Citation: Le-Tian Zhang, Bin Xia, Nan Lu, Quan-Wen Li, Xia Zhang, Na Li, Xian-He Bu. A novel naphthalenediimide-based metal-organic framework for inkless erasable printing with ultra-long cycling performance[J]. Chinese Chemical Letters, ;2025, 36(12): 110534. doi: 10.1016/j.cclet.2024.110534 shu

A novel naphthalenediimide-based metal-organic framework for inkless erasable printing with ultra-long cycling performance

Le-Tian Zhang ^{a, 1} ,
Bin Xia ^{a, c, d, 1} ,
Nan Lu ^b ,
Quan-Wen Li ^{b, *,} ,
Xia Zhang ^a ,
Na Li ^{a, *,} ,
Xian-He Bu ^{a, b}

a.
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
b.
School of Materials Science and Engineering, Nankai University, Tianjin 300350, China
c.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China
d.
PPM Institute of Functional Materials, Poly Plastic Masterbatch (Suzhou) Co., Ltd., Suzhou 215144, China

liqw@nankai.edu.cn

lina@nankai.edu.cn

Received Date: 28 July 2024
Revised Date: 27 September 2024
Accepted Date: 8 October 2024
Available Online: 16 October 2024

Figures(4)

Photo-responsive metal-organic frameworks (MOFs) have evoked considerable attention due to their potential application in inkless printing paper. However, the poor cycling performance and low printing resolution greatly inhibit their practical application. Herein, a novel MOF based on naphthalenediimide derivate moiety, [La(H₂O)(BINDI)_0.5(DMF)₃][NO₃] (1, H₄BINDI = N, N'-bis(5-isophthalic acid)naphthalenediimide), was successfully synthesized for inkless erasable printing. This material exhibits reversible photochromic behavior and good stability. The inkless printing paper coated with 1 delivers high resolution reaching up to 0.2 mm, comparable to commercial printers. Furthermore, the stable framework and suitable reversibility enable excellent cycling performance with 197 cycles, surpassing almost all reported MOFs. This work sheds light on new opportunities in designing outstanding photochromic MOFs for ink-free printing.
- Metal-organic framework,
- Naphthalenediimide,
- Photochromism,
- Inkless printing,
- Electron transfer
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