Citation: Changsheng Yang, Yuhang Jiang, Panpan Yu, Shiguo Han, Shihai You, Zeng-Kui Zhu, Zihao Yu, Junhua Luo. Realizing self-powered broadband photodetection with low detection limit in a trilayered perovskite ferroelectric[J]. Chinese Chemical Letters, ;2025, 36(8): 110218. doi: 10.1016/j.cclet.2024.110218 shu

Realizing self-powered broadband photodetection with low detection limit in a trilayered perovskite ferroelectric

Changsheng Yang ^{a, b, 1} ,
Yuhang Jiang ^{a, b, 1} ,
Panpan Yu ^{b, 1, *,} ,
Shiguo Han ^c ,
Shihai You ^c ,
Zeng-Kui Zhu ^{a, b, c} ,
Zihao Yu ^c ,
Junhua Luo ^{a, b, c, *,}

a.
School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
b.
Key Laboratory of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Jiangxi Normal University, Nanchang 330022, China
c.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

ppyu@jxnu.edu.cn

luojunhua@jxnu.edu.cn

Received Date: 13 May 2024
Revised Date: 5 June 2024
Accepted Date: 4 July 2024
Available Online: 5 July 2024

Figures(3)

Two-dimensional perovskite ferroelectric which strongly couple ferroelectricity with semiconducting properties are promising candidates for optoelectronic applications. However, it is still a great challenge to fabricate self-powered broadband photodetectors with low detection limit. Herein, we successfully realized self-powered broadband photodetection with low detection limit by using a trilayered perovskite ferroelectric (BA)₂EA₂Pb₃I₁₀ (1, BA = n-butylamine, EA = ethylamine). Giving to its large spontaneous polarization (5.6 µC/cm²), 1 exhibits an open-circuit voltage of 0.25 V which provide driving force to separate carriers. Combining with its low dark current (~10⁻¹⁴ A) and narrow bandgap (E_g = 1.86 eV), 1 demonstrates great potential on detecting the broadband weak lights. Thus, a prominent photodetection performance with high open-off ratio (~10⁵), outstanding responsivity (> 10 mA/W), and promising detectivity (> 10¹¹ Jones), as well as the low detecting limit (~nW/cm²) among the wide wavelength from 377 nm to 637 nm was realized based on the single crystal of 1. This work demonstrates the great potential of 2D perovskite ferroelectric on self-powered broadband photodetectors.
- Hybrid perovskite,
- Self-powered,
- Broadband photodetection,
- Detection limit,
- Ferroelectric,
- Bulk photovoltaic effect
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沈阳化工大学材料科学与工程学院沈阳 110142