Citation: Yanxue Wu, Xijun Xu, Shanshan Shi, Fangkun Li, Shaomin Ji, Jingwei Zhao, Jun Liu, Yanping Huo. Facile construction of Cu_2-xSe@C nanobelts as anode for superior sodium-ion storage[J]. Chinese Chemical Letters, ;2025, 36(6): 110062. doi: 10.1016/j.cclet.2024.110062 shu

Facile construction of Cu_2-xSe@C nanobelts as anode for superior sodium-ion storage

Yanxue Wu ^a ,
Xijun Xu ^{b, d,} ,
Shanshan Shi ^c ,
Fangkun Li ^e ,
Shaomin Ji ^{b, d} ,
Jingwei Zhao ^f ,
Jun Liu ^e, ,
Yanping Huo ^{a, b, d,}

a.
Analysis and Test Center, Guangdong University of Technology, Guangzhou 510006, China
b.
Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center, Jieyang 515200, China
c.
R & D Center, Yunnan Yuntianhua Co., Ltd., Kunming 650228, China
d.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China
e.
Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China
f.
Research and Development Center, Guangzhou Tinci Materials Technology Co., Ltd., Guangzhou 510765, China

Received Date: 30 April 2024
Accepted Date: 27 May 2024
Available Online: 28 May 2024

Figures(6)

Transition metal selenides are considered promising electrochemical energy storage materials due to their excellent rate properties and high capacity based on multi-step conversion reactions. However, its practical applications are hampered by poor conductivity and large volume variation for Na⁺ storage, which resulting fast capacity decay. Herein, a facile metal-organic framework (MOF) derived method is explored to embed Cu_2-xSe@C particles into a carbon nanobelts matrix. Such carbon encapsulated nanobelts' structural moderate integral electronic conductivity and maintained the structure from collapsing during Na⁺ insertion/extraction. Furthermore, the porous structure of these nanobelts endows enough void space to mitigate volume stress and provide more diffusion channels for Na⁺/electrons transporting. Due to the unique structure, these Cu_2-xSe@C nanobelts achieved ultra-stable cycling performance (170.7 mAh/g at 1.0 A/g after 1000 cycles) and superior rate capability (94.6 mAh/g at 8 A/g) for sodium-ion batteries. The kinetic analysis reveals that these Cu_2-xSe@C nanobelts with considerable pesoudecapactive contribution benefit the rapid sodiation/desodiation. This rational design strategy broadens an avenue for the development of metal selenide materials for energy storage devices.
- Cu_2-xSe@C,
- Nanobelts,
- Metal-organic framework (MOF),
- Anode,
- Sodium-ion batteries
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Facile construction of Cu2-xSe@C nanobelts as anode for superior sodium-ion storage

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通讯作者: 陈斌, bchen63@163.com

Facile construction of Cu_2-xSe@C nanobelts as anode for superior sodium-ion storage