Citation: Feng-Fan Yang, Yin-Kang Ding, Lin-Kai Wu, Jiayue Tian, Shuai Dou, Wenjing Wang, Linfeng Liang. A 1,3,5-triazine μ₃-bridged neutral Cu(Ⅰ) framework with enhanced stability and CO₂ capture selectivity[J]. Chinese Chemical Letters, ;2025, 36(12): 110550. doi: 10.1016/j.cclet.2024.110550 shu

A 1,3,5-triazine μ₃-bridged neutral Cu(Ⅰ) framework with enhanced stability and CO₂ capture selectivity

Feng-Fan Yang ^a ,
Yin-Kang Ding ^a ,
Lin-Kai Wu ^a ,
Jiayue Tian ^b ,
Shuai Dou ^b ,
Wenjing Wang ^c ,
Linfeng Liang ^{a, d, *,}

a.
Institute of Crystalline Materials, Shanxi University, Taiyuan 030006, China
b.
School of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450000, China
c.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
d.
Key Laboratory of Materials for Energy Conversion and Storage of Shanxi Province, Taiyuan 030006, China

jtcl@sxu.edu.cn

Received Date: 14 August 2024
Revised Date: 8 October 2024
Accepted Date: 13 October 2024
Available Online: 15 October 2024

Figures(4)

Compounds with 1,3,5-triazine ring such as melamine derivatives, known for their low cost and high stability, offer potential for affordable, stable metal organic framework (MOF) synthesis. However, reported such frameworks are facing issues like low stability and reduced porosity. To overcome such problems, we explored organic ligands with protonated nitrogen atoms on the 1,3,5-triazine ring, facilitated by introducing hydroxyl groups on carbon atoms of the triazine ring to construct MOFs. By using 5-azacytosine, we have successfully synthesized SXU-121, a neutral ultramicroporous MOF with eta-topology and high density of open Cu(Ⅰ) sites. SXU-121 features robust structural stability and significant CO₂ adsorption capacity with high selectivity over N₂ under ambient conditions. We believe SXU-121's development opens new avenues for creating a class of stable and low cost metal-triazine frameworks with potential diverse functionalities.
- 5-Azacytosine,
- Metal organic framework,
- Carbon dioxide capture,
- Crystal engineering,
- Gas adsorption and separation
1. [1]
  O. Delgado-Friedrichs, M. O'Keeffe, O.M. Yaghi, Acta Crystallogr. 62 (2006) 350–355.
2. [2]
  M. Li, D. Li, M. O'Keeffe, O.M. Yaghi, Chem. Rev. 114 (2014) 1343–1370. doi: 10.1021/cr400392k
3. [3]
  D. Zhao, D.J. Timmons, D.Q. Yuan, H.C. Zhou, Acc. Chem. Res. 44 (2011) 123–133. doi: 10.1021/ar100112y
4. [4]
  B. Bann, S.A. Miller, Chem. Rev. 58 (1958) 131–172. doi: 10.1021/cr50019a004
5. [5]
  M. Kalmutzki, M. Ströbele, F. Wackenhut, A.J. Meixner, H.J. Meyer, Angew. Chem. Int. Ed. 53 (2014) 14260–14263. doi: 10.1002/anie.201407708
6. [6]
  Y. Kamakura, P. Chinapang, S. Masaoka, et al., J. Am. Chem. Soc. 142 (2020) 27–32. doi: 10.1021/jacs.9b10436
7. [7]
  T.J. Koller, S.M.J. Endraß, M. Rösch, et al., Angew. Chem. Int. Ed. 63 (2024) e202404927.
8. [8]
  S. Tominaka, H. Hamoudi, T. Suga, et al., Chem. Sci. 6 (2015) 1465–1473.
9. [9]
  D. Sun, Y.H. Li, S.T. Wu, et al., CrystEngComm 13 (2011) 7311–7315. doi: 10.1039/c1ce05672g
10. [10]
  H.B. Zhang, M.J. Zhang, P. Lin, et al., Chem. Eur. J. 22 (2016) 1141–1145. doi: 10.1002/chem.201503561
11. [11]
  Y. Zhang, Q.F. Yang, X.P. Li, et al., CrystEngComm 22 (2020) 5690–5697. doi: 10.1039/d0ce00835d
12. [12]
  M. Eddaoudi, D.F. Sava, J.F. Eubank, K. Adil, V. Guillerm, Chem. Soc. Rev. 44 (2015) 228–249.
13. [13]
  K.C. Wang, Y.P. Li, L.H. Xie, X.Y. Li, J.R. Li, Chem. Soc. Rev. 51 (2022) 6417–6441. doi: 10.1039/d1cs00891a
14. [14]
  J.P. Zhang, Y.B. Zhang, J.B. Lin, X.M. Chen, Chem. Rev. 112 (2012) 1001–1033. doi: 10.1021/cr200139g
15. [15]
  X.W. Zhang, H. He, Y.W. Gan, et al., Angew. Chem. Int. Ed. 63 (2024) e202317648.
16. [16]
  M.H. Almatarneh, A.A.A.A. Abu-Saleh, K.M. Uddin, R.A. Poirier, P.L. Warburton, Int. J. Quantum Chem. 117 (2017) 180–189. doi: 10.1002/qua.25308
17. [17]
  M. Hatanaka, Spectrochim. Acta A 202 (2018) 87–92.
18. [18]
  Y.H. Jang, S. Hwang, S.B. Chang, J. Ku, D.S. Chung, J. Phys. Chem. A 113 (2009) 13036–13040. doi: 10.1021/jp9053583
19. [19]
  T.F. Willems, C.H. Rycroft, M. Kazi, J.C. Meza, M. Haranczyk, Microporous Mesoporous Mater. 149 (2012) 134–141.
20. [20]
  A. Spek, J. Appl. Crystallogr. 36 (2003) 7–13.
21. [21]
  P.S. Nugent, V.L. Rhodus, T. Pham, et al., J. Am. Chem. Soc. 135 (2013) 10950–10953. doi: 10.1021/ja4054948
22. [22]
  J. Peng, Z. Liu, Y. Wu, S. Xian, Z. Li, ACS Appl. Mater. Interfaces 14 (2022) 21089–21097. doi: 10.1021/acsami.2c04779
23. [23]
  Y. Shi, Y. Xie, H. Cui, et al., Chem. Engin. J. 446 (2022) 137101.
24. [24]
  C. Xiao, J.D. Tian, Q.H. Chen, M.C. Hong, Chem. Sci. 15 (2024) 1570–1610. doi: 10.1039/d3sc06076d
25. [25]
  D.D. Zhou, X.W. Zhang, Z.W. Mo, et al., EnergyChem 1 (2019) 100016.
26. [26]
  H. Alawisi, B. Li, Y. He, et al., Cryst. Growth Des. 14 (2014) 2522–2526. doi: 10.1021/cg500235j
27. [27]
  Z.L. Ma, P.X. Liu, Z.Y. Liu, et al., Inorg. Chem. 60 (2021) 6550–6558. doi: 10.1021/acs.inorgchem.1c00357
28. [28]
  P. Nugent, Y. Belmabkhout, S.D. Burd, et al., Nature 495 (2013) 80–84. doi: 10.1038/nature11893
29. [29]
  J. Peng, Z. Liu, Y. Wu, et al., ACS Appl. Mater. Interfaces 14 (2022) 21089–21097. doi: 10.1021/acsami.2c04779
30. [30]
  B. Wang, H. Huang, X.L. Lv, et al., Inorg. Chem. 53 (2014) 9254–9259. doi: 10.1021/ic5013473
31. [31]
  Z.S. Wang, M. Li, Y.L. Peng, et al., Angew. Chem. Int. Ed. 58 (2019) 16071–16076. doi: 10.1002/anie.201909046
32. [32]
  F. Yang, X. Wang, J. Tian, X. Wang, L. Liang, Processes 11 (2023) 1387. doi: 10.3390/pr11051387
33. [33]
  B. Zheng, H. Liu, Z. Wang, et al., CrystEngComm 15 (2013) 3517–3520. doi: 10.1039/c3ce26177h
1. [1]
  Shan-Qing Yang , Lu-Lu Wang , Rajamani Krishna , Bo Xing , Lei Zhou , Fei-Yang Zhang , Qiang Zhang , Yi-Long Li , Chao-Sheng Bao , Tong-Liang Hu . Efficient C₃H₆/C₃H₈ separation within a bifunctional ultramicroporous metal-organic framework with high purity and record packing density. Chinese Chemical Letters, 2025, 36(12): 110556-. doi: 10.1016/j.cclet.2024.110556
2. [2]
  Xuexia Lin , Yihui Zhou , Jiafu Hong , Xiaofeng Wei , Bin Liu , Chong-Chen Wang . Facile preparation of ZIF-8/ZIF-67-derived biomass carbon composites for highly efficient electromagnetic wave absorption. Chinese Chemical Letters, 2024, 35(9): 109835-. doi: 10.1016/j.cclet.2024.109835
3. [3]
  Na Wang , Wang Luo , Huaiyi Shen , Huakai Li , Zejiang Xu , Zhiyuan Yue , Chao Shi , Hengyun Ye , Leping Miao . Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement type hybrid perovskite system. Chinese Chemical Letters, 2024, 35(5): 108696-. doi: 10.1016/j.cclet.2023.108696
4. [4]
  Hao-Fei Ni , Jia-He Lin , Gele Teri , Qiang-Qiang Jia , Pei-Zhi Huang , Hai-Feng Lu , Chang-Feng Wang , Zhi-Xu Zhang , Da-Wei Fu , Yi Zhang . B-site ion regulation strategy enables performance optimization and multifunctional integration of hybrid perovskite ferroelectrics. Chinese Chemical Letters, 2025, 36(3): 109690-. doi: 10.1016/j.cclet.2024.109690
5. [5]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
6. [6]
  Xun Zhu , Chenchen Zhang , Yingying Li , Yin Lu , Na Huang , Dawei Wang . Degradation of perfluorooctanoic acid by inductively heated Fenton-like process over the Fe₃O₄/MIL-101 composite. Chinese Chemical Letters, 2024, 35(12): 109753-. doi: 10.1016/j.cclet.2024.109753
7. [7]
  Shanqing YANG , Lulu WANG , Qiang ZHANG , Jiajia LI , Yilong LI , Tongliang HU . A propane-selective metal-organic framework for inverse selective adsorption propane/propylene separation. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2138-2148. doi: 10.11862/CJIC.20250154
8. [8]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
9. [9]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
10. [10]
  Hongzhe GUO , Sen WANG , Lu YANG , Fucheng LIU , Jiongpeng ZHAO , Zhaoquan YAO . Highly selective acetylene capture by a pacs-type metal-organic framework constructed using metal-formate complexes as pore partition units. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2157-2164. doi: 10.11862/CJIC.20250179
11. [11]
  Yuchen Zhang , Lifeng Ding , Zhenghe Xie , Xin Zhang , Xiaofeng Sui , Jian-Rong Li . Porous sorbents for direct capture of carbon dioxide from ambient air. Chinese Chemical Letters, 2025, 36(3): 109676-. doi: 10.1016/j.cclet.2024.109676
12. [12]
  Xinbao Tong , Jiaying Liu , Yanqi Zhao , Jingjun Li , Ye Tian , Qingyi Liu , Shuiying Gao , Rong Cao . Metal-organic framework supported carbon quantum dots as white light-emitting phosphor. Chinese Chemical Letters, 2025, 36(7): 111058-. doi: 10.1016/j.cclet.2025.111058
13. [13]
  Jian Yang , Guang Yang , Zhijie Chen . Capturing carbon dioxide from air by using amine-functionalized metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(5): 100267-100267. doi: 10.1016/j.cjsc.2024.100267
14. [14]
  Xinyu Wu , Jianfeng Lu , Zihao Zhu , Suijun Liu , Herui Wen . Recent advances of metal-organic frameworks and MOF-derived materials based on p-block metal for the electrochemical reduction of carbon dioxide. Chinese Chemical Letters, 2025, 36(7): 110151-. doi: 10.1016/j.cclet.2024.110151
15. [15]
  Jiarui Wu , Gengxin Wu , Yan Wang , Yingwei Yang . Crystal Engineering Based on Leaning Towerarenes. University Chemistry, 2024, 39(3): 58-62. doi: 10.3866/PKU.DXHX202304014
16. [16]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
17. [17]
  Xinnan XIE , Boyu ZHANG , Jianxun YANG , Yi ZHONG , Younis Osama , Jianxiao YANG , Xinchun YANG . Ultrafine platinum clusters achieved by metal-organic framework derived cobalt nanoparticle/porous carbon: Remarkable catalytic performance in dehydrogenation of ammonia borane. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2095-2102. doi: 10.11862/CJIC.20250025
18. [18]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
19. [19]
  Xiaxia Xing , Xiaoyu Chen , Zhenxu Li , Xinhua Zhao , Yingying Tian , Xiaoyan Lang , Dachi Yang . Polyethylene imine functionalized porous carbon framework for selective nitrogen dioxide sensing with smartphone communication. Chinese Chemical Letters, 2024, 35(9): 109230-. doi: 10.1016/j.cclet.2023.109230
20. [20]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(11)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A 1,3,5-triazine μ3-bridged neutral Cu(Ⅰ) framework with enhanced stability and CO2 capture selectivity

Metrics

通讯作者: 陈斌, bchen63@163.com

A 1,3,5-triazine μ₃-bridged neutral Cu(Ⅰ) framework with enhanced stability and CO₂ capture selectivity