Citation: Hui Yang, Guangxun Zhang, Yueyao Sun, Huijie Zhou, Huan Pang. Bimetallic zeolitic imidazolate framework derived hollow layered double hydroxide with tailorable interlayer spacing for nickel-zinc batteries[J]. Chinese Chemical Letters, ;2025, 36(6): 110016. doi: 10.1016/j.cclet.2024.110016 shu

Bimetallic zeolitic imidazolate framework derived hollow layered double hydroxide with tailorable interlayer spacing for nickel-zinc batteries

School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225009, China

panghuan@yzu.edu.cn

Received Date: 18 March 2024
Revised Date: 18 April 2024
Accepted Date: 14 May 2024
Available Online: 16 May 2024

Figures(6)

Rationally design the morphology and structure of electroactive nanomaterials is an effective approach to enhance the performance of aqueous batteries. Herein, we co-engineered the hollow architecture and interlayer spacing of layered double hydroxides (LDH) to achieve high electrochemical activity. The hierarchical hollow LDH was prepared from bimetallic zeolitic imidazolate frameworks (ZIF) by a facile cation exchange strategy. Zn and Cu elements were selected as the second metals incorporated in Co-ZIF. The characteristics of the corresponding derivatives were studied. Besides, the transformation mechanism of CoZn-ZIF into nanosheet-assembled hollow CoZnNi LDH (denoted as CoZnNi-OH) was systematically investigated. Importantly, the interlayer spacing of CoZnNi-OH expands due to Zn²⁺ incorporation. The prepared CoZnNi-OH offers large surface area, exposed active sites, and rapid mass transfer/diffusion rate, which lead to a significant enhancement in the specific capacitance, rate performance, and cycle stability of CoZnNi-OH electrode. In addition, the aqueous alkaline CoZnNi-OH//Zn showed a maximum energy density/power density of 0.924 mWh/cm², 8.479 mW/cm². This work not only raises an insightful strategy for regulating the morphology and interlayer spacing of LDH, but also provides a reference of designing hollow nickel-based nanomaterials for aqueous batteries.
- Nickel-zinc battery,
- Hollow,
- Interlayer spacing,
- Layered double hydroxide,
- Zeolitic imidazolate framework
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