Citation: Hong Yao, Feixiang Yang, Jianpeng Hu, Wenyu Cao, Shuning Qin, Tai-Bao Wei, Bingbing Shi, Qi Lin. Ultralong room temperature phosphorescence and broad color-tunability persistent luminescence via new strategy[J]. Chinese Chemical Letters, ;2025, 36(6): 110375. doi: 10.1016/j.cclet.2024.110375 shu

Ultralong room temperature phosphorescence and broad color-tunability persistent luminescence via new strategy

Key Laboratory of Eco-Functional Polymer Materials of the Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

yhxbz@126.com

linqi2004@126.com

Received Date: 30 May 2024
Revised Date: 17 August 2024
Accepted Date: 26 August 2024
Available Online: 27 August 2024

Figures(6)

Pure organic materials with ultralong room-temperature phosphorescence (RTP) and persistent luminescence in broad color gamut exhibit tremendous potential and broad application prospects due to their unique optical properties. This article proposes a simple strategy, polyatomic synergistic effect, to endow persistent luminescent materials with ultralong lifetime and broad color-tunability through polyatomic synergistic effect and non-traditional phosphorescence resonance energy transfer (PRET). By leveraging the polyatomic synergistic effect to enhance the intersystem crossing (ISC) in bibenzimidazole (BBI) derivatives and suppress the non-radiative transition process, ultralong persistent room-temperature phosphorescence has been successfully achieved after incorporating BBI-Cl-M into poly(methyl methacrylate) (PMMA) to form a rigid matrix(BBI-Cl-M@PMMA). Specifically, the ester functionalized bibenzimidazole with modified chlorine on molecular skeleton (BBI-Cl-M) demonstrates a remarkable phosphorescent lifetime (τ_p) of up to 256.4 ms. In addition, the behaviors and mechanism of RTP via polyatomic synergistic effect have been further understood by theoretical calculation and single crystal analysis. Subsequently, utilizing BBI-Cl-M as the energy donor and Rhodamine B (RB) as the energy acceptor, persistent and multicolor organic afterglow covering from green to red has been realized successfully by simply regulating the doping composition and concentration of PRET systems. These RTP materials have also been applied in underwater afterglow emission and multilevel anti-counterfeiting technology successfully.
- Polyatomic synergistic effect,
- RTP,
- PRET,
- Multilevel anti-counterfeiting,
- Underwater phosphorescence
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