,
- Quinoxalin-2(1H)-ones
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