Citation: Qingbai Tian, BingLiang Yu, Zhihao Li, Wei Hong, Qian Li, Xing Xu. Versatile catalytic membranes anchored with metal-nitrogen based metal oxides for ultrafast Fenton-like oxidation[J]. Chinese Chemical Letters, ;2025, 36(6): 110322. doi: 10.1016/j.cclet.2024.110322 shu

Versatile catalytic membranes anchored with metal-nitrogen based metal oxides for ultrafast Fenton-like oxidation

Qingbai Tian ^a ,
BingLiang Yu ^a ,
Zhihao Li ^{b, *,} ,
Wei Hong ^{c, *,} ,
Qian Li ^a ,
Xing Xu ^{a, *,}

a.
Shandong Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, Qingdao 266237, China
b.
Henan water Conservancy Survey design Research Co., Ltd., Zhengzhou 450000, China
c.
Shandong Resources and Environment Construction Group Co., Ltd., Ji’nan 250100, China

lizhihao050@163.com

honw@163.com

xuxing@sdu.edu.cn

Received Date: 26 April 2024
Revised Date: 4 July 2024
Accepted Date: 6 August 2024
Available Online: 10 August 2024

Figures(5)

Although the powder Fenton-like catalysts have exhibited high catalytic performances towards pollutant degradation, they cannot be directly used for Fenton-like industrialization considering the problems of loss and recovery. Therefore, the membrane fixation of catalyst is an important step to realize the actual application of Fenton-like catalysts. In this work, an efficient catalyst was developed with Co-N_x configuration facilely reconstructed on the surface of Co₃O₄ (Co-N_x/Co₃O₄), which exhibited superior catalytic activity. We further fixed the highly efficient Co-N_x/Co₃O₄ onto three kinds of organic membranes and one kind of inorganic ceramic membrane installing with the residual PMS treatment device to investigate its catalytic stability and sustainability. Results indicated that the inorganic ceramic membrane (CM) can achieve high water flux of 710 L m^-2 h^-1, and the similar water flux can be achieved by Co-N_x/Co₃O₄/CM even without the pressure extraction. We also employed the Co-N_x/Co₃O₄/CM system to the wastewater secondary effluent, and the pollutant in complicated secondary effluent could be highly removed by the Co-Nx/Co₃O₄/CM system. This paper provides a new point of view for the application of metal-based catalysts with M-N_x coordination in catalytic reaction device.
- Peroxymonosulfate,
- Catalytic membranes,
- Metal oxides,
- Fenton-like reaction,
- Ceramic membrane
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