Citation: Le Han, Zhou Yuan, Bohan Li, Yuchi Zhang, Lin Yang, Yan Xu. Highly-stable cesium lead halide perovskite CsPbBr₃/CsPb₂Br₅ heteronanocrystals in zeolitic imidazolate framework-8 for antibiotic photodegradation[J]. Chinese Chemical Letters, ;2025, 36(6): 110349. doi: 10.1016/j.cclet.2024.110349 shu

Highly-stable cesium lead halide perovskite CsPbBr₃/CsPb₂Br₅ heteronanocrystals in zeolitic imidazolate framework-8 for antibiotic photodegradation

Le Han ^a ,
Zhou Yuan ^a ,
Bohan Li ^a ,
Yuchi Zhang ^a ,
Lin Yang ^a ,
Yan Xu ^{a, b, *,}

a.
Department of Chemistry, College of Sciences, Northeastern University, Shenyang 110819, China
b.
Foshan Graduate School of Innovation, Northeastern University, Foshan 528311, China

xuyan@mail.neu.edu.cn

Received Date: 8 May 2024
Revised Date: 18 July 2024
Accepted Date: 17 August 2024
Available Online: 17 August 2024

Figures(7)

Metal halide perovskite nanocrystals (MHP NCs) are of great candidates in photocatalytic applications due to their extreme light utilization efficiency. However, the instability towards humid environment severely restrict their practical application. Herein, the CsPbBr₃/CsPb₂Br₅ heteronanocrystals (HNCs) were successfully encapsulated into ZIF-8 through a thermal injection method via controlling the molar ratio of Cs⁺/Pb²⁺. The surface of ZIF-8 was then modified with hydrophobic copolymer of poly(methyl methacrylate) (PMMA) to improve the water stability. Benefiting from the intimate interfacial interaction and staggered energy band structure, the type-Ⅱ heterojunction of CsPbBr₃/CsPb₂Br₅ guarantees efficient separation and migration of photogenerated electron/hole pairs. Meanwhile, the formation of Z-scheme heterojunction between ZIF-8 and CsPbBr₃/CsPb₂Br₅ HNCs contributes to the adsorption and enrichment of pollutants, further accelerates the photocatalytic antibiotic degradation efficiency towards tetracycline hydrochloride (TCH) in aqueous solution. Nearly 87% of TCH (40 mg/L, 50 mL) was degraded by 40 mg catalyst within 100 min. This work offers a feasible approach in assembling high-performance MHP NCs-based efficient photocatalyst with expanding application in aqueous solution.
- Perovskite,
- Heterojunction,
- High stability,
- Tetracycline,
- Aqueous photocatalysis
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沈阳化工大学材料科学与工程学院沈阳 110142

Highly-stable cesium lead halide perovskite CsPbBr3/CsPb2Br5 heteronanocrystals in zeolitic imidazolate framework-8 for antibiotic photodegradation

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通讯作者: 陈斌, bchen63@163.com

Highly-stable cesium lead halide perovskite CsPbBr₃/CsPb₂Br₅ heteronanocrystals in zeolitic imidazolate framework-8 for antibiotic photodegradation