Citation: Mufan Cao, Long Pan, Yaping Wang, Xianwei Sui, Xiong Xiong Liu, Shengfa Feng, Pengcheng Yuan, Min Gao, Jiacheng Liu, Song-Zhu Kure-Chu, Takehiko Hihara, Yang Zhou, Zheng-Ming Sun. Mechanical-durable and humidity-resistant dry-processed halide solid-state electrolyte films for all-solid-state battery[J]. Chinese Chemical Letters, ;2025, 36(6): 110391. doi: 10.1016/j.cclet.2024.110391 shu

Mechanical-durable and humidity-resistant dry-processed halide solid-state electrolyte films for all-solid-state battery

Mufan Cao ^{a, 1} ,
Long Pan ^{a, 1,} ,
Yaping Wang ^a ,
Xianwei Sui ^b ,
Xiong Xiong Liu ^a ,
Shengfa Feng ^a ,
Pengcheng Yuan ^a ,
Min Gao ^a ,
Jiacheng Liu ^c ,
Song-Zhu Kure-Chu ^c ,
Takehiko Hihara ^c ,
Yang Zhou ^{d, *,} ,
Zheng-Ming Sun ^{a, *,}

a.
Key Laboratory of Advanced Metallic Materials of Jiangsu Province, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China
b.
Daikin Fluorochemicals (China) Co., Ltd., Shenzhen 518129, China
c.
Department of Materials Function and Design, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, Aichi 466-8555, Japan
d.
Jiangsu Key Laboratory of Construction Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China

panlong@seu.edu.cn

tomaszy@seu.edu.cn

zmsun@seu.edu.cn

Received Date: 2 June 2024
Revised Date: 2 August 2024
Accepted Date: 29 August 2024
Available Online: 31 August 2024

Figures(4)

Halide solid-state electrolytes (HSSEs) with excellent ionic conductivity and high voltage stability are promising for all-solid-state Li-ion batteries (ASSLBs). However, they suffer from poor processability, mechanical durability and humidity stability, hindering their large-scale applications. Here, we introduce a dry-processing fibrillation strategy using hydrophobic polytetrafluoroethylene (PTFE) binder to encapsulate Li₃InCl₆ (LIC) particles (the most representative HSSE). By manipulating the fibrillating process, only 0.5 wt% PTFE is sufficient to prepare free-standing LIC-PTFE (LIC-P) HSSEs. Additionally, LIC-P demonstrates excellent mechanical durability and humidity resistance. They can maintain their shapes after being exposed to humid atmosphere for 30 min, meanwhile still exhibit high ionic conductivity of > 0.2 mS/cm at 25 ℃. Consequently, the LIC-P-based ASSLBs deliver a high specific capacity of 126.6 mAh/g at 0.1 C and long cyclability of 200 cycles at 0.2 C. More importantly, the ASSLBs using moisture-exposed LIC-P can still operate properly by exhibiting a high capacity-retention of 87.7% after 100 cycles under 0.2 C. Furthermore, for the first time, we unravel the LIC interfacial morphology evolution upon cycling because the good mechanical durability enables a facile separation of LIC-P from ASSLBs after testing.
- Halide solid-state electrolytes,
- Dry-process,
- Humidity resistance,
- Mechanical durability,
- All solid-state battery
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