Citation: Qiang-Qiang Jia, Jia-Qi Luo, Zhi-Yu Xue, Jing-Song Tang, Wen-Qiang Qiu, Chang-Feng Wang, Zhi-Xu Zhang, Hai-Feng Lu, Yi Zhang, Da-Wei Fu. Enhanced output power density of PVDF/LM composite for piezoelectric sensor[J]. Chinese Chemical Letters, ;2025, 36(11): 110471. doi: 10.1016/j.cclet.2024.110471 shu

Enhanced output power density of PVDF/LM composite for piezoelectric sensor

Qiang-Qiang Jia ^{a, 1} ,
Jia-Qi Luo ^{a, 1} ,
Zhi-Yu Xue ^a ,
Jing-Song Tang ^a ,
Wen-Qiang Qiu ^a ,
Chang-Feng Wang ^a ,
Zhi-Xu Zhang ^a ,
Hai-Feng Lu ^{a, *,} ,
Yi Zhang ^{a, *,} ,
Da-Wei Fu ^{a, b, *,}

a.
Institute for Science and Applications of Molecular Ferroelectrics, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321004, China
b.
Ordered Matter Science Research Center, Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, China

luhaifeng@zjnu.edu.cn

yizhang1980@seu.edu.cn

dawei@seu.edu.cn

Received Date: 9 July 2024
Revised Date: 3 September 2024
Accepted Date: 17 September 2024
Available Online: 18 September 2024

Figures(5)

Poly(vinylidene fluoride) (PVDF) based piezoelectric materials have received tremendous scientific attention for many decades. However, the high output power density remains a significant challenge and an area of intense interest. Herein, we present a piezoelectric sensor with high output power density by incorporating liquid metal (LM) microdroplets into PVDF piezoelectric substrate. Remarkably, the LM/PVDF composite showed the β-phase content above 90% and the output power density is enhanced to 353 µW/cm², nearly 1000 times higher than that of pure PVDF materials and significantly surpassing other PVDF-based composite materials. These exceptional performances are attributed to two key factors: The formation of a liquid-solid/electric-dielectric interface between the LM and PVDF, and the incorporation of the LM's outstanding charge transfer capability. This work might present an effective strategy for advancing the utilization of PVDF-based piezoelectric materials in compelling applications within the realm of intelligent wearable electronics.
- PVDF,
- Liquid metal,
- Piezoelectric,
- Ferroelectric,
- Flexible self-powered sensing
1. [1]
  P. Martins, A.C. Lopes, S. Lanceros-Mendez, Prog. Polym. Sci. 39 (2014) 683–706.
2. [2]
  Z.X. Zhang, H.F. Ni, J.S. Tang, et al., J. Am. Chem. Soc. 146 (2024) 27443–27450. doi: 10.1021/jacs.4c07268
3. [3]
  C.M. Costa, V.F. Cardoso, P. Martins, et al., Chem. Rev. 123 (2023) 11392–11487. doi: 10.1021/acs.chemrev.3c00196
4. [4]
  Q.Q. Jia, G. Teri, J.Q. Luo, et al., J. Am. Chem. Soc. 146 (2024) 21120. doi: 10.1021/jacs.4c06929
5. [5]
  C.Y. Su, Z.X. Zhang, J. Yao, et al., Chin. Chem. Lett. 34 (2023) 107442.
6. [6]
  J. Hu, H. Qian, S. Han, P. Zhang, Y. Lu, Nano-Micro Lett 16 (2024) 274.
7. [7]
  Q. Xu, Z. Wang, J. Zhong, et al., Adv. Funct. Mater. 33 (2023) 1383–1391. doi: 10.3390/plants12061383
8. [8]
  Y.Y. Yu, P.Z. Huang, Y.Z. Wang, et al., Chin. Chem. Lett. 32 (2021) 3558–3561.
9. [9]
  C.F. Wang, Y. Yang, Y. Hu, et al., Angew. Chem. Int. Ed. 63 (2024) e202413726. doi: 10.1002/anie.202413726
10. [10]
  S. Liu, J. Liao, X. Huang, et al., Nano-Micro Lett. 15 (2023) 131. doi: 10.3390/rs16010131
11. [11]
  H. Peng, Q. Liu, Y. Liu, Y. Lu, W. Liao, Chin. Chem. Lett. 34 (2023) 107980.
12. [12]
  L. Zhou, L. Zhu, T. Yang, et al., Nano-Micro Lett. 14 (2021) 30.
13. [13]
  C.F. Wang, N. Wang, C. Shi, et al., Chin. Chem. Lett. 34 (2023) 107774.
14. [14]
  Q.Q. Jia, T. Shao, L. Tong, et al., Chin. Chem. Lett. 34 (2023) 107539.
15. [15]
  P.Z. Huang, H.F. Ni, C.Y. Su, et al., CCS Chem. 5 (2022) 1942–1951.
16. [16]
  L. Pan, Y. Wang, Q. Jin, et al., Chem. Eng. J. 479 (2024) 147742.
17. [17]
  Y.Q. Zhu, H.H. Chen, L. Wang, Chin. Chem. Lett. 35 (2024) 108884.
18. [18]
  Z. Song, S. Yu, K. Wang, et al., J. Rare Earths 41 (2023) 365.
19. [19]
  C. Gao, Q. You, J. Huang, et al., Nano-Micro Lett. 16 (2024) 123.
20. [20]
  H. Kim, B. Rigo, G. Wong, Y.J. Lee, W.H. Yeo, Nano-Micro Lett. 16 (2023) 52.
21. [21]
  K. Men, H. Liu, X. Wang, et al., J. Rare Earths 41 (2023) 434.
22. [22]
  H.F. Ni, J.H. Lin, G. Teri, et al., Chin. Chem. Lett. 36 (2025) 109690. doi: 10.1016/j.cclet.2024.109690
23. [23]
  L. Gao, B.L. Hu, L. Wang, et al., Science 381 (2023) 540–544. doi: 10.1126/science.adh2509
24. [24]
  R. Pandey, G. Sb, S. Grover, et al., ACS Energy Lett. 4 (2019) 1004–1011. doi: 10.1021/acsenergylett.9b00323
25. [25]
  Y.S. Xue, Z.X. Zhang, P.P. Shi, et al., Chin. Chem. Lett. 32 (2021) 539–542.
26. [26]
  Y. Li, M.H. Xu, Y.S. Xia, et al., Chem. Eng. J. 388 (2020) 124205.
27. [27]
  A. Ferri, S. Barrau, R. Bourez, et al., Compos. Sci. Technol. 186 (2020) 107914.
28. [28]
  J. Yang, Q. Chen, F. Xu, et al., Adv. Electron. Mater. 6 (2020) 2000578.
29. [29]
  L. Lu, W. Ding, J. Liu, et al., Nano Energy 78 (2020) 105251.
30. [30]
  M.T. Chorsi, E.J. Curry, H.T. Chorsi, et al., Adv. Mater. 31 (2018) 1802084.
31. [31]
  Y. Li, W. Feng, L. Meng, et al., Mater. Des. 199 (2021) 09415.
32. [32]
  J. Fang, H. Niu, H. Wang, et al., Energy Environ. Sci. 6 (2013) 2196–2202. doi: 10.1039/c3ee24230g
33. [33]
  Z. Gao, X. Xiao, A.D. Carlo, et al., Adv. Funct. Mater. 33 (2023) 2214265.
34. [34]
  Y.M. Yousry, K. Yao, A.M. Mohamed, et al., Adv. Funct. Mater. 30 (2020) 1910592.
35. [35]
  X. Du, Z. Zhou, Z. Zhang, et al., J. Adv. Ceram. 11 (2022) 331–344. doi: 10.1007/s40145-021-0537-3
36. [36]
  Z. Liu, S. Zhang, J. Li, et al., Appl. Catal. B: Environ. 158 (2014) 11–19.
37. [37]
  Y.M. Yousry, K. Yao, S. Chen, et al., Adv. Electron. Mater. 4 (2018) 1700562.
38. [38]
  Y. Huang, G. Rui, Q. Li, et al., Nat. Commun. 12 (2021) 675. doi: 10.1111/jfd.13329
39. [39]
  Y.Y. Zhang, J.Q. Luo, Y. Han, et al., Chin. Chem. Lett. 36 (2024) 109530. doi: 10.1016/j.cclet.2024.109530
40. [40]
  Y. Su, W. Li, X. Cheng, et al., Nat. Commun. 13 (2022) 4867.
41. [41]
  S. Supriya, J. Rare Earths 41 (2023) 331.
42. [42]
  P. Chen, C. Cheng, X. Yang, et al., ACS Nano 17 (2023) 25625–25637. doi: 10.1021/acsnano.3c10227
43. [43]
  R.W. Style, R. Tutika, J.Y. Kim, et al., Adv. Funct. Mater. 31 (2020) 2005804.
44. [44]
  H. Li, S. Lim, J. Mater. Chem. A 10 (2022) 14894–14905. doi: 10.1039/d2ta02276a
45. [45]
  J. Liu, S. Zeng, M. Zhang, et al., Adv. Sci. 10 (2023) 2304096.
46. [46]
  T. Daeneke, K. Khoshmanesh, N. Mahmood, et al., Chem. Soc. Rev. 47 (2018) 4073–4111. doi: 10.1039/c7cs00043j
47. [47]
  M. Zhang, S. Yao, W. Rao, et al., Mater. Sci. Eng. R: Rep. 138 (2019) 1–35.
48. [48]
  Y. He, J. You, M.D. Dickey, et al., Adv. Funct. Mater. 25 (2023) 2309614.
49. [49]
  X. Guan, B. Xu, J. Gong, Nano Energy 70 (2020) 104516.
50. [50]
  W. Tang, B.D. Chen, Z.L. Wang, Adv. Funct. Mater. 29 (2019) 1901069.
51. [51]
  G. Huang, A.A. Khan, M.M. Rana, et al., ACS Energy Lett. 6 (2021) 16–23. doi: 10.1021/acsenergylett.0c02200
52. [52]
  B. Joshi, T. Kim, W. Lim, et al., J. Mater. Sci. Technol. 177 (2024) 103–113.
53. [53]
  R. Ding, X. Zhang, G. Chen, et al., Nano Energy 37 (2017) 126–135.
54. [54]
  S.H. Wankhade, S. Tiwari, A. Gaur, et al., Energy Rep. 6 (2020) 358–364.
55. [55]
  S. Tiwari, A. Gaur, C. Kumar, et al., Energy 171 (2019) 485–492.
56. [56]
  M.M. Rana, A.A. Khan, G. Huang, et al., ACS Appl. Mater. Interfaces 12 (2020) 47503–47512. doi: 10.1021/acsami.0c12874
57. [57]
  A.A. Khan, M.M. Rana, G. Huang, et al., J. Mater. Chem. A 8 (2020) 13619–13629. doi: 10.1039/d0ta03416a
58. [58]
  S. Kang, S.H. Kim, H.B. Lee, et al., Nano Energy 99 (2022) 107386.
59. [59]
  D. Bhattacharya, S. Bayan, R.K. Mitra, et al., Nanoscale 13 (2021) 15819–15829. doi: 10.1039/d1nr03808g
1. [1]
  Mengchen Liu , Yufei Zhang , Yi Xiao , Yang Wei , Meichen Bi , Huaide Jiang , Yan Yu , Shenghong Zhong . High stretchability and toughness of liquid metal reinforced conductive biocompatible hydrogels for flexible strain sensors. Chinese Journal of Structural Chemistry, 2025, 44(3): 100518-100518. doi: 10.1016/j.cjsc.2025.100518
2. [2]
  Changsheng Yang , Yuhang Jiang , Panpan Yu , Shiguo Han , Shihai You , Zeng-Kui Zhu , Zihao Yu , Junhua Luo . Realizing self-powered broadband photodetection with low detection limit in a trilayered perovskite ferroelectric. Chinese Chemical Letters, 2025, 36(8): 110218-. doi: 10.1016/j.cclet.2024.110218
3. [3]
  Zheng Zhang , Lei Shi , Bin Wang , Jingyuan Qu , Xiaoling Wang , Tao Wang , Qitao Jiang , Wuhong Xue , Xiaohong Xu . Epitaxial growth of full-vdW α-In₂Se₃/MoS₂ heterostructures for all-in-one sensing and memory-computing artificial visual system. Chinese Chemical Letters, 2025, 36(3): 109687-. doi: 10.1016/j.cclet.2024.109687
4. [4]
  Hao-Fei Ni , Jia-He Lin , Gele Teri , Qiang-Qiang Jia , Pei-Zhi Huang , Hai-Feng Lu , Chang-Feng Wang , Zhi-Xu Zhang , Da-Wei Fu , Yi Zhang . B-site ion regulation strategy enables performance optimization and multifunctional integration of hybrid perovskite ferroelectrics. Chinese Chemical Letters, 2025, 36(3): 109690-. doi: 10.1016/j.cclet.2024.109690
5. [5]
  Biao Fang , Runwei Mo . PVDF-based solid-state battery. Chinese Journal of Structural Chemistry, 2024, 43(8): 100347-100347. doi: 10.1016/j.cjsc.2024.100347
6. [6]
  Saadullah Khattak , Hong-Tao Xu , Jianliang Shen . Bio-electronic bandage: Self-powered performances to accelerate intestinal wound healing. Chinese Chemical Letters, 2024, 35(12): 110210-. doi: 10.1016/j.cclet.2024.110210
7. [7]
  Qinghong Pan , Huafang Zhang , Qiaoling Liu , Donghong Huang , Da-Peng Yang , Tianjia Jiang , Shuyang Sun , Xiangrong Chen . A self-powered cathodic molecular imprinting ultrasensitive photoelectrochemical tetracycline sensor via ZnO/C photoanode signal amplification. Chinese Chemical Letters, 2025, 36(1): 110169-. doi: 10.1016/j.cclet.2024.110169
8. [8]
  Xin Dong , Tianqi Chen , Jing Liang , Lei Wang , Huajie Wu , Zhijin Xu , Junhua Luo , Li-Na Li . Structure design of lead-free chiral-polar perovskites for sensitive self-powered X-ray detection. Chinese Journal of Structural Chemistry, 2024, 43(6): 100256-100256. doi: 10.1016/j.cjsc.2024.100256
9. [9]
  Qianxi Wang , Xiaoqi Li , Fen Zhang , Qingyin Wei , Zengshan Yue , Xiantan Lin , Yicong Lv , Xitao Liu , Junhua Luo . Mixed cation ordering scaffold polar 2D halide perovskite semiconductor for self-powered polarization-sensitive photodetection. Chinese Chemical Letters, 2025, 36(10): 110405-. doi: 10.1016/j.cclet.2024.110405
10. [10]
  Yuqing Zhu , Haohao Chen , Li Wang , Liqun Ye , Houle Zhou , Qintian Peng , Huaiyong Zhu , Yingping Huang . Piezoelectric materials for pollutants degradation: State-of-the-art accomplishments and prospects. Chinese Chemical Letters, 2024, 35(4): 108884-. doi: 10.1016/j.cclet.2023.108884
11. [11]
  Neng Shi , Haonan Jia , Jixiang Zhang , Pengyu Lu , Chenglong Cai , Yixin Zhang , Liqiang Zhang , Nongyue He , Weiran Zhu , Yan Cai , Zhangqi Feng , Ting Wang . Accurate expression of neck motion signal by piezoelectric sensor data analysis. Chinese Chemical Letters, 2024, 35(9): 109302-. doi: 10.1016/j.cclet.2023.109302
12. [12]
  Cunjun Li , Wencong Liu , Xianlei Chen , Liang Li , Shenyu Lan , Mingshan Zhu . Adsorption and activation of peroxymonosulfate on BiOCl for carbamazepine degradation: The role of piezoelectric effect. Chinese Chemical Letters, 2024, 35(10): 109652-. doi: 10.1016/j.cclet.2024.109652
13. [13]
  Lingna Wang , Chenxin Tian , Ruobin Dai , Zhiwei Wang . Eco-friendly regeneration of end-of-life PVDF membrane with triethyl phosphate: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(9): 109356-. doi: 10.1016/j.cclet.2023.109356
14. [14]
  Shunshun Jiang , Ji Zhang , Jing Wang , Shan-Tao Zhang . Excellent energy storage properties in non-stoichiometric Bi_0.5Na_0.5TiO₃-based relaxor ferroelectric ceramics. Chinese Chemical Letters, 2024, 35(7): 108955-. doi: 10.1016/j.cclet.2023.108955
15. [15]
  Zhouze Chen , Yujie Yan , Jun Luo , Pengnian Shan , Changyu Lu , Feng Guo , Weilong Shi . Piezoelectric effect synergistically boosted NIR-driven photothermal-assisted photocatalytic hydrogen evolution. Chinese Chemical Letters, 2025, 36(10): 111302-. doi: 10.1016/j.cclet.2025.111302
16. [16]
  Jian Wang , Baohui Wang , Pin Ma , Yifei Zhang , Honghong Gong , Biyun Peng , Sen Liang , Yunchuan Xie , Hailong Wang . Regulation of uniformity and electric field distribution achieved highly energy storage performance in PVDF-based nanocomposites via continuous gradient structure. Chinese Chemical Letters, 2025, 36(4): 109714-. doi: 10.1016/j.cclet.2024.109714
17. [17]
  Sheng Zhao , Junjie Lu , Bifu Sheng , Siying Zhang , Hao Li , Jizhang Chen , Xiang Han . High-performance room temperature solid-state lithium battery enabled by PP-PVDF multilayer composite electrolyte. Chinese Chemical Letters, 2025, 36(6): 110008-. doi: 10.1016/j.cclet.2024.110008
18. [18]
  Qinyu Zhao , Yunchao Zhao , Songjing Zhong , Zhaoyang Yue , Zhuoheng Jiang , Shaobo Wang , Quanhong Hu , Shuncheng Yao , Kaikai Wen , Linlin Li . Urchin-like piezoelectric ZnSnO₃/Cu₃P p-n heterojunction for enhanced cancer sonodynamic therapy. Chinese Chemical Letters, 2024, 35(12): 109644-. doi: 10.1016/j.cclet.2024.109644
19. [19]
  Ning Zhang , Mengjie Qin , Jiawen Zhu , Xuejing Lou , Xiao Tian , Wende Ma , Youmei Wang , Minghua Lu , Zongwei Cai . Thickness-controllable synthesis of metal-organic framework based hollow nanoflowers with magnetic core via liquid phase epitaxy for phosphopeptides enrichment. Chinese Chemical Letters, 2025, 36(4): 110177-. doi: 10.1016/j.cclet.2024.110177
20. [20]
  Shuangliang Xie , Yuyue Chen , Qing He , Liang Chen , Jikun Yang , Shiqing Deng , Yimei Zhu , He Qi . Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO₃-based lead-free ceramics for high-efficiency large-capacitive energy storage. Chinese Chemical Letters, 2024, 35(7): 108871-. doi: 10.1016/j.cclet.2023.108871

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(21)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142