Citation: Shengyong Liu, Hui Li, Wei Zhang, Yan Zhang, Yan Dong, Wei Tian. Multiple host-guest and metal coordination interactions induce supramolecular assembly and structural transition[J]. Chinese Chemical Letters, ;2025, 36(6): 110465. doi: 10.1016/j.cclet.2024.110465 shu

Multiple host-guest and metal coordination interactions induce supramolecular assembly and structural transition

Shengyong Liu ^a ,
Hui Li ^{a, *,} ,
Wei Zhang ^a ,
Yan Zhang ^a ,
Yan Dong ^a ,
Wei Tian ^{b, *,}

a.
Jiangxi Province Key Laboratory of Functional Crystalline Materials Chemistry, School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
b.
Shaanxi Key Laboratory of Macromolecular Science and Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an 710072, China

lh@jxust.edu.cn

happytw_3000@nwpu.edu.cn

Received Date: 28 June 2024
Revised Date: 1 September 2024
Accepted Date: 13 September 2024
Available Online: 15 September 2024

Figures(8)

Three monomers, namely A2, B2, and GH, were designed and synthesized. By utilizing double host-guest interactions, the monomers A2+B2+GH underwent self-assembly to form a supramolecular linear polymer (SLP) at high concentrations. Long fibers could be pulled from the concentrated SLP solution. Upon the addition of PdCl₂(PhCN)₂ into the SLP solution, a structural transformation occurred from SLP to a supramolecular crosslinked polymer (SCP) through metal coordination interaction. This transformation induced fluorescence quenching, test paper strips for ion detection experiment confirmed that the SLP had good detection ability for Pd²⁺. Furthermore, the SCP underwent a transformation into a gel when the concentration exceeded 145 mmol/L. The SCP gel demonstrated sensitivity to different stimuli, such as K⁺ ions and changes in temperature, accompanied by a reversible transition between sol and gel states. Additionally, rheological analyses indicated that the gel possessed favorable self-healing properties.
- Self-assembly,
- Supramolecular chemistry,
- Macrocycles,
- Host-guest interaction,
- Metal coordination
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