Citation: Xingjie Li, Chengjun Yi, Weifei Hu, Huishan Zhang, Jiale Xia, Yuanyuan Li, Jinping Liu. Emerging sulfide-polymer composite solid electrolyte membranes[J]. Chinese Chemical Letters, ;2025, 36(6): 110215. doi: 10.1016/j.cclet.2024.110215 shu

Emerging sulfide-polymer composite solid electrolyte membranes

Xingjie Li ^{a, 1} ,
Chengjun Yi ^{a, 1} ,
Weifei Hu ^a ,
Huishan Zhang ^a ,
Jiale Xia ^{a, *} ,
Yuanyuan Li ^{b, *} ,
Jinping Liu ^{a, *}

a.
School of Chemistry, Chemical Engineering and Life Science, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
b.
School of Integrated Circuits, Huazhong University of Science and Technology, Wuhan 430074, China

jialexia@whut.edu.cn

liyynano@hust.edu.cn

liujp@whut.edu.cn

Received Date: 4 June 2024
Revised Date: 17 June 2024
Accepted Date: 4 July 2024
Available Online: 4 July 2024

Figures(8)

Sulfide solid electrolytes with an ultrahigh ionic conductivity are considered to be extremely promising alternatives to liquid electrolytes for next-generation lithium batteries. However, it is difficult to obtain a thin solid electrolyte layer with good mechanical properties due to the weak binding ability between their powder particles, which seriously limits the actual energy density of sulfide all-solid-state lithium batteries (ASSLBs). Fortunately, the preparation of sulfide-polymer composite solid electrolyte (SPCSE) membranes by introducing polymer effectively reduces the thickness of solid electrolytes and guarantees high mechanical properties. In this review, recent progress of SPCSE membranes for ASSLBs is summarized. The classification of components in SPCSE membranes is first introduced briefly. Then, the preparation methods of SPCSE membranes are categorized according to process characteristics, in which the challenges of different methods and their corresponding solutions are carefully reviewed. The energy densities of the full battery composed of SPCSE membranes are further given whenever available to help understanding the device-level performance. Finally, we discuss the potential challenges and research opportunities for SPCSE membranes to guide the future development of high-performance sulfide ASSLBs.
- All-solid-state lithium batteries,
- Sulfide solid electrolyte,
- Composite electrolyte,
- Membrane processing,
- High energy density
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