Citation: Hong Wang, Yong Tian, Tiancheng Wu, Shun He, Jiaxi Cui, Jian Chen, Xudong Chen. Photoswitchable dual-color fluorescent polymeric nanoparticles for self-erased time-resolved information encryption and anti-counterfeiting[J]. Chinese Chemical Letters, ;2025, 36(7): 110509. doi: 10.1016/j.cclet.2024.110509 shu

Photoswitchable dual-color fluorescent polymeric nanoparticles for self-erased time-resolved information encryption and anti-counterfeiting

Hong Wang ^{a, b, 1} ,
Yong Tian ^{a, 1} ,
Tiancheng Wu ^{a, 1} ,
Shun He ^a ,
Jiaxi Cui ^c ,
Jian Chen ^{a, b, *,} ,
Xudong Chen ^{d, e}

a.
Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education, Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers, Hunan Provincial Key Lab of Advanced Materials for New Energy Storage and Conversion, Hunan Province College Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China
b.
School of Resource & Environment and Safety Engineering, Hunan University of Science and Technology, Xiangtan 411201, China
c.
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 611731, China
d.
Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory, Jieyang 515200, China
e.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

cj0066@gmail.com

Received Date: 24 July 2024
Revised Date: 23 September 2024
Accepted Date: 25 September 2024
Available Online: 18 October 2024

Figures(5)

Photoswitchable fluorescent polymeric nanoparticles were widely concerned because of their excellent features including the flexible design, easy preparation and functionalization, and thus exhibited great application potential in information encryption, anti-counterfeiting, but remained challenging in improving the security. Herein, we described a self-erased time-resolved information encryption via using photoswitchable dual-color fluorescent polymeric nanoparticles (PDFPNs) containing two fluorescence dyes (blue and red) and photochromic spiroxazine derivatives. In view of the different thermo-induced isomerization rates of photochromic spiroxazine derivatives in different flexible substrates, the decoloration rate of PDFPNs can be programmatically tuned by regulating ratio between rigid polymer and flexible polymer. Therefore, after ultraviolet light (UV) irradiation, correct information could only be recognized in preestablished time during the self-erased process. Our results indicated that PDFPNs exhibited fast photo-responsibility (2 min), high fluorescence contrast, well-pleasing photo-reversibility (> 20 times), and programmable thermo-responsiveness (24 s-6 h). We thus demonstrated their application in the self-erased time-resolved information encryption and anti-counterfeiting with high security.
- Photoswitchable dual-color fluorescence,
- Polymeric nanoparticles,
- FRET,
- Self-erasure,
- Time-resolved information encryption
1. [1]
  K. Peng, F. Lv, H. Lu, et al., Chin. Chem. Lett. 31 (2020) 755–758.
2. [2]
  A. Abdollahi, B. Ghasemi, S. Nikzaban, et al., ACS Appl. Mater. Interfaces 15 (2023) 7466–7484. doi: 10.1021/acsami.2c22532
3. [3]
  H. Wang, P. Zhang, B.P. Krishnan, et al., J. Mater. Chem. C 6 (2018) 9897–9902. doi: 10.1039/c8tc03757d
4. [4]
  Z. Quan, Q. Zhang, H. Li, S. Sun, Y. Xu, Coord. Chem. Rev. 493 (2023) 215287.
5. [5]
  W. Wan, M. -Q. Zhu, Z. Tian, A.D.Q. Li, J. Am. Chem. Soc. 137 (2015) 4312–4315. doi: 10.1021/jacs.5b01007
6. [6]
  Z. Yao, X. Wang, J. Liu, et al., Chem. Commun. 59 (2023) 2469–2472. doi: 10.1039/d2cc06707b
7. [7]
  J. Li, M. Tian, H. Xu, X. Ding, J. Guo, Part. Part. Syst. Char. 36 (2019) 1900346.
8. [8]
  S. Lin, Y. Tang, W. Kang, et al., Nat. Commun. 14 (2023) 3005.
9. [9]
  M. Yu, P. Zhang, B.P. Krishnan, et al., Adv. Funct. Mater. 28 (2018) 1804759.
10. [10]
  Y. Zhuang, X. Ren, X. Che, et al., Adv. Photon. 3 (2021) 014001.
11. [11]
  J. Tan, Q. Li, S. Meng, et al., Adv. Mater. 33 (2021) 2006781.
12. [12]
  D. Guo, X. Le, H. Shang, et al., Chin. Chem. Lett. 34 (2023) 108347.
13. [13]
  D. Feng, Q. Guo, Z. Huang, et al., Adv. Mater. 36 (2024) 2314201.
14. [14]
  Q. Wang, Z. Qi, Q. -M. Wang, et al., Adv. Funct. Mater. 32 (2022) 2208865.
15. [15]
  X. Le, H. Shang, H. Yan, et al., Angew. Chem. Int. Ed. 60 (2021) 3640–3646. doi: 10.1002/anie.202011645
16. [16]
  Z. Zou, J. Wang, Y. Sun, Q. Wang, D.H. Qu, Chin. Chem. Lett. 35 (2024) 108972.
17. [17]
  Y. Zhang, X. Zhang, Z. Feng, et al., ACS Appl. Mater. Interfaces 13 (2021) 44797–44805. doi: 10.1021/acsami.1c12647
18. [18]
  J. Zhou, D. Liu, L. Li, et al., Chin. Chem. Lett. 35 (2024) 109929.
19. [19]
  D. Li, Z. Feng, Y. Han, et al., Adv. Sci. 9 (2022) 2104790.
20. [20]
  Z. Gao, S. Qiu, F. Yan, et al., Chem. Sci. 12 (2021) 10041–10047. doi: 10.1039/d1sc03105h
21. [21]
  Y. Ma, Y. Yu, P. She, et al., Sci. Adv. 6 (2020) eaaz2386.
22. [22]
  D. Lou, Y. Sun, J. Li, et al., Angew. Chem. Int. Ed. 61 (2022) e202117066.
23. [23]
  M. Tao, X. Liang, J. Guo, et al., ACS Appl. Mater. Interfaces 13 (2021) 33574–33583. doi: 10.1021/acsami.1c09677
24. [24]
  Y. Xie, M.C. Arno, J.T. Husband, M. Torrent-Sucarrat, R.K. O'Reilly, Nat. Commun. 11 (2020) 2460.
25. [25]
  M.H. Sharifian, A.R. Mahdavian, H. Salehi-Mobarakeh, Langmuir 33 (2017) 8023–8031. doi: 10.1021/acs.langmuir.7b01869
26. [26]
  H. Wang, P. Zhang, J. Chen, et al., Sens. Actuators B: Chem. 242 (2017) 818–824.
27. [27]
  Z. Lin, H. Wang, M. Yu, et al., J. Mater. Chem. C 7 (2019) 11515–11521. doi: 10.1039/c9tc04054d
28. [28]
  T. Wu, Y. Tian, J. Wu, et al., Dyes. Pigments 212 (2023) 111119.
29. [29]
  L. Shi, L. Ding, Y. Zhang, S. Lu, Nano Today 55 (2024) 102200.
30. [30]
  Y. Wu, X. Chen, W. Wu, Small 19 (2023) 2206709.
1. [1]
  Tingting Hu , Chao Shen , Xueyan Wang , Fengbo Wu , Zhiyao He . Tumor microenvironment-sensitive polymeric nanoparticles for synergetic chemo-photo therapy. Chinese Chemical Letters, 2024, 35(11): 109562-. doi: 10.1016/j.cclet.2024.109562
2. [2]
  Chunyu Yan , Qinglong Qiao , Wei Zhou , Xuelian Zhou , Yonghui Chen , Lu Miao , Zhaochao Xu . FRET-based in vitro assay for rapid detecting of SARS-CoV-2 entry inhibitors. Chinese Chemical Letters, 2025, 36(5): 110258-. doi: 10.1016/j.cclet.2024.110258
3. [3]
  Xiaoyao Ma , Jinling Zhang , Ge Fang , He Gao , Jie Gao , Li Fu , Yuanyuan Hou , Gang Bai . Förster resonance energy transfer reveals phillygenin and swertiamarin concurrently target AKT on different binding domains to increase the anti-inflammatory effect. Chinese Chemical Letters, 2024, 35(5): 108823-. doi: 10.1016/j.cclet.2023.108823
4. [4]
  Zixi Zou , Jingyuan Wang , Yian Sun , Qian Wang , Da-Hui Qu . Controlling molecular assembly on time scale: Time-dependent multicolor fluorescence for information encryption. Chinese Chemical Letters, 2024, 35(7): 108972-. doi: 10.1016/j.cclet.2023.108972
5. [5]
  Yiling Li , Zekun Gao , Xiuxiu Yue , Minhuan Lan , Xiuli Zheng , Benhua Wang , Shuang Zhao , Xiangzhi Song . FRET-based two-photon benzo[a] phenothiazinium photosensitizer for fluorescence imaging-guided photodynamic therapy. Chinese Chemical Letters, 2024, 35(7): 109133-. doi: 10.1016/j.cclet.2023.109133
6. [6]
  Min Liu , Bin Feng , Feiyi Chu , Duoyang Fan , Fan Zheng , Fei Chen , Wenbin Zeng . An ESIPT-boosted NIR nanoprobe for ratiometric sensing of carbon monoxide via activatable aggregation-induced dual-color fluorescence. Chinese Chemical Letters, 2025, 36(5): 110043-. doi: 10.1016/j.cclet.2024.110043
7. [7]
  Yiran Tao , Chunlei Dai , Zhaoxiang Xie , Xinru You , Kaiwen Li , Jun Wu , Hai Huang . Redox responsive polymeric nanoparticles enhance the efficacy of cyclin dependent kinase 7 inhibitor for enhanced treatment of prostate cancer. Chinese Chemical Letters, 2024, 35(8): 109170-. doi: 10.1016/j.cclet.2023.109170
8. [8]
  Shuang Liang , Jianjun Yao , Dan Liu , Mengli Zhou , Yong Cui , Zhaohui Wang . Tumor-responsive covalent organic polymeric nanoparticles enhancing STING activation for cancer immunotherapy. Chinese Chemical Letters, 2025, 36(3): 109856-. doi: 10.1016/j.cclet.2024.109856
9. [9]
  Xu Qu , Pengzhao Wu , Kaixuan Duan , Guangwei Wang , Liang-Liang Gao , Yuan Guo , Jianjian Zhang , Donglei Shi . Self-calibrating probes constructed on a unique dual-emissive fluorescence platform for the precise tracking of cellular senescence. Chinese Chemical Letters, 2024, 35(12): 109681-. doi: 10.1016/j.cclet.2024.109681
10. [10]
  Wei Su , Xiaoyan Luo , Peiyuan Li , Ying Zhang , Chenxiang Lin , Kang Wang , Jianzhuang Jiang . Phthalocyanine self-assembled nanoparticles for type Ⅰ photodynamic antibacterial therapy. Chinese Chemical Letters, 2024, 35(12): 109522-. doi: 10.1016/j.cclet.2024.109522
11. [11]
  Hui Peng , Xiao Wang , Weiguo Huang , Shuiyue Yu , Linghang Kong , Qilin Wei , Jialong Zhao , Bingsuo Zou . Efficient tunable visible and near-infrared emission in Sb³⁺/Sm³⁺-codoped Cs₂NaLuCl₆ for near-infrared light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption. Chinese Chemical Letters, 2024, 35(11): 109462-. doi: 10.1016/j.cclet.2023.109462
12. [12]
  Zhixue Liu , Haiqi Chen , Lijuan Guo , Xinyao Sun , Zhi-Yuan Zhang , Junyi Chen , Ming Dong , Chunju Li . Luminescent terphen[3]arene sulfate-activated FRET assemblies for cell imaging. Chinese Chemical Letters, 2024, 35(9): 109666-. doi: 10.1016/j.cclet.2024.109666
13. [13]
  Wenbin Zhou , Yafei Gao , Xinyu Feng , Yanqing Zhang , Cong Yang , Lanxi He , Fenghe Zhang , Xiaoguang Li , Qing Li . Biomimetic nanoplatform integrates FRET-enhanced photodynamic therapy and chemotherapy for cascaded revitalization of the tumor immune microenvironment in OSCC. Chinese Chemical Letters, 2025, 36(1): 109763-. doi: 10.1016/j.cclet.2024.109763
14. [14]
  Yuwen Zhu , Xiang Deng , Yan Wu , Baode Shen , Lingyu Hang , Yuye Xue , Hailong Yuan . Formation mechanism of herpetrione self-assembled nanoparticles based on pH-driven method. Chinese Chemical Letters, 2025, 36(1): 109733-. doi: 10.1016/j.cclet.2024.109733
15. [15]
  Hao Zhang , Hao Liu , Ke Huang , Qingxiu Xia , Hongjie Xiong , Xiaohui Liu , Hui Jiang , Xuemei Wang . Ionic exchange based intracellular self-assembly of pitaya-structured nanoparticles for tumor imaging. Chinese Chemical Letters, 2025, 36(6): 110281-. doi: 10.1016/j.cclet.2024.110281
16. [16]
  Jiayin Zhou , Depeng Liu , Longqiang Li , Min Qi , Guangqiang Yin , Tao Chen . Responsive organic room-temperature phosphorescence materials for spatial-time-resolved anti-counterfeiting. Chinese Chemical Letters, 2024, 35(11): 109929-. doi: 10.1016/j.cclet.2024.109929
17. [17]
  Xiangqian Cao , Chenkai Yang , Xiaodong Zhu , Mengxin Zhao , Yilin Yan , Zhengnan Huang , Jinming Cai , Jingming Zhuang , Shengzhou Li , Wei Li , Bing Shen . Synergistic enhancement of chemotherapy for bladder cancer by photothermal dual-sensitive nanosystem with gold nanoparticles and PNIPAM. Chinese Chemical Letters, 2024, 35(8): 109199-. doi: 10.1016/j.cclet.2023.109199
18. [18]
  Wen-Jun Xia , Yong-Jiang Wang , Yun-Fei Cao , Cai Sun , Xin-Xiong Li , Yan-Qiong Sun , Shou-Tian Zheng . A luminescent folded S-shaped high-nuclearity Eu₁₉-oxo-cluster embedded polyoxoniobate for information encryption. Chinese Chemical Letters, 2025, 36(2): 110248-. doi: 10.1016/j.cclet.2024.110248
19. [19]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
20. [20]
  Sijia Zhou , Tianyi Zhou , Yuhua Hou , Wang Li , Yanfei Shen , Songqin Liu , Kaiqing Wu , Yuanjian Zhang . Recent advances in electrochemiluminescence based on polymeric luminophores. Chinese Chemical Letters, 2025, 36(5): 110284-. doi: 10.1016/j.cclet.2024.110284

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(3)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142