Citation: Hong Yao, Feixiang Yang, Jianpeng Hu, Wenyu Cao, Shuning Qin, Tai-Bao Wei, Bingbing Shi, Qi Lin. Ultralong room temperature phosphorescence and broad color-tunability persistent luminescence via new strategy[J]. Chinese Chemical Letters, ;2025, 36(6): 110375. doi: 10.1016/j.cclet.2024.110375 shu

Ultralong room temperature phosphorescence and broad color-tunability persistent luminescence via new strategy

Key Laboratory of Eco-Functional Polymer Materials of the Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

yhxbz@126.com

linqi2004@126.com

Received Date: 30 May 2024
Revised Date: 17 August 2024
Accepted Date: 26 August 2024
Available Online: 27 August 2024

Figures(6)

Pure organic materials with ultralong room-temperature phosphorescence (RTP) and persistent luminescence in broad color gamut exhibit tremendous potential and broad application prospects due to their unique optical properties. This article proposes a simple strategy, polyatomic synergistic effect, to endow persistent luminescent materials with ultralong lifetime and broad color-tunability through polyatomic synergistic effect and non-traditional phosphorescence resonance energy transfer (PRET). By leveraging the polyatomic synergistic effect to enhance the intersystem crossing (ISC) in bibenzimidazole (BBI) derivatives and suppress the non-radiative transition process, ultralong persistent room-temperature phosphorescence has been successfully achieved after incorporating BBI-Cl-M into poly(methyl methacrylate) (PMMA) to form a rigid matrix(BBI-Cl-M@PMMA). Specifically, the ester functionalized bibenzimidazole with modified chlorine on molecular skeleton (BBI-Cl-M) demonstrates a remarkable phosphorescent lifetime (τ_p) of up to 256.4 ms. In addition, the behaviors and mechanism of RTP via polyatomic synergistic effect have been further understood by theoretical calculation and single crystal analysis. Subsequently, utilizing BBI-Cl-M as the energy donor and Rhodamine B (RB) as the energy acceptor, persistent and multicolor organic afterglow covering from green to red has been realized successfully by simply regulating the doping composition and concentration of PRET systems. These RTP materials have also been applied in underwater afterglow emission and multilevel anti-counterfeiting technology successfully.
- Polyatomic synergistic effect,
- RTP,
- PRET,
- Multilevel anti-counterfeiting,
- Underwater phosphorescence
1. [1]
  X. Wang, G. Pan, H. Ren, et al., Angew. Chem. Int. Ed. 61 (2021) E202114264.
2. [2]
  Y. Yan, C. Liu, J. Fan, et al., Research. 6 (2023) 0241. doi: 10.34133/research.0241
3. [3]
  L. Huang, C. Qian, Z. Ma, Chem. Eur. J. 26 (2020) 11914-11930. doi: 10.1002/chem.202000526
4. [4]
  G. Wang, Z. Wang, B. Ding, et al., Chin. Chem. Lett. 32 (2021) 3039-3042. doi: 10.1016/j.cclet.2021.03.054
5. [5]
  Y. Wang, H. Gao, J. Yang, et al., Adv. Mater. 33 (2021) 2007811. doi: 10.1002/adma.202007811
6. [6]
  X. Yao, J. Wang, D. Jiao, et al., Adv. Mater. 33 (2020) 2005973.
7. [7]
  D. Li, Y. Yang, J. Yang, et al., Nat. Commun. 13 (2022) 347. doi: 10.1038/s41467-022-28011-6
8. [8]
  S. Cui, B. Wang, Y. Zan, et al., Chem. Eng. J. 431 (2022) 133373. doi: 10.1016/j.cej.2021.133373
9. [9]
  Y. Wang, J. Yang, M. Fang, et al., Adv. Funct. Mater. 31 (2021) 2101719. doi: 10.1002/adfm.202101719
10. [10]
  J. Zhou, D. Liu, L. Li, et al., Chin. Chem. Lett. (2024) 109929. doi: 10.1016/j.cclet.2024.109929
11. [11]
  T. Wang, Z. Hu, X. Nie, et al., Nat. Commun. 12 (2021) 1364. doi: 10.1038/s41467-021-21676-5
12. [12]
  L. Bian, H. Shi, X. Wang, et al., J. Am. Chem. Soc. 140 (2018) 10734-10739. doi: 10.1021/jacs.8b03867
13. [13]
  X. Wang, H. Shi, H. Ma, et al., Nat. Photonics 15 (2021) 187-192. doi: 10.1038/s41566-020-00744-0
14. [14]
  J. Song, L. Ma, S. Sun, et al., Angew. Chem. Int. Ed. 61 (2022) e202206157. doi: 10.1002/anie.202206157
15. [15]
  H. Li, H. Li, J. Gu, et al., Chem. Sci. 12 (2021) 3580-3586. doi: 10.1039/d0sc06025a
16. [16]
  H. Sun, L. Zhu, Aggregate 4 (2022) e253.
17. [17]
  H. Gao, X. Ma, Aggregate 2 (2021) e38. doi: 10.1002/agt2.38
18. [18]
  Y. Wang, C. Wang, J. Zhang, et al., Chin. Chem. Lett. 34 (2023)108062. doi: 10.1016/j.cclet.2022.108062
19. [19]
  Y. Liu, G. Zhan, W. Liu, et al., Chin. Chem. Lett. 27 (2016) 1231-1240. doi: 10.1016/j.cclet.2016.06.029
20. [20]
  Y. Sun, L. Jiang, Y. Chen, et al., Chin. Chem. Lett. 35 (2024) 108644. doi: 10.1016/j.cclet.2023.108644
21. [21]
  W. Zhao, Z. He, J.W.Y. Lam, et al., Chem 1 (2016) 592-602. doi: 10.1016/j.chempr.2016.08.010
22. [22]
  J. Yang, X. Zhen, B. Wang, et al., Nat. Commun. 9 (2018) 840. doi: 10.1071/mf17375
23. [23]
  O. Bolton, D. Lee, J. Jung, et al., Chem. Mater. 26 (2014) 6644-6649. doi: 10.1021/cm503678r
24. [24]
  Y. Gong, Y. Tan, J. Mei, et al., Sci. China Chem. 56 (2013) 1178-1182. doi: 10.1007/s11426-013-4923-8
25. [25]
  C.R. Wang, Y.Y. Gong, W.Z. Yuan, et al., Chin. Chem. Lett. 27 (2016) 1184-1192. doi: 10.1016/j.cclet.2016.05.026
26. [26]
  D. Lee, O. Bolton, B.C. Kim, et al., J. Am. Chem. Soc. 135 (2013) 6325-6329. doi: 10.1021/ja401769g
27. [27]
  T. Li, Y. Zheng, C. Wu, et al., Chin. Chem. Lett. 33 (2022) 4238-4242. doi: 10.1016/j.cclet.2022.03.047
28. [28]
  J. Wang, Z. Huang, X. Ma, et al., Angew. Chem. Int. Ed. 59 (2020) 9928-9933. doi: 10.1002/anie.201914513
29. [29]
  Z. An, C. Zheng, Y. Tao, et al., Nat. Mater. 14 (2015) 685-690. doi: 10.1038/nmat4259
30. [30]
  C.C. Zhang, S. Yuan, Y.H. Lou, et al., Adv. Mater. 32 (2020) 2001479. doi: 10.1002/adma.202001479
31. [31]
  X. Zheng, J. Jiang, Q. Lin, et al., Chem. Eng. J. 469 (2023) 143929. doi: 10.1016/j.cej.2023.143929
32. [32]
  K. Zhang, L.Y. Peng, X.X. Liu, et al., Angew. Chem. Int. Ed. 62 (2023) e202300927. doi: 10.1002/anie.202300927
33. [33]
  S. Li, Z.Y. Zhang, J.F. Lv, et al., J. Mater. Chem. A 11 (2023) 4957-4962. doi: 10.1039/d2ta09993d
34. [34]
  H. Shi, Z. An, P.Z. Li, et al., Cryst. Growth Des. 16 (2016) 808-813. doi: 10.1021/acs.cgd.5b01400
35. [35]
  S. Xiong, Y. Xiong, D. Wang, et al., Adv. Mater. 35 (2023) e2301874. doi: 10.1002/adma.202301874
36. [36]
  N. Gan, X. Zou, M. Dong, et al., Nat. Commun. 13 (2022) 3995. doi: 10.1038/s41467-022-31554-3
37. [37]
  Q. Dang, Y. Jiang, J. Wang, et al., Adv. Mater. 32 (2020) e2006752. doi: 10.1002/adma.202006752
38. [38]
  S. Kuila, S.J. George, Angew. Chem. Int. Ed. 59 (2020) 9393-9397. doi: 10.1002/anie.202002555
39. [39]
  L. Kong, Y. Zhu, S. Sun, et al., Chem. Eng. J. 469 (2023) 143931. doi: 10.1016/j.cej.2023.143931
40. [40]
  Y. Zhu, S. Sun, H. Li, et al., Eur. Polym. J. 202 (2024) 112600. doi: 10.1016/j.eurpolymj.2023.112600
41. [41]
  L. Kong, S. Sun, Y. Zhu, et al., Dyes Pigm. 226 (2024) 112131. doi: 10.1016/j.dyepig.2024.112131
42. [42]
  Y.Q. Zhu, X.H. Wang, M.X. Wu, Adv. Funct. Mater. 33 (2023) 2308096. doi: 10.1002/adfm.202308096
43. [43]
  S. Sun, J. Wang, L. Ma, et al., Angew. Chem. Int. Ed. 60 (2021) 18557-18560. doi: 10.1002/anie.202107323
44. [44]
  G. Jiang, Q. Li, A. Lv, et al., J. Mater. Chem. C 10 (2022) 13797-13804. doi: 10.1039/d2tc01093c
45. [45]
  T. Zhang, X. Ma, H. Tian, Chem. Sci. 11 (2020) 482-487. doi: 10.1039/c9sc05502a
46. [46]
  H. Zhu, I. Badia-Dominguez, B. Shi, et al., J. Am. Chem. Soc. 143 (2021) 2164-2169. doi: 10.1021/jacs.0c12659
47. [47]
  W. Zhao, Z. He, B.Z. Tang, Nat. Rev. Mater. 5 (2020) 869-885. doi: 10.1038/s41578-020-0223-z
48. [48]
  X. Yang, S. Wang, K. Sun, et al., Angew. Chem. Int. Ed. 62 (2023) e202306475. doi: 10.1002/anie.202306475
49. [49]
  D. Beljonne, Z. Shuai, G. Pourtois, et al., J. Phys. Chem. A 105 (2001) 3899-3907. doi: 10.1021/jp010187w
50. [50]
  C. Qian, X. Zhang, Z. Ma, et al., CCS Chem. 6 (2024) 798-811. doi: 10.31635/ccschem.023.202202561
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