Citation: Xinlin Zhang, Cheng Tang, Haitao Li, Jie Sun, Aijun Du, Minghong Wu, Haijiao Zhang. Robust assembly of TiO₂ quantum dots onto Ti₃C₂T_x for excellent lithium storage capability[J]. Chinese Chemical Letters, ;2025, 36(6): 110088. doi: 10.1016/j.cclet.2024.110088 shu

Robust assembly of TiO₂ quantum dots onto Ti₃C₂T_x for excellent lithium storage capability

Xinlin Zhang ^a ,
Cheng Tang ^b ,
Haitao Li ^a ,
Jie Sun ^a ,
Aijun Du ^b ,
Minghong Wu ^a ,
Haijiao Zhang ^{a, c, *,}

a.
Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
b.
School of Chemistry and Physics and Centre for Materials Science, Queensland University of Technology, Brisbane, QLD 4001, Australia
c.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

hjzhang128@shu.edu.cn

Received Date: 21 May 2024
Accepted Date: 4 June 2024
Available Online: 4 June 2024

Figures(5)

TiO₂ has been widely studied as one of the most promising anode materials for lithium-ion batteries (LIBs) due to good structural stability and small volume changes. However, its applications are still greatly affected by its poor electrical conductivity. In this work, ultrasmall TiO₂ quantum dots (QDs) are firmly grown onto 2D Ti₃C₂T_x nanosheets (A-TiO₂/Ti₃C₂T_x), benefiting from the positive regulation of (3-aminopropyl)triethoxysilane (APTES). Interestingly, SiO₂ nanoparticles produced by the hydrolysis of APTES can strengthen the strong coupling of TiO₂ QDs with Ti₃C₂T_x, thereby enhancing the structural integrity of the composite. As expected, the A-TiO₂/Ti₃C₂T_x composite demonstrates an exceptional lithium storage performance, achieving a high capacity of 425.4 mAh/g for 400 cycles at 0.1 A/g, and an outstanding long-term cycling stability. In-situ electrochemical impedance spectroscopy and theoretical analysis unconver that the superior lithium storage performance is attributed to its unique heterostructure and in-situ N doping derived from APTES, which not only reduces the Li⁺ adsorption energy, but also gives the fast charge transfer dynamics.
- TiO₂ quantum dots,
- Ti₃C₂T_x MXene,
- Robust assembly,
- Lithium-ion batteries,
- Anode materials
1. [1]
  X. Xiao, Z.J. Zhang, W.T. Yu, et al., Appl. Energy 328 (2022) 120186. doi: 10.1016/j.apenergy.2022.120186
2. [2]
  F.Y. He, C. Tang, Y.D. Liu, et al., J. Mater. Sci. Technol. 100 (2022) 101–109. doi: 10.1016/j.jmst.2021.05.048
3. [3]
  L. Luo, K. Liang, Z. Khanam, et al., Small 20 (2024) 2307103. doi: 10.1002/smll.202307103
4. [4]
  C.F. Zhang, M. Beidaghi, M. Naguib, et al., Chem. Mater. 28 (2016) 3937–3943. doi: 10.1021/acs.chemmater.6b01244
5. [5]
  J. Jang, H. s. Kim, S. Moon, et al., Nano Lett. 22 (2022) 761–767. doi: 10.1021/acs.nanolett.1c04290
6. [6]
  M.H. Wu, L.B. Gu, Q. Wang, et al., ChemNanoMat 4 (2018) 387–393. doi: 10.1002/cnma.201700369
7. [7]
  C.F. Zhang, S.J. Kim, M. Ghidiu, et al., Adv. Funct. Mater. 26 (2016) 4143–4151. doi: 10.1002/adfm.201600682
8. [8]
  I.Z. Nejad, N. Zolfaghari, M.M. Mashhadi, et al., Sustain. Energy Technol. Assess. 47 (2021) 101438.
9. [9]
  W.L. Cai, C. Yan, Y.X. Yao, et al., Small Struct. 1 (2020) 2000010. doi: 10.1002/sstr.202000010
10. [10]
  H.T. Li, F.T. Lv, X. Fang, et al., Carbon Neutral. 2 (2023) 678–688. doi: 10.1002/cnl2.93
11. [11]
  Y.P. Wang, P.C. Yuan, Z.Y. Xu, et al., Chin. Chem. Lett. 35 (2024) 108776. doi: 10.1016/j.cclet.2023.108776
12. [12]
  H.A. Tariq, U. Nisar, J.J. Abraham, et al., Appl. Surf. Sci. 583 (2022) 152441. doi: 10.1016/j.apsusc.2022.152441
13. [13]
  L. Li, G.X. Jiang, C.H. An, et al., Nanoscale 12 (2020) 10369–10379. doi: 10.1039/d0nr01222j
14. [14]
  M.H. Wu, Y.P. Gao, Y. Hu, et al., Chin. Chem. Lett. 31 (2020) 897–902. doi: 10.1016/j.cclet.2019.07.039
15. [15]
  H. Zhang, L. Yang, P.G. Zhang, et al., Adv. Mater. 33 (2021) 2008447. doi: 10.1002/adma.202008447
16. [16]
  L. Petrizza, D. Genovese, G. Valenti, et al., Electroanalysis 28 (2016) 2777–2784. doi: 10.1002/elan.201600262
17. [17]
  X.L. Liu, Y.X. Chen, H.B. Liu, et al., J. Mater. Sci. Technol. 33 (2017) 239–245. doi: 10.1016/j.jmst.2016.07.021
18. [18]
  Y. Zhang, Z.H. Bao, R. Wang, et al., Nanoscale 16 (2024) 1751–1757. doi: 10.1039/d3nr05723b
19. [19]
  J.P. Yang, Y.X. Wang, W. Li, et al., Adv. Mater. 29 (2017) 1700523. doi: 10.1002/adma.201700523
20. [20]
  N. Talreja, M. Ashfaq, D. Chauhan, et al., Mater. Chem. Phys. 294 (2023) 127029. doi: 10.1016/j.matchemphys.2022.127029
21. [21]
  Q. Liu, Y.X. Ji, X.M. Yin, et al., Energy Storage Mater. 46 (2022) 384–393. doi: 10.1016/j.ensm.2021.12.017
22. [22]
  Y.C. Zhang, Y. Tian, Z.R. Wang, et al., Chem. Eng. J. 458 (2023) 141388. doi: 10.1016/j.cej.2023.141388
23. [23]
  N. Huang, C. Tang, H. Jiang, et al., Nano Res. 17 (2023) 2619–2627.
24. [24]
  C. Yang, Y. Liu, X. Sun, et al., Electrochim. Acta 271 (2018) 165–172. doi: 10.1016/j.electacta.2018.03.118
25. [25]
  X.F. Lou, Y.Y. Zhang, L. Zhao, et al., Sci. Rep. 13 (2023) 18560. doi: 10.1038/s41598-023-45763-3
26. [26]
  Y. Li, S. Wang, D.N. Lei, et al., J. Mater. Chem. A 5 (2017) 12236–12242. doi: 10.1039/C7TA02361H
27. [27]
  H.L. Wang, P.C. Zhang, P.F. Huang, J. Chem. Technol. Biotechnol. 97 (2022) 2815–2819. doi: 10.1002/jctb.7150
28. [28]
  W. Devina, D. Nam, J. Hwang, et al., Electrochim. Acta 321 (2019) 134639. doi: 10.1016/j.electacta.2019.134639
29. [29]
  Y.J. Zheng, B.J. Liu, P. Cao, et al., J. Mater. Sci. Technol. 35 (2019) 667–673. doi: 10.1016/j.jmst.2018.10.028
30. [30]
  W.L. Xu, Y.L. Xu, T. Schultz, et al., ACS Appl. Mater. Interfaces 15 (2022) 795–805.
31. [31]
  G. Hasegawa, T. Sato, K. Kanamori, et al., New J. Chem. 38 (2014) 1380–1384. doi: 10.1039/c3nj01332d
32. [32]
  D. McNulty, E. Carroll, C. O'Dwyer, Adv. Energy Mater. 7 (2017) 1602291. doi: 10.1002/aenm.201602291
33. [33]
  M.N. Hyder, B.M. Gallant, N.J. Shah, et al., Nano Lett. 13 (2013) 4610–4619. doi: 10.1021/nl401387s
34. [34]
  M.N. Tahir, B. Oschmann, D. Buchholz, et al., Adv. Energy Mater. 6 (2016) 1501489. doi: 10.1002/aenm.201501489
35. [35]
  F.Y. He, C. Tang, G.J. Zhu, et al., Sci. China Chem. 64 (2021) 964–973. doi: 10.1007/s11426-020-9942-9
36. [36]
  D.P. Li, X.H. Ren, Q. Ai, et al., Adv. Energy Mater. 8 (2018) 1802386. doi: 10.1002/aenm.201802386
37. [37]
  W.X. Zhao, X.Q. Ma, X.D. Wang, et al., J. Mater. Chem. A 11 (2023) 2431–2442. doi: 10.1039/d2ta08276d
38. [38]
  L.B. Tang, P.Y. Li, R.D. Cui, et al., Small Methods 7 (2023) 2201387. doi: 10.1002/smtd.202201387
39. [39]
  S.F. Ho, H.Y. Tuan, Chem. Eng. J. 452 (2023) 139199. doi: 10.1016/j.cej.2022.139199
40. [40]
  D.G. Sun, C. Tang, H. Cheng, et al., J. Energy Chem. 72 (2022) 479–486. doi: 10.1016/j.jechem.2022.05.043
41. [41]
  M.M. Abdelaal, C.C. Yang, T.F. Hung, J. Energy Storage 77 (2024) 109926. doi: 10.1016/j.est.2023.109926
1. [1]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
2. [2]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
3. [3]
  Junqi Wang , Shuai Zhang , Jingjing Ma , Xiangjun Liu , Yayun Ma , Zhimin Fan , Jingfeng Wang . Augmenting levoglucosan production through catalytic pyrolysis of biomass exploiting Ti₃C₂T_x MXene. Chinese Chemical Letters, 2024, 35(12): 109725-. doi: 10.1016/j.cclet.2024.109725
4. [4]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123
5. [5]
  Guihuang Fang , Ying Liu , Yangyang Feng , Ying Pan , Hongwei Yang , Yongchuan Liu , Maoxiang Wu . Tuning the ion-dipole interactions between fluoro and carbonyl (EC) by electrolyte design for stable lithium metal batteries. Chinese Chemical Letters, 2025, 36(1): 110385-. doi: 10.1016/j.cclet.2024.110385
6. [6]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
7. [7]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2024.100309
8. [8]
  Hui Gu , Mingyue Gao , Kuan Shen , Tianli Zhang , Junhao Zhang , Xiangjun Zheng , Xingmei Guo , Yuanjun Liu , Fu Cao , Hongxing Gu , Qinghong Kong , Shenglin Xiong . F127 assisted fabrication of Ge/rGO/CNTs nanocomposites with three-dimensional network structure for efficient lithium storage. Chinese Chemical Letters, 2024, 35(9): 109273-. doi: 10.1016/j.cclet.2023.109273
9. [9]
  Sheng Zhao , Junjie Lu , Bifu Sheng , Siying Zhang , Hao Li , Jizhang Chen , Xiang Han . High-performance room temperature solid-state lithium battery enabled by PP-PVDF multilayer composite electrolyte. Chinese Chemical Letters, 2025, 36(6): 110008-. doi: 10.1016/j.cclet.2024.110008
10. [10]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
11. [11]
  Peng Zhou , Ziang Jiang , Yang Li , Peng Xiao , Feixiang Wu . Sulphur-template method for facile manufacturing porous silicon electrodes with enhanced electrochemical performance. Chinese Chemical Letters, 2024, 35(8): 109467-. doi: 10.1016/j.cclet.2023.109467
12. [12]
  Guihuang Fang , Wei Chen , Hongwei Yang , Haisheng Fang , Chuang Yu , Maoxiang Wu . Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive. Chinese Chemical Letters, 2024, 35(6): 108799-. doi: 10.1016/j.cclet.2023.108799
13. [13]
  Wendi Dou , Guangying Wan , Tiefeng Liu , Lin Han , Wu Zhang , Chuang Sun , Rensheng Song , Jianhui Zheng , Yujing Liu , Xinyong Tao . Conductive composite binder for recyclable LiFePO₄ cathode. Chinese Chemical Letters, 2024, 35(11): 109389-. doi: 10.1016/j.cclet.2023.109389
14. [14]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
15. [15]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
16. [16]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . Hierarchical MoS₂/Ti₃C₂T_x heterostructure with excellent photothermal conversion performance for solar-driven vapor generation. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-. doi: 10.1016/j.actphy.2025.100053
17. [17]
  Xiangyue Li , Dexin Zhu , Kunmin Pan , Xiaoye Zhou , Jiaming Zhu , Yingxue Wang , Yongpeng Ren , Hong-Hui Wu . Identifying key determinants of discharge capacity in ternary cathode materials of lithium-ion batteries. Chinese Chemical Letters, 2025, 36(5): 109870-. doi: 10.1016/j.cclet.2024.109870
18. [18]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
19. [19]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
20. [20]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(151)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Robust assembly of TiO2 quantum dots onto Ti3C2Tx for excellent lithium storage capability

Metrics

通讯作者: 陈斌, bchen63@163.com

Robust assembly of TiO₂ quantum dots onto Ti₃C₂T_x for excellent lithium storage capability