Citation: Peiyang Du, Ling Yuan, Tong Bao, Yamin Xi, Jiaxin Li, Yin Bi, Luli Yin, Jing Wang, Chao Liu. Facet effect of metal-organic frameworks on supporting co-catalysts for photocatalytic hydrogen peroxide production[J]. Chinese Chemical Letters, ;2025, 36(11): 110472. doi: 10.1016/j.cclet.2024.110472 shu

Facet effect of metal-organic frameworks on supporting co-catalysts for photocatalytic hydrogen peroxide production

Peiyang Du ^{a, 1} ,
Ling Yuan ^{a, 1} ,
Tong Bao ^a ,
Yamin Xi ^a ,
Jiaxin Li ^a ,
Yin Bi ^a ,
Luli Yin ^b ,
Jing Wang ^{b, *,} ,
Chao Liu ^{a, c, *,}

a.
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241, China
b.
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China
c.
State Key Laboratory of Petroleum Molecular and Process Engineering, SKLPMPE, East China Normal University, Shanghai 200062, China

jingwang@sit.edu.cn

cliu@chem.ecnu.edu.cn

Received Date: 22 July 2024
Revised Date: 27 August 2024
Accepted Date: 17 September 2024
Available Online: 19 September 2024

Figures(5)

The facet effect of metal-organic frameworks (MOF) on regulating the property of loaded co-catalysts is an important but unexplored issue in the field of photocatalysis. In this work, a series of MIL-125-NH₂ polyhedrons (MIL = Materials Institute Lavoisier) with facet exposure of {001}, {001}/{111} and {111} are synthesized and used to load Pd-based co-catalysts for photocatalytic oxygen reduction reaction (ORR) toward H₂O₂ production. The different facets with distinct chemical environments (Ti-O clusters on {111} facets and carboxyl ligands on {001} facets) result in the selective loading of Pd⁰ and PdO dominated cocatalysts on {001} and {111} facets, respectively. The {001}/{111} co-exposed MIL-125-NH₂ thus enables the spatially separated loading of Pd⁰ and PdO dual cocatalysts respectively. Pd⁰ efficiently traps the photoexcited electrons and PdO trends to capture the holes, collaboratively promoting the directional separation of photogenerated electron-hole pairs. As a result, the photocatalytic ORR activity is significantly enhanced with a H₂O₂ production rate of 128.6 mmol L^-1 g^-1 h^-1, superior than pristine and single cocatalyst modified MIL-125-NH₂ samples. Our findings provide new insight into the design of high-performance photocatalysts.
- Facet effect,
- Photocatalyst,
- Co-catalyst,
- MOF,
- H₂O₂ production
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