Citation: Xing Gao, Luofeng Wang, Jia Cheng, Jialiang Zhao, Xueli Liu. Manufacturing process of MOF-based separator for lithium sulfur batteries: A mini review[J]. Chinese Chemical Letters, ;2025, 36(8): 110247. doi: 10.1016/j.cclet.2024.110247 shu

Manufacturing process of MOF-based separator for lithium sulfur batteries: A mini review

School of Material and Chemical Engineering, Chuzhou University, Chuzhou 239000, China

gaoxinggxone@163.com

n_xueli@163.com

Received Date: 15 May 2024
Revised Date: 29 June 2024
Accepted Date: 12 July 2024
Available Online: 14 July 2024

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Metal organic frameworks (MOFs) are crystalline materials with three-dimensional porous network structure. They are obtained by self-assembly of coordinate bond with metal ions as the nodes and organic ligands as the connecting chains. MOFs have attracted extensive attention from researchers over the years due to their clear pore and rich topological structure. As the typical powder materials, a specific separator manufacturing process must be possessed when incorporating MOFs into lithium sulfur batteries separator. This mini review summarized the manufacturing process of MOFs separator for LSBs in recent years, and summed up the effects and mechanisms of separators prepared by various separator-forming processes on the performance of LSBs, the potential for industrialization of different separator manufacturing processes is also mentioned briefly.
- Metal-organic frameworks,
- Lithium sulfur batteries,
- Shuttling effect,
- Separator,
- Manufacturing process
1. [1]
  R. Deng, M. Wang, H. Yu, et al., Energy Environ. Mater. 5 (2022) 777–799. doi: 10.1002/eem2.12257
2. [2]
  M. Zhao, B.Q. Li, X.Q. Zhang, et al., ACS Cent. Sci. 6 (2020) 1095–1104. doi: 10.1021/acscentsci.0c00449
3. [3]
  Y. Li, S. Guo, Matter 4 (2021) 1142–1188.
4. [4]
  J. Zhao, Y. Qi, Q. Yang, et al., Chem. Eng. J. 429 (2022) 131997.
5. [5]
  R. Zou, W. Liu, F. Ran, InfoMat 4 (2022) 12319.
6. [6]
  Y.W. Tian, Y.J. Zhang, L. Wu, et al., ACS Appl. Mater. Interfaces 15 (2023) 6877–6887. doi: 10.1021/acsami.2c20461
7. [7]
  J.G. Kim, Y. Noh, Y. Kim, Chem. Eng. J. 435 (2022) 131339.
8. [8]
  Z.W. Seh, Y. Sun, Q. Zhang, et al., Chem. Soc. Rev. 45 (2016) 5605–5634.
9. [9]
  F. Pei, S. Dai, B. Guo, et al., Energy Environ. Sci. 14 (2021) 975–985. doi: 10.1039/d0ee03005h
10. [10]
  Q. Shao, S. Zhu, J. Chen, Nano Res. 16 (2023) 8097–8138. doi: 10.1007/s12274-022-5227-0
11. [11]
  S. Li, H. Dai, Y. Li, et al., Energy Storage Mater. 18 (2019) 222–228.
12. [12]
  Z. Li, J. Wu, P. Chen, et al., Chem. Eng. J. 435 (2022) 135125.
13. [13]
  C. Shi, M. Yu, Energy Storage Mater. 57 (2023) 429–459.
14. [14]
  Y. Zhang, C. Guo, J. Zhou, et al., Small 19 (2023) e2206616.
15. [15]
  Z. Han, S. Li, M. Sun, et al., J. Energy Chem. 68 (2022) 752–761. doi: 10.3390/su14020752
16. [16]
  H. Sul, A. Bhargav, A. Manthiram, Adv. Energy Mater. 12 (2022) 2200680.
17. [17]
  X. Zhang, W. Yuan, H. Huang, et al., Inter. J. Extreme Manufac. 5 (2022) 015501.
18. [18]
  Y. Zhang, C. Guo, L. Zhou, et al., Small Sci. 3 (2023) 2300056.
19. [19]
  S. Foley, H. Geaney, G. Bree, et al., Adv. Funct. Mater. 28 (2018) 1800587.
20. [20]
  P. Marino, P.R. Donnarumma, H.A. Bicalho, et al., ACS Sustain. Chem. Eng. 9 (2021) 16356–16362. doi: 10.1021/acssuschemeng.1c06032
21. [21]
  C.W. Ashling, D.N. Johnstone, R.N. Widmer, et al., J. Am. Chem. Soc. 141 (2019) 15641–15648. doi: 10.1021/jacs.9b07557
22. [22]
  D. Sun, M. Xu, Y. Jiang, et al., Small Methods 2 (2018) 1800164.
23. [23]
  S. Hou, W. Ding, S. Liu, et al., Chem. Eng. J. 460 (2023) 141785.
24. [24]
  S. Xie, F. Li, S. Xu, et al., Chin. J. Catal. 40 (2019) 1205–1211.
25. [25]
  K. Ge, S. Sun, Y. Zhao, et al., Angew. Chem. Int. Ed. 60 (2021) 12097–12102. doi: 10.1002/anie.202102632
26. [26]
  Z. Zhao, H. Li, K. Zhao, et al., Chem. Eng. J. 428 (2022) 131006.
27. [27]
  W. Li, Y. Zhang, Z. Yu, et al., ACS Nano 16 (2022) 14779–14791. doi: 10.1021/acsnano.2c05624
28. [28]
  Y. Jeon, J. Lee, H. Jo, et al., Chem. Eng. J. 407 (2021) 126967.
29. [29]
  S. Qiu, J. Zhang, X. Liang, et al., Chem. Eng. J. 450 (2022) 138287.
30. [30]
  F. Wu, S. Zhao, L. Chen, et al., Energy Storage Mater. 14 (2018) 383–391.
31. [31]
  C. Qi, L. Xu, J. Wang, et al., ACS Sustain. Chem. Eng. 8 (2020) 12968–12975. doi: 10.1021/acssuschemeng.0c03536
32. [32]
  S. Suriyakumar, M. Kanagaraj, M. Kathiresan, et al., Electro. Acta 265 (2018) 151–159.
33. [33]
  X.J. Hong, C.L. Song, Y. Yang, et al., ACS Nano 13 (2019) 1923–1931.
34. [34]
  X. Leng, J. Zeng, M. Yang, et al., J. Energy Chem. 82 (2023) 484–496.
35. [35]
  H.G. Jin, M. Wang, J.X. Wen, et al., ACS Appl. Mater. Interfaces 13 (2021) 3899–3910. doi: 10.1021/acsami.0c18899
36. [36]
  Z. Chang, Y. Qiao, J. Wang, et al., Energy Storage Mater. 25 (2020) 164–171.
37. [37]
  Z. Wang, W. Huang, J. Hua, et al., Small Methods 4 (2020) 2000082.
38. [38]
  S. Bai, K. Zhu, S. Wu, et al., J. Mater. Chem. A 4 (2016) 16812–16817.
39. [39]
  Y. He, Z. Chang, S. Wu, et al., Adv. Energy Mater. 8 (2018) 1802130.
40. [40]
  Y. Chen, L. Zhang, H. Pan, et al., J. Mater. Chem. A 9 (2021) 26929–26938. doi: 10.1039/d1ta07820h
41. [41]
  H. Chen, Y. Xiao, C. Chen, et al., ACS Appl. Mater. Interfaces 11 (2019) 11459–11465. doi: 10.1021/acsami.8b22564
42. [42]
  S.H. Kim, J.S. Yeon, R. Kim, et al., J. Mater. Chem. A 6 (2018) 24971–24978. doi: 10.1039/c8ta08843h
43. [43]
  Y. Li, S. Lin, D. Wang, et al., Adv. Mater. 32 (2020) 1906722.
44. [44]
  M. Li, Y. Wan, J.K. Huang, et al., ACS Energy Lett. 2 (2017) 2362–2367. doi: 10.1021/acsenergylett.7b00692
45. [45]
  M. Tian, F. Pei, M. Yao, et al., Energy Storage Mater. 21 (2019) 14–21.
46. [46]
  S. Bai, X. Liu, K. Zhu, et al., Nat. Energy 1 (2016) 16010.
47. [47]
  C. Zhou, Q. He, Z. Li, et al., Chem. Eng. J. 395 (2020) 124979.
48. [48]
  J. Liu, J. Wang, L. Zhu, et al., Chem. Eng. J. 411 (2021) 128540.
49. [49]
  J. Liu, J. Wang, L. Zhu, et al., J. Mater. Chem. A 10 (2022) 14098–14110. doi: 10.1039/d2ta03301a
50. [50]
  Y. Zang, F. Pei, J. Huang, et al., Adv. Energy Mater. 8 (2018) 1802052.
51. [51]
  Y. Guo, M. Sun, H. Liang, et al., ACS Appl. Mater. Interfaces 10 (2018) 30451–30459. doi: 10.1021/acsami.8b11042
52. [52]
  G. Gao, Y. Wang, H. Zhu, et al., Adv. Sci. 7 (2020) 2002190.
53. [53]
  Y. Feng, G. Wang, W. Kang, et al., Electro. Acta 365 (2021) 137344.
54. [54]
  N. Deng, L. Wang, Y. Feng, et al., Chem. Eng. J. 388 (2020) 124241.
55. [55]
  H. Wu, Y. Yang, W. Jia, et al., J. Alloy. Compd. 874 (2021) 159917.
56. [56]
  G.K. Gao, Y.R. Wang, S.B. Wang, et al., Angew. Chem. Int. Ed. 60 (2021) 10147–10154. doi: 10.1002/anie.202016608
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