Citation: Qing Li, Fangyu Fu, Mengyun Zhao, Yeqin Feng, Manzhou Chi, Zichen Zhao, Hongjin Lv, Guo-Yu Yang. Asymmetrically anchoring silver alkynyl cluster to the cobalt-containing polyoxometalate[J]. Chinese Chemical Letters, ;2025, 36(7): 110090. doi: 10.1016/j.cclet.2024.110090 shu

Asymmetrically anchoring silver alkynyl cluster to the cobalt-containing polyoxometalate

MOE Key Laboratory of Cluster Science, Beijing Key Laboratory of Photoelectric/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China

hlv@bit.edu.cn

Received Date: 8 May 2024
Revised Date: 25 May 2024
Accepted Date: 4 June 2024
Available Online: 4 June 2024

Figures(4)

Comparing to the conventional polyoxometalate (POM)-templated silver (Ag) clusters, asymmetrically covered POM-templated Ag clusters have been rarely reported. In this work, a new Ag cluster, H[Co(SiW₁₁O₃₉)Co₄(OH)₃(NO₃)₂(SiW₉O₃₄)@Ag₃₇(^tBuC≡C)₂₃(NO₃)₂(DMF)₃] (Ag₃₇Co₅), has been successfully prepared using a facile solvothermal approach. Such a unique asymmetrical architecture is ascribed to the uneven charge distribution of the in situ generated [Co(SiW₁₁O₃₉)]⁶⁻ and [Co₄(OH)₃(NO₃)₂(SiW₉O₃₄)]⁷⁻ moieties, leading to the asymmetrical coverage of alkynyl-protected Ag shell. Various physicochemical and catalytic studies revealed that the resulting solid-state Ag₃₇Co₅ crystals exhibited interesting temperature-dependent photoluminescence property, efficient and recyclable photothermal conversion ability, and good catalytic activity towards the detoxication of 4-nitrophenol.
- Polyoxometalate,
- Silver clusters,
- Photothermal conversion,
- 4-Nitrophenol reduction,
- Temperature-dependent photoluminescence
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