Citation: Ying Chen, Lun Li, Guohao Han, Ren Liu, Guanghui An, Yi Zhu. Macromolecular coumarin sulfonium salt with side chain effect constructed by copolymerization strategy for free radical, cationic, and hybrid photopolymerizations[J]. Chinese Chemical Letters, ;2025, 36(7): 110458. doi: 10.1016/j.cclet.2024.110458 shu

Macromolecular coumarin sulfonium salt with side chain effect constructed by copolymerization strategy for free radical, cationic, and hybrid photopolymerizations

Ying Chen ^a ,
Lun Li ^a ,
Guohao Han ^a ,
Ren Liu ^a ,
Guanghui An ^{c, *,} ,
Yi Zhu ^{a, b, *,}

a.
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China
b.
State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai 200433, China
c.
School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China

chemagh@163.com

zhuyi@jiangnan.edu.cn

Received Date: 24 June 2024
Revised Date: 30 August 2024
Accepted Date: 13 September 2024
Available Online: 14 September 2024

Figures(5)

Developing high-efficient, multi spectral applicable one-component macrophotoinitiators (Macro-PIs) with excellent performance that can simultaneously initiate cationic polymerization (CP), free radical polymerization (FRP), and hybrid polymerization (HP) has been a charming research direction. Herein, we synthesized a novel cationic macro-PI (P-CSS) by copolymerizing polymerizable coumarin sulfonium salt (CSS) and methyl methacrylate (MMA). Photochemical and photophysical investigations indicated that the extraordinary absorption ability and the 50 nm redshift of P-CSS may be due to chromophores aggregating on the side chain. Photopolymerization kinetics studies established that P-CSS has effective initiating ability for FRP and CP both under LED@365, 405 nm and under Laser@980 nm (with upconversion particles, UCPs). The migration stability experiments showed that the migration rate of P-CSS in trimethylolpropane triacrylate (TMTPA) polymer is 1.25% of CSS, and in 3, 4-epoxycyclohexylmethyl-3, 4-epoxycyclohexanecarboxylate (EPOX) polymer is 1.96%. These results indicate the great potential of P-CSS in preparing biosafety and environmentally friendly polymers for packaging and biological materials.
- Macrophotoinitiator,
- Photopolymerization,
- Low migration,
- Sulfonium salt,
- Near-infrared light
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