Citation: Xiaojuan Lv, Yuting Dong, Hongliang Huang, Dariusz W. Szczepanik, Naoki Aratani, Takahisa Ikeue, Feng Chen, Tao Zhang, Fengxian Qiu, Toshiharu Teranishi, Songlin Xue. Local aromatic ring cleaves the global aromatic ring in hexaphyrin(2.1.2.1.2.1)[J]. Chinese Chemical Letters, ;2025, 36(7): 110435. doi: 10.1016/j.cclet.2024.110435 shu

Local aromatic ring cleaves the global aromatic ring in hexaphyrin(2.1.2.1.2.1)

Xiaojuan Lv ^a ,
Yuting Dong ^a ,
Hongliang Huang ^{b, *,} ,
Dariusz W. Szczepanik ^c ,
Naoki Aratani ^d ,
Takahisa Ikeue ^e ,
Feng Chen ^a ,
Tao Zhang ^a ,
Fengxian Qiu ^{a, *,} ,
Toshiharu Teranishi ^{f, *,} ,
Songlin Xue ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
b.
School of Chemical Engineering and Technology, Tiangong University, Tianjin 300387, China
c.
Guminski Department of Theoretical Chemistry, Faculty of Chemistry, Jagiellonian University, Kraków 30-387, Poland
d.
Division of Materials Science, Nara Institute of Science and Technology, Nara 630-0192, Japan
e.
Department of Materials Chemistry, Graduate School of Natural Science and Technology, Shimane University, Shimane 690-8504, Japan
f.
Graduate School of Science and Institute for Chemical Research, Kyoto University, Kyoto 611-0011, Japan

huanghongliang@tiangong.edu.cn

fxqiu@ujs.edu.cn

teranisi@scl.kyoto-u.ac.jp

slxue@ujs.edu.cn

Received Date: 19 June 2024
Revised Date: 28 August 2024
Accepted Date: 8 September 2024
Available Online: 10 September 2024

Figures(4)

Novel benzo-bridged hexaphyrin(2.1.2.1.2.1) and its copper complex were synthesized. Single-crystal structures showed typical figure-of-eight Hückel topologies. NMR, NICS, HOMA, ACID, and EDDB analysis supported their non-aromatic properties owning to the strong local aromatic benzo rings cutting the global aromatic ring of the benzo-bridged figure-of-eight hexaphyrin(2.1.2.1.2.1). The redox properties and degenerate HOMOs and LUMOs levels indicate multielectron donating and accepting abilities.
- Local aromaticity,
- Global aromaticity,
- Hexaphyrin(2.1.2.1.2.1),
- Cleavage,
- Multielectron,
- DFT calculation
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沈阳化工大学材料科学与工程学院沈阳 110142