Citation: Haoyu Luo, Jinsong Chen, Mengfei Luo, Hui Ma, Shengyan Pu. Heterogeneous Fenton catalytic degradation of nitrobenzene by controlled-release nano calcium peroxide[J]. Chinese Chemical Letters, ;2025, 36(6): 110367. doi: 10.1016/j.cclet.2024.110367 shu

Heterogeneous Fenton catalytic degradation of nitrobenzene by controlled-release nano calcium peroxide

State Key Laboratory of Geohazard Prevention and Geoenvironent Protection, Chengdu University of Technology, Chengdu 610059, China

mahui.orange@gmail.com

Received Date: 26 April 2024
Revised Date: 23 July 2024
Accepted Date: 23 August 2024
Available Online: 24 August 2024

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Degradation of nitrobenzene (NB) via Fenton-like reaction is considered as an efficient approach for contaminated groundwater remediation. However, the poor stability of H₂O₂ limits the application of traditional Fenton reactions in soil and groundwater due to the transportation risks of H₂O₂. In this study, we synthesized a controlled release nano calcium peroxide (nCP) by coating it with polydopamine (PDA) as a solid H₂O₂ to construct a Fe(Ⅱ)/PDA@nCP Fenton-like system for contaminants degradation. The phenol-quinone transformations of catechol groups on the PDA surface facilitated the Fe(Ⅱ)/Fe(Ⅲ) cycle, resulting in enhanced generation of hydroxyl radicals (HO) and effective long-term degradation of NB. Moreover, the PDA shell modulated the nCP decomposition rate and inhibited sharp pH fluctuations, and the NB removal efficiency was achieved up to 96.8% at pH ranging from 3.0 to 9.0. This study demonstrated the promising application potential of PDA@nCP as a solid-controlled release H₂O₂ source in Fenton-like system for groundwater contamination remediation.
- Calcium peroxide,
- Controlled release materials,
- Reactive species,
- Fe(Ⅱ)/Fe(Ⅲ) cycle,
- Hydroxyl radicals
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