Citation: Yaru Geng, Ruiqing Li, Tingting Zhu, Xinling Li, Qianwen Guan, Huang Ye, Peng Wang, Junlin Li, Junhua Luo. Formamidine intercalation to broaden photoresponsive range in alternating-cations-interlayered hybrid perovskite[J]. Chinese Chemical Letters, ;2025, 36(8): 110216. doi: 10.1016/j.cclet.2024.110216 shu

Formamidine intercalation to broaden photoresponsive range in alternating-cations-interlayered hybrid perovskite

Yaru Geng ^{a, b} ,
Ruiqing Li ^a ,
Tingting Zhu ^a ,
Xinling Li ^a ,
Qianwen Guan ^a ,
Huang Ye ^a ,
Peng Wang ^a ,
Junlin Li ^{a, b} ,
Junhua Luo ^{a, b, *,}

a.
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350002, China

jhluo@fjirsm.ac.cn

Received Date: 28 April 2024
Revised Date: 17 June 2024
Accepted Date: 4 July 2024
Available Online: 5 July 2024

Figures(4)

Two-dimensional (2D) organic-inorganic hybrid perovskites (OIHPs) have been developed as promising candidates for photodetection, owing to their excellent semiconducting features and structural tunability. However, as an important parameter for photodetection, the photoresponsive range of 2D OIHPs is usually modulated by finite metal-halide combinations, constraining their further development. The emerging aromatic amine-based alternating-cations-interlayered (A-ACI) hybrid perovskites that exhibit excellent charge transport and additional interlayered structural designability, provide an extra solution for achieving ideal photoresponsive range. Herein, for the first time, the photoresponsive range is successfully broadened in A-ACI hybrid perovskites (NMA)₄(FA)₂Pb₃Br₁₂ (2) remolding from (NMA)₄(MA)₂Pb₃Br₁₂ (1) (NMA = N-methylbenzylaminium, FA = formamidinium and MA = methylammonium). Particularly, 1 and 2 adopt an unprecedented configuration that NMA and MA/FA are alternately arranged in the interlayer in a 4:2 manner. Importantly, 2 exhibits a narrower bandgap than 1, which can be ascribed to the low-lying conduct band composed of intercalation FA π^* orbitals. Meanwhile, 2 possesses a shorter interlayer distance and flatter inorganic skeleton, synergistically facilitating the wider photo-absorption range and further endowing a broadening photoresponsive range (70 nm). This research not only enriches the perovskite family but also provides insights into structure-property relationships.
- Hybrid perovskites,
- Alternating-cations-interlayered,
- Formamidine intercalation,
- Broadening photoresponsive range,
- Photodetection
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