Citation: Siyu Zong, Xiaowei Yu, Yining Yang, Xin Yang, Jiyang Li. Multi-mode luminescence anti-counterfeiting and visual iron(Ⅲ) ions RTP detection constructed by assembly of CDs&Eu³⁺ in porous RHO zeolite[J]. Chinese Chemical Letters, ;2025, 36(6): 110343. doi: 10.1016/j.cclet.2024.110343 shu

Multi-mode luminescence anti-counterfeiting and visual iron(Ⅲ) ions RTP detection constructed by assembly of CDs&Eu³⁺ in porous RHO zeolite

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

lijiyang@jlu.edu.cn

Received Date: 10 May 2024
Revised Date: 15 July 2024
Accepted Date: 14 August 2024
Available Online: 15 August 2024

Figures(5)

Carbon dots (CDs)-based composites have shown impressive performance in fields of information encryption and sensing, however, a great challenge is to simultaneously implement multi-mode luminescence and room-temperature phosphorescence (RTP) detection in single system due to the formidable synthesis. Herein, a multifunctional composite of Eu&CDs@pRHO has been designed by co-assembly strategy and prepared via a facile calcination and impregnation treatment. Eu&CDs@pRHO exhibits intense fluorescence (FL) and RTP coming from two individual luminous centers, Eu³⁺ in the free pores and CDs in the interrupted structure of RHO zeolite. Unique four-mode color outputs including pink (Eu³⁺, ex. 254 nm), light violet (CDs, ex. 365 nm), blue (CDs, 254 nm off), and green (CDs, 365 nm off) could be realized, on the basis of it, a preliminary application of advanced information encoding has been demonstrated. Given the free pores of matrix and stable RTP in water of confined CDs, a visual RTP detection of Fe³⁺ ions is achieved with the detection limit as low as 9.8 µmol/L. This work has opened up a new perspective for the strategic amalgamation of luminous guests with porous zeolite to construct the advanced functional materials.
- Carbon dots,
- Zeolite,
- Host-guest assembly,
- Multi-mode luminescence,
- Phosphorescence detection,
- Information encryption
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沈阳化工大学材料科学与工程学院沈阳 110142

Multi-mode luminescence anti-counterfeiting and visual iron(Ⅲ) ions RTP detection constructed by assembly of CDs&Eu3+ in porous RHO zeolite

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通讯作者: 陈斌, bchen63@163.com

Multi-mode luminescence anti-counterfeiting and visual iron(Ⅲ) ions RTP detection constructed by assembly of CDs&Eu³⁺ in porous RHO zeolite