Citation: Liangju Zhao, Shiyu Qin, Fei Wu, Limin Zhu, Qing Han, Lingling Xie, Xuejing Qiu, Hongliang Wei, Lanhua Yi, Xiaoyu Cao. Polycarbonyl conjugated porous polyimide as anode materials for high performance sodium-ion batteries[J]. Chinese Chemical Letters, ;2025, 36(8): 110246. doi: 10.1016/j.cclet.2024.110246 shu

Polycarbonyl conjugated porous polyimide as anode materials for high performance sodium-ion batteries

Liangju Zhao ^{a, c} ,
Shiyu Qin ^a ,
Fei Wu ^{a, c} ,
Limin Zhu ^{a, c, *,} ,
Qing Han ^{a, c} ,
Lingling Xie ^{b, c} ,
Xuejing Qiu ^{b, c} ,
Hongliang Wei ^a ,
Lanhua Yi ^{d, *,} ,
Xiaoyu Cao ^{a, c, *,}

a.
School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001, China
b.
School of Environmental Engineering, Henan University of Technology, Zhengzhou 450001, China
c.
Henan Engineering Technology Research Center of Electrochemical Energy Storage, Key Laboratory of High Specific Energy Materials for Electrochemical Power Sources of Zhengzhou City, Zhengzhou 450001, China
d.
Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, School of Chemistry, Xiangtan University, Xiangtan 411105, China

lmzhu@haut.edu.cn

yilanhua@xtu.edu.cn

caoxy@haut.edu.cn

Received Date: 9 June 2024
Revised Date: 22 June 2024
Accepted Date: 12 July 2024
Available Online: 14 July 2024

Figures(8)

Conjugated microporous polymers (CMPs) have attracted considerable attention as potential organic anode materials for sodium-ion batteries (SIBs) due to their flexible chemical structure, high porosity, environmental friendliness, and cost effectiveness. However, the inherent shortcomings of organic electrodes, such as low conductivity, high solubility in electrolyte, narrow material utilization, etc., limit their further development. In this work, we successfully prepared a novel porous polyimide PPD containing multicarbonyl active centers via the polycondensation of pyromellitic dianhydride (PMDA) and 2,6-diaminoanthraquinone (DAAQ). The stable conjugated structure and multiple redox centers give the polymer high reversible specific capacity (244.6 mAh/g after 100 cycles at 100 mA/g), ultra-long cycle stability (100.7 mAh/g after 2000 cycles at 1.0 A/g), and predominant rate capability. Meanwhile, the sodium storage mechanism of the electrode materials during the charging and discharging process is investigated by ex-situ XPS/FTIR analysis. Due to the exceptional electrochemical properties and simple synthesis method, this work may shed light on the preparation of polyimide-based anodes for high specific capacity and rate capability secondary batteries.
- Sodium-ion batteries,
- Porous polyimide,
- Polycarbonyl,
- Organic materials,
- Anodes
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