Citation: Haoyu Luo, Jinsong Chen, Mengfei Luo, Hui Ma, Shengyan Pu. Heterogeneous Fenton catalytic degradation of nitrobenzene by controlled-release nano calcium peroxide[J]. Chinese Chemical Letters, ;2025, 36(6): 110367. doi: 10.1016/j.cclet.2024.110367 shu

Heterogeneous Fenton catalytic degradation of nitrobenzene by controlled-release nano calcium peroxide

State Key Laboratory of Geohazard Prevention and Geoenvironent Protection, Chengdu University of Technology, Chengdu 610059, China

mahui.orange@gmail.com

Received Date: 26 April 2024
Revised Date: 23 July 2024
Accepted Date: 23 August 2024
Available Online: 24 August 2024

Figures(5)

Degradation of nitrobenzene (NB) via Fenton-like reaction is considered as an efficient approach for contaminated groundwater remediation. However, the poor stability of H₂O₂ limits the application of traditional Fenton reactions in soil and groundwater due to the transportation risks of H₂O₂. In this study, we synthesized a controlled release nano calcium peroxide (nCP) by coating it with polydopamine (PDA) as a solid H₂O₂ to construct a Fe(Ⅱ)/PDA@nCP Fenton-like system for contaminants degradation. The phenol-quinone transformations of catechol groups on the PDA surface facilitated the Fe(Ⅱ)/Fe(Ⅲ) cycle, resulting in enhanced generation of hydroxyl radicals (HO) and effective long-term degradation of NB. Moreover, the PDA shell modulated the nCP decomposition rate and inhibited sharp pH fluctuations, and the NB removal efficiency was achieved up to 96.8% at pH ranging from 3.0 to 9.0. This study demonstrated the promising application potential of PDA@nCP as a solid-controlled release H₂O₂ source in Fenton-like system for groundwater contamination remediation.
- Calcium peroxide,
- Controlled release materials,
- Reactive species,
- Fe(Ⅱ)/Fe(Ⅲ) cycle,
- Hydroxyl radicals
1. [1]
  S. Kiani, S.M. Mousavi, S. Afrang, J. Polym. Environ. 31 (2023) 2968–2982. doi: 10.1007/s10924-023-02784-3
2. [2]
  M. Van den Berg, R. Cattley, J.W. Cherrie, et al., Lancet Oncol. 19 (2018) e681–e682. doi: 10.1016/S1470-2045(18)30823-4
3. [3]
  J.Dong L.Deng, J. Bai, et al., J. Hydrol. 593 (2021) 125914. doi: 10.1016/j.jhydrol.2020.125914
4. [4]
  Q. Shi, S. Pu, X. Yang, et al., Chin. Chem. Lett. 33 (2022) 2129–2133. doi: 10.1016/j.cclet.2021.07.063
5. [5]
  J. Chen, H. Luo, D. Luo, et al., Sep. Purif. Technol. 322 (2023) 124252. doi: 10.1016/j.seppur.2023.124252
6. [6]
  Y. Chen, H. Li, W. Liu, et al., Chemosphere 113 (2014) 48–55. doi: 10.1016/j.chemosphere.2014.03.122
7. [7]
  S. Han, M. Qin, Y. Wang, et al., J. Hazard. Mater. 466 (2024) 133582. doi: 10.1016/j.jhazmat.2024.133582
8. [8]
  B. Walawska, J. Gluzińska, K. Miksch, et al., Pol. J. Chem. Technol. 9 (2007) 68–72. doi: 10.2478/v10026-007-0057-0
9. [9]
  J. Chen, H. Ma, H. Luo, et al., J. Hazard. Mater. 464 (2024) 132902. doi: 10.1016/j.jhazmat.2023.132902
10. [10]
  Y. Liu, X. Sheng, Z. Zhou, et al., J. Hazard. Mater. 432 (2022) 128693. doi: 10.1016/j.jhazmat.2022.128693
11. [11]
  J. Gryzenia, D. Cassidy, D. Hampton, Chemosphere 77 (2009) 540–545. doi: 10.1016/j.chemosphere.2009.07.012
12. [12]
  K. Moraczewski, A. Trafarski, R. Malinowski, Materials 14 (2021) 6862. doi: 10.3390/ma14226862
13. [13]
  Y. Xie, L. Lei, L. Luo, J. Clust. Sci. 34 (2023) 2361–2371. doi: 10.1007/s10876-022-02387-3
14. [14]
  X. Liu, S. Li, H. Liu, Colloid. Surf. A 648 (2022) 129265. doi: 10.1016/j.colsurfa.2022.129265
15. [15]
  J. Xiao, C. Wang, S. Lyu, et al., Sep. Purif. Technol. 169 (2016) 202–209. doi: 10.1016/j.seppur.2016.04.031
16. [16]
  H. Wang, Y. Zhao, T. Li, et al., Chem. Eng. J. 303 (2016) 450–457. doi: 10.1016/j.cej.2016.05.123
17. [17]
  M. Ali, U. Farooq, S. Lyu, et al., Sep. Purif. Technol. 241 (2020) 116729. doi: 10.1016/j.seppur.2020.116729
18. [18]
  C. Vogt, B.M. Weckhuysen, Nat. Rev. Chem. 6 (2022) 89–111. doi: 10.1038/s41570-021-00340-y
19. [19]
  Z. Li, Y. Zhou, M. Xie, et al., Angew. Chem. Int. Ed. 62 (2023) e202217815. doi: 10.1002/anie.202217815
20. [20]
  A. Rastinfard, B. Dalisson, J. Barralet, et al., Acta Biomater. 145 (2022) 390–402. doi: 10.1016/j.actbio.2022.04.004
21. [21]
  Z. Yang, C. Shan, B. Pan, J.J. Pignatello, Environ. Sci. Technol. 55 (2021) 8299–8308. doi: 10.1021/acs.est.1c00230
22. [22]
  W. Wang, Y. Wang, K. Zhou, et al, Sci. Total Environ. 848 (2022) 157708. doi: 10.1016/j.scitotenv.2022.157708
23. [23]
  Y. Zhang, K. Zhang, C. Dai, et al, Chem. Eng. J. 244 (2014) 438–445. doi: 10.1016/j.cej.2014.01.088
24. [24]
  Y. Liu, X. Sheng, M. Habib, et al, Chem. Eng. J. 475 (2023) 146032. doi: 10.1016/j.cej.2023.146032
25. [25]
  D. Rubio, E. Nebot, J.F. Casanueva, et al., Water Res. 47 (2013) 6367–6379. doi: 10.1016/j.watres.2013.08.006
26. [26]
  J. Zhang, L. Chen, H. Yin, et al., Environ. Pollut. 225 (2017) 86–92. doi: 10.1016/j.envpol.2017.03.047
27. [27]
  X. Li, B. Wu, Q. Zhang, et al., Chem. Eng. J. 378 (2019) 122142. doi: 10.1016/j.cej.2019.122142
28. [28]
  C. Liu, Y. Cao, Y. Cheng, et al., Nat. Commun. 11 (2020) 1735. doi: 10.1038/s41467-020-15591-4
29. [29]
  D. Wang, D. Zhang, Q. Xu, et al., Chem. Eng. J. 355 (2019) 22–32. doi: 10.1117/12.2536256
30. [30]
  Y.Y. Jiang, Z.W. Chen, M.M. Li, et al., Sci. Total Environ. 773 (2021) 144801. doi: 10.1016/j.scitotenv.2020.144801
31. [31]
  J. Clément, N. Ferré, D. Siri, et al., J. Org. Chem. 70 (2005) 1198–1203. doi: 10.1021/jo048518z
32. [32]
  S.K. Han, T.M. Hwang, Y. Yoon, et al., Chemosphere 84 (2011) 1095–1101. doi: 10.1016/j.chemosphere.2011.04.051
33. [33]
  X. Zhang, X. Gu, S. Lu, et al., J. Hazard. Mater. 284 (2015) 253–260. doi: 10.1016/j.jhazmat.2014.11.030
34. [34]
  Y. Li, H. Dong, J. Xiao, et al., Chem. Eng. J. 446 (2022) 136882. doi: 10.1016/j.cej.2022.136882
35. [35]
  A. Northup, D. Cassidy, J. Hazard. Mater. 152 (2008) 1164–1170. doi: 10.1016/j.jhazmat.2007.07.096
36. [36]
  Y. Xie, R. Xiong, J. Li, et al., J. Environ. Manage. 333 (2023) 117428. doi: 10.1016/j.jenvman.2023.117428
37. [37]
  M. Ali, M. Tariq, Y. Sun, et al., J. Hazard. Mater. 416 (2021) 125935. doi: 10.1016/j.jhazmat.2021.125935
38. [38]
  M. Ali, X. Zhang, A. Idrees, et al., J. Environ. Chem. Eng. 9 (2021) 104591. doi: 10.1016/j.jece.2020.104591
39. [39]
  B.A.G. de Melo, F.L. Motta, M.H.A. Santana, Mater. Sci. Eng. C 62 (2016) 967–974. doi: 10.1016/j.msec.2015.12.001
40. [40]
  H. Leng, Z. Lv, H. Tan, et al., Process Saf. Environ. Protect. 169 (2023) 34–47. doi: 10.1016/j.psep.2022.10.075
41. [41]
  J. Xu, S. Wang, C. Yan, et al., Chemosphere 288 (2022) 132666. doi: 10.1016/j.chemosphere.2021.132666
42. [42]
  J. Bai, Y. Liu, X. Yin, et al., Appl. Surf. Sci. 416 (2017) 45–50. doi: 10.1016/j.apsusc.2017.04.117
1. [1]
  Shiyu Pan , Bo Cao , Deling Yuan , Tifeng Jiao , Qingrui Zhang , Shoufeng Tang . Complexes of cupric ion and tartaric acid enhanced calcium peroxide Fenton-like reaction for metronidazole degradation. Chinese Chemical Letters, 2024, 35(7): 109185-. doi: 10.1016/j.cclet.2023.109185
2. [2]
  Jinshuai Zheng , Junfeng Niu , Crispin Halsall , Yadi Guo , Peng Zhang , Linke Ge . New insights into transformation mechanisms for sulfate and chlorine radical-mediated degradation of sulfonamide and fluoroquinolone antibiotics. Chinese Chemical Letters, 2025, 36(5): 110202-. doi: 10.1016/j.cclet.2024.110202
3. [3]
  Zhongyu Wang , Lijun Wang , Huaixin Zhao . DNA-based nanosystems to generate reactive oxygen species for nanomedicine. Chinese Chemical Letters, 2024, 35(11): 109637-. doi: 10.1016/j.cclet.2024.109637
4. [4]
  Xiaoxue Li , Hongwei Zhou , Rongrong Qian , Xu Zhang , Lei Yu . A concise synthesis of Se/Fe materials for catalytic oxidation reactions of anthracene and polyene. Chinese Chemical Letters, 2025, 36(3): 110036-. doi: 10.1016/j.cclet.2024.110036
5. [5]
  Haixian Ren , Yuting Du , Xiaojing Yang , Fangjun Huo , Le Zhang , Caixia Yin . Development of ESIPT-based specific fluorescent probes for bioactive species based on the protection-deprotection of the hydroxyl. Chinese Chemical Letters, 2025, 36(2): 109867-. doi: 10.1016/j.cclet.2024.109867
6. [6]
  Yuanyi Zhou , Ke Ma , Jinfeng Liu , Zirun Zheng , Bo Hu , Yu Meng , Zhizhong Li , Mingshan Zhu . Is reactive oxygen species the only way for cancer inhibition over single atom nanomedicine? Autophagy regulation also works. Chinese Chemical Letters, 2024, 35(6): 109056-. doi: 10.1016/j.cclet.2023.109056
7. [7]
  Chi Zhang , Ning Ding , Yuwei Pan , Lichun Fu , Ying Zhang . The degradation pathways of contaminants by reactive oxygen species generated in the Fenton/Fenton-like systems. Chinese Chemical Letters, 2024, 35(10): 109579-. doi: 10.1016/j.cclet.2024.109579
8. [8]
  Zhuan Chen , Bo Yang , Jun Li , Kun Du , Jiangchen Fu , Xiao Wu , Jiazhen Cao , Mingyang Xing . Environmentally safe storage and sustained release of hydrogen peroxide utilizing commercial hydrogel. Chinese Chemical Letters, 2025, 36(6): 110320-. doi: 10.1016/j.cclet.2024.110320
9. [9]
  Yuhan Wu , Qing Zhao , Zhijie Wang . Layered vanadium oxides: Promising cathode materials for calcium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(5): 100271-100271. doi: 10.1016/j.cjsc.2024.100271
10. [10]
  Zheyi Li , Xiaoyang Liang , Zitong Qiu , Zimeng Liu , Siyu Wang , Yue Zhou , Nan Li . Ion-interferential cell cycle arrest for melanoma treatment based on magnetocaloric bimetallic-ion sustained release hydrogel. Chinese Chemical Letters, 2024, 35(11): 109592-. doi: 10.1016/j.cclet.2024.109592
11. [11]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
12. [12]
  Ning DING , Siyu WANG , Shihua YU , Pengcheng XU , Dandan HAN , Dexin SHI , Chao ZHANG . Crystalline and amorphous metal sulfide composite electrode materials with long cycle life: Preparation and performance of hybrid capacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1784-1794. doi: 10.11862/CJIC.20240146
13. [13]
  Yuwei Liu , Yihui Zhu , Weijian Duan , Yizhuo Yang , Haorui Tuo , Chunhua Feng . Electrocatalytic nitrate reduction on Fe, Fe₃O₄, and Fe@Fe₃O₄ cathodes: Elucidating structure-sensitive mechanisms of direct electron versus hydrogen atom transfer. Chinese Chemical Letters, 2025, 36(6): 110347-. doi: 10.1016/j.cclet.2024.110347
14. [14]
  Jiayu Huang , Kuan Chang , Qi Liu , Yameng Xie , Zhijia Song , Zhiping Zheng , Qin Kuang . Fe-N-C nanostick derived from 1D Fe-ZIFs for Electrocatalytic oxygen reduction. Chinese Journal of Structural Chemistry, 2023, 42(10): 100097-100097. doi: 10.1016/j.cjsc.2023.100097
15. [15]
  Yi Zhang , Biao Wang , Chao Hu , Muhammad Humayun , Yaping Huang , Yulin Cao , Mosaad Negem , Yigang Ding , Chundong Wang . Fe–Ni–F electrocatalyst for enhancing reaction kinetics of water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100243-100243. doi: 10.1016/j.cjsc.2024.100243
16. [16]
  Yun-Fei Zhang , Chun-Hui Zhang , Jian-Hui Xu , Lei Li , Dan Li , Jin-Hong Fan , Jiale Gao , Xin Quan , Qi Wu , Yue Zou , Yan-Ling Liu . Enhanced degradation of florfenicol by microscale SiC/Fe: Dechlorination via hydrogenolysis. Chinese Chemical Letters, 2024, 35(7): 109385-. doi: 10.1016/j.cclet.2023.109385
17. [17]
  Yanqiong Wang , Yaqi Hou , Fengwei Huo , Xu Hou . Fe³⁺ ion quantification with reusable bioinspired nanopores. Chinese Chemical Letters, 2025, 36(2): 110428-. doi: 10.1016/j.cclet.2024.110428
18. [18]
  Weichen Zhu , Wei Zuo , Pu Wang , Wei Zhan , Jun Zhang , Lipin Li , Yu Tian , Hong Qi , Rui Huang . Fe-N-C heterogeneous Fenton-like catalyst for the degradation of tetracycline: Fe-N coordination and mechanism studies. Chinese Chemical Letters, 2024, 35(9): 109341-. doi: 10.1016/j.cclet.2023.109341
19. [19]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
20. [20]
  Linjing Li , Wenlai Xu , Jianyong Ning , Yaping Zhong , Chuyue Zhang , Jiane Zuo , Zhicheng Pan . Revealing the intrinsic mechanisms for accelerating nitrogen removal efficiency in the Anammox reactor by adding Fe(II) at low temperature. Chinese Chemical Letters, 2024, 35(8): 109243-. doi: 10.1016/j.cclet.2023.109243

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(164)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142