Citation: Chunwei Lei, Jian Li, Bo Xu, Yu Xie, Yun Ling, Juhua Luo, Wei Zhang. Synthesis of Ni/MnO/C nano-microspheres with synergistic effects of dielectric and magnetic loss for efficient microwave absorption[J]. Chinese Chemical Letters, ;2025, 36(7): 110419. doi: 10.1016/j.cclet.2024.110419 shu

Synthesis of Ni/MnO/C nano-microspheres with synergistic effects of dielectric and magnetic loss for efficient microwave absorption

Chunwei Lei ^{a, 1} ,
Jian Li ^{a, 1} ,
Bo Xu ^a ,
Yu Xie ^a,, ,
Yun Ling ^a ,
Juhua Luo ^b,, ,
Wei Zhang ^c,,

a.
School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China
b.
School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China
c.
School of Ecology and Environment, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: Yu Xie, xieyu_121@163.com Juhua Luo, ljh@ycit.edu.cn Wei Zhang, zhangwei88@zzu.edu.cn

xieyu_121@163.com

ljh@ycit.edu.cn

zhangwei88@zzu.edu.cn

Received Date: 5 April 2024
Revised Date: 27 July 2024
Accepted Date: 5 September 2024
Available Online: 6 September 2024

Figures(8)

NiMn-MOF was prepared via one-step hydrothermal method, and then Ni/MnO/C composites were synthesized by high-temperature pyrolysis. The findings indicate that the sample acquired at the pyrolysis temperature of 700 ℃ demonstrate superior microwave absorption capabilities. The minimum reflection value achieves -19.2 dB at a thickness of 1.4 mm, and the effective absorption bandwidth extends to 5.04 GHz at a mere 1.6 mm. The exceptional microwave absorption proficiency can be ascribed to the multiple reflections and scattering generated by the material's unique porous spherical structure, optimized impedance matching, suitable conduction loss, rich interfacial and dipole polarization, and magnetic loss. This study presents a straightforward procedural technique for the fabrication of effective composite absorbers.
- Magnetic-dielectric synergy,
- Heterogeneous interface engineering,
- Impedance matching,
- Microwave absorption
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