Citation: Weiping Xiao, Yuhang Chen, Qin Zhao, Danil Bukhvalov, Caiqin Wang, Xiaofei Yang. Constructing the synergistic active sites of nickel bicarbonate supported Pt hierarchical nanostructure for efficient hydrogen evolution reaction[J]. Chinese Chemical Letters, ;2024, 35(12): 110176. doi: 10.1016/j.cclet.2024.110176 shu

Constructing the synergistic active sites of nickel bicarbonate supported Pt hierarchical nanostructure for efficient hydrogen evolution reaction

Weiping Xiao ^{a, b, *,} ,
Yuhang Chen ^a ,
Qin Zhao ^a ,
Danil Bukhvalov ^a ,
Caiqin Wang ^a ,
Xiaofei Yang ^{a, *,}

a.
College of Science, Institute of Materials Physics and Chemistry, Nanjing Forestry University, Nanjing 210037, China
b.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China

wpxiao@njfu.edu.cn

xiaofei.yang@njfu.edu.cn

Received Date: 25 January 2024
Revised Date: 28 May 2024
Accepted Date: 25 June 2024
Available Online: 25 June 2024

Figures(4)

Constructing synergistic active sites and optimizing the cooperative adsorption energies for hydrogen and hydroxyl based intermediates are two essential strategies to improve the sluggish kinetics of hydrogen evolution reaction (HER) in alkaline medium. However, it is still in its infancy to simultaneously achieve these goals, especially for designing a well-defined carrier with multiple hydroxyl adsorption sites. Herein, the Ni(HCO₃)₂ nanoplates (NHC) with horizontal interfaces sites of Ni-terminated NiO, NiOOH, NiCOO, and Ni(OH)₂ were employed as the hydroxyl adsorption active sites, which could anchor Pt particles with hydrogen adsorption active sites, constructing the synergistic active sites (NHC-Pt) for HER catalysis. Evidenced by X-ray photoelectron spectroscopy (XPS) and extended X-ray absorption fine structure (EXAFS), the NHC could affect the chemical state and electronic structure of Pt particles by forming bond of Pt-O which could reduce the reaction energy barriers, facilitate the adsorption of hydrogen and establishment of H–H bond. Furthermore, density functional theory (DFT) theoretical calculation revealed that the related process of hydroxide was the rate-determining step. It is demonstrated the hydroxyl group presents the lowest energy barrier for desorption in the process of HER when the gradual desorption process could be described as a migration from Ni(HCO₃)₂·OH directly or via other Ni-based systems formed after partial decomposition of nickel hydrocarbonate to Ni(OH)₂···OH with following desorption. As a result, the NHC-Pt hierarchical nanostructure demonstrated superior activity towards HER in a pH-universal solution. This enhancement can be attributed to the optimized electronic structure of Pt, the migration of hydroxyl group on NHC substrates, and the synergistic effects between the NHC carrier and Pt particles.
- Hydrogen evolution reaction,
- Density functional theory,
- Synergistic active sites,
- Pt-supported hierarchical nanostructure,
- Electrocatalysis
1. [1]
  R. Wu, J. Xu, C.L. Zhao, et al., Nat. Commun. 14 (2023) 2306. doi: 10.1038/s41467-023-37641-3
2. [2]
  L. Yang, R. Grzeschik, P. Jiang, et al., Angew. Chem. Int. Ed. 62 (2023) 202302126. doi: 10.1002/anie.202302126
3. [3]
  Y. Zhu, K. Fan, C.S. Hsu, et al., Adv. Mater. 35 (2023) 2301133. doi: 10.1002/adma.202301133
4. [4]
  Q. Li, Y. Gao, M. Liu, et al., J. Colloid Interface Sci. 646 (2023) 391–398. doi: 10.1016/j.jcis.2023.05.065
5. [5]
  Y. Lai, Z. Zhang, Z. Zhang, et al., Chem. Eng. J. 435 (2022) 135102. doi: 10.1016/j.cej.2022.135102
6. [6]
  K. Liu, H. Yang, Y. Jiang, et al., Nat. Commun. 14 (2023) 2424. doi: 10.1038/s41467-023-38018-2
7. [7]
  M. Cococcioni, S. de Gironcoli, Phys. Rev. B 71 (2005) 035105. doi: 10.1103/PhysRevB.71.035105
8. [8]
  Z. Wu, P. Yang, Q. Li, et al., Angew. Chem. Int. Ed. 62 (2023) 202300406. doi: 10.1002/anie.202300406
9. [9]
  P. Wang, Y. Yan, P. Wang, et al., Chem. Eng. J. 455 (2023) 140856. doi: 10.1016/j.cej.2022.140856
10. [10]
  J. Durst, A. Siebel, C. Simon, et al., Energy Environ. Sci. 7 (2014) 2255–2260. doi: 10.1039/C4EE00440J
11. [11]
  T.J. Schmidt, P.N. Ross, N.M. Markovic, J. Electroanal. Chem. 524–525 (2002) 252–260.
12. [12]
  W. Sheng, M. Myint, J.G. Chen, Y. Yan, Energy Environ. Sci. 6 (2013) 1509–1512. doi: 10.1039/c3ee00045a
13. [13]
  F. Li, G.F. Han, H.J. Noh, et al., Nat. Commun. 10 (2019) 4060. doi: 10.1038/s41467-019-12012-z
14. [14]
  W. Sheng, Z. Zhuang, M. Gao, et al., Nat. Commun. 6 (2015) 5848. doi: 10.1038/ncomms6848
15. [15]
  J. Zheng, W. Sheng, Z. Zhuang, B. Xu, Y. Yan, Sci. Adv. 2 (2016) 1501602. doi: 10.1126/sciadv.1501602
16. [16]
  K. Elbert, J. Hu, Z. Ma, et al., ACS Catal. 5 (2015) 6764–6772. doi: 10.1021/acscatal.5b01670
17. [17]
  S. Xu, M. Niu, G. Zhao, et al., Nano Res. 16 (2023) 6212–6219. doi: 10.1007/s12274-022-5250-1
18. [18]
  S. Lu, Z. Zhuang, J. Am. Chem. Soc. 139 (2017) 5156–5163. doi: 10.1021/jacs.7b00765
19. [19]
  Y. Wang, G. Wang, G. Li, et al., Energy Environ. Sci. 8 (2014) 177–181.
20. [20]
  L. Wang, H.N. Liu, X. Meng, et al., Rare Met. 43 (2024) 2851–2858. doi: 10.1007/s12598-024-02642-8
21. [21]
  J. Dai, Y. Zhu, H.A. Tahini, Nat. Commun. 11 (2020) 5657. doi: 10.1038/s41467-020-19433-1
22. [22]
  I.T. McCrum, M.T.M. Koper, Nat. Energy 5 (2020) 891–899. doi: 10.1038/s41560-020-00710-8
23. [23]
  R. Subbaraman, D. Tripkovic, D. Strmcnik, et al., Science 334 (2011) 1256–1260. doi: 10.1126/science.1211934
24. [24]
  E. Liu, J. Li, L. Jiao, et al., J. Am. Chem. Soc. 141 (2019) 3232–3239. doi: 10.1021/jacs.8b13228
25. [25]
  D. Strmcnik, M. Uchimura, C. Wang, et al., Nat. Chem. 5 (2013) 300–306. doi: 10.1038/nchem.1574
26. [26]
  M.Y. Fan, J.J. Wang, J. Zhao, et al., Rare Met. 43 (2024) 1537–1546. doi: 10.1007/s12598-023-02553-0
27. [27]
  B. Zhou, Y. Li, Y. Zou, et al., Angew. Chem. Int. Ed. 60 (2021) 22908–22914. doi: 10.1002/anie.202109211
28. [28]
  V.R. Stamenkovic, B.S. Mun, M. Arenz, et al., Nat. Mater. 6 (2007) 241–247. doi: 10.1038/nmat1840
29. [29]
  H. Yin, S. Zhao, K. Zhao, et al., Nat. Commun. 6 (2015) 6430. doi: 10.1038/ncomms7430
30. [30]
  Y. Wei, G. Cheng, J. Xiong, et al., ACS Sustain. Chem. Eng. 5 (2017) 5027–5038. doi: 10.1021/acssuschemeng.7b00417
31. [31]
  S. Zhao, Z. Wang, Y. He, et al., ACS Energy Lett. 2 (2017) 111–116. doi: 10.1021/acsenergylett.6b00582
32. [32]
  M. Lao, K. Rui, G. Zhao, et al., Angew. Chem. Int. Ed. 131 (2019) 5489–5491.
33. [33]
  B. Muthukutty, T.C. Doan, H. Yoo, Environ. Res. 241 (2024) 117655. doi: 10.1016/j.envres.2023.117655
34. [34]
  K.L. Zhou, C. Wang, Z. Wang, et al., Energy Environ. Sci. 13 (2020) 3082–3092. doi: 10.1039/D0EE01347A
35. [35]
  B. Pang, X. Liu, T. Liu, et al., Energy Environ. Sci. 15 (2022) 102–108. doi: 10.1039/D1EE02518J
36. [36]
  J. Zhang, Y. Zhao, X. Guo, et al., Nat. Catal. 1 (2018) 985–992. doi: 10.1038/s41929-018-0195-1
37. [37]
  C. Li, Z. Chen, H. Yi, et al., Angew. Chem. Int. Ed. 59 (2020) 15902–15907. doi: 10.1002/anie.202005282
38. [38]
  Y. Dong, Y. Ma, D. Li, et al., Chem. Sci. 9 (2018) 8682–8691. doi: 10.1039/C8SC02868K
39. [39]
  C. Rincke, S. Bette, R.E. Dinnebier, W. Voigt, Eur. J. Inorg. Chem. 2015 (2015) 5913–5920. doi: 10.1002/ejic.201501094
40. [40]
  J. Greeley, T.F. Jaramillo, J. Bonde, I. Chorkendorff, J.K. Nørskov, Nat. Mater. 5 (2006) 909–913. doi: 10.1038/nmat1752
41. [41]
  Y. Tang, B.L. Allen, D.R. Kauffman, A. Star, J. Am. Chem. Soc. 131 (2009) 13200–13201. doi: 10.1021/ja904595t
42. [42]
  C. Descorme, D. Duprez, Appl. Catal. A: Gen. 202 (2000) 231–241. doi: 10.1016/S0926-860X(00)00537-8
43. [43]
  M. Colin, D. Duprez, M. Pélissier, Stud. Surf. Sci. Catal. 112 (1997) 303–312.
44. [44]
  L. Cao, O. Petracic, X.K. Wei, Small 17 (2021) 2104356. doi: 10.1002/smll.202104356
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2. [2]
  Chunru Liu , Ligang Feng . Advances in anode catalysts of methanol-assisted water-splitting reactions for hydrogen generation. Chinese Journal of Structural Chemistry, 2023, 42(10): 100136-100136. doi: 10.1016/j.cjsc.2023.100136
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4. [4]
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  Bin Dong , Ning Yu , Qiu-Yue Wang , Jing-Ke Ren , Xin-Yu Zhang , Zhi-Jie Zhang , Ruo-Yao Fan , Da-Peng Liu , Yong-Ming Chai . Double active sites promoting hydrogen evolution activity and stability of CoRuOH/Co₂P by rapid hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109221-. doi: 10.1016/j.cclet.2023.109221
6. [6]
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7. [7]
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