Citation: Xi Tang, Chunlei Zhu, Yulu Yang, Shihan Qi, Mengqiu Cai, Abdullah N. Alodhayb, Jianmin Ma. Additive regulating Li⁺ solvation structure to construct dual LiF−rich electrode electrolyte interphases for sustaining 4.6 V Li||LiCoO₂ batteries[J]. Chinese Chemical Letters, ;2024, 35(12): 110014. doi: 10.1016/j.cclet.2024.110014 shu

Additive regulating Li⁺ solvation structure to construct dual LiF−rich electrode electrolyte interphases for sustaining 4.6 V Li||LiCoO₂ batteries

a.
School of Physics and Electronics, Hunan University, Changsha 410082, China
b.
Department of Physics and Astronomy, College of Science, King Saud University, Riyadh 11451, Saudi Arabia

nanoelechem@hnu.edu.cn

Received Date: 29 June 2023
Revised Date: 8 April 2024
Accepted Date: 14 May 2024
Available Online: 11 September 2024

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The battery energy density can be improved by raising the operating voltage, however, which may lead to rapid capacity decay due to the continuous electrolyte decomposition and the thickening of electrode electrolyte interphases. To address these challenges, we proposed tripropyl phosphate (TPP) as an additive−regulating Li⁺ solvation structure to construct a stable LiF–rich electrode carbonate−based electrolyte interphases for sustaining 4.6 V Li||LiCoO₂ batteries. This optimized interphases could help reduce the resistance and achieve better rate performance and cycling stability. As expected, the Li||LiCoO₂ battery retained 79.4% capacity after 100 cycles at 0.5 C, while the Li||Li symmetric cell also kept a stable plating/stripping process over 450 h at the current density of 1.0 mA/cm² with a deposited amount of 0.5 mAh/cm².
- Lithium metal batteries,
- Electrolyte additive,
- Solid electrolyte interphase,
- Cathode electrolyte interphase,
- Solvation structure
1. [1]
  J.C. Zhang, Z.D. Liu, C.H. Zeng, et al., Rare Met. 41 (2022) 3946–3956. doi: 10.1007/s12598-022-02070-6
2. [2]
  D. Li, B. Zhang, X. Ou, et al., Chin. Chem. Lett. 32 (2021) 2333–2337. doi: 10.1016/j.cclet.2020.11.074
3. [3]
  Q. Wu, B. Zhang, Y. Lu, J. Energy Chem. 74 (2022) 283–308. doi: 10.1016/j.jechem.2022.07.007
4. [4]
  Y. Wang, Q. Zhang, Z.C. Xue, et al., Adv. Energy Mater. 10 (2020) 2001413. doi: 10.1002/aenm.202001413
5. [5]
  J. Huang, Y. Zhu, Y. Feng, et al., Acta Phys. Chim. Sin. 38 (2022) 2208008.
6. [6]
  X. Chen, Q. Sun, J. Xie, et al., J. Energy Chem. 74 (2022) 91–99. doi: 10.1016/j.jechem.2022.07.006
7. [7]
  G.G. Bizuneh, C. Zhu, J. Huang, et al., Small Methods 7 (2023) 2300079. doi: 10.1002/smtd.202300079
8. [8]
  J. Liu, M. Wu, X. Li, et al., Adv. Energy Mater. 13 (2023) 2300084. doi: 10.1002/aenm.202300084
9. [9]
  K. Guo, C. Zhu, H. Wang, et al., Adv. Energy Mater. 13 (2023) 2204272. doi: 10.1002/aenm.202204272
10. [10]
  F. Xian, J. Li, Z. Hu, et al., Chem. Commun. 56 (2020) 4998–5001. doi: 10.1039/D0CC00049C
11. [11]
  J. Zhang, H. Zhang, S. Weng, et al., Nat. Commun. 14 (2023) 2211. doi: 10.1038/s41467-023-37999-4
12. [12]
  Z. Sun, H. Zhou, X. Luo, et al., J. Power Sources 503 (2021) 230033. doi: 10.1016/j.jpowsour.2021.230033
13. [13]
  Y. Lyu, X. Wu, K. Wang, et al., Adv. Energy Mater. 11 (2021) 2000982. doi: 10.1002/aenm.202000982
14. [14]
  X. Hu, J. Liu, Y. Yang, et al., Chin. Chem. Lett. 34 (2023) 108456. doi: 10.1016/j.cclet.2023.108456
15. [15]
  R. Yu, Z. Li, X. Zhang, X. Guo, Chem. Commun. 58 (2022) 8994–8997. doi: 10.1039/D2CC03096A
16. [16]
  H. Wang, J. He, J. Liu, et al., Adv. Funct. Mater. 31 (2021) 2002578. doi: 10.1002/adfm.202002578
17. [17]
  S. Qi, J. He, J. Liu, et al., Adv. Funct. Mater. 31 (2021) 2009013. doi: 10.1002/adfm.202009013
18. [18]
  B. Roy, P. Cherepanov, C. Nguyen, et al., Adv. Energy Mater. 11 (2021) 2101422. doi: 10.1002/aenm.202101422
19. [19]
  F. Li, J. He, J. Liu, et al., Angew. Chem. Int. Ed. 60 (2021) 6600–6608. doi: 10.1002/anie.202013993
20. [20]
  W. Xue, R. Gao, Z. Shi, et al., Energy Environ. Sci. 14 (2021) 6030–6040. doi: 10.1039/D1EE01265G
21. [21]
  W. Lu, J. Zhang, J. Xu, X. Wu, L. Chen, ACS Appl. Mater. Interfaces 9 (2017) 19313–19318. doi: 10.1021/acsami.7b03024
22. [22]
  K. Zhang, J. Chen, W. Feng, et al., J. Power Sources 553 (2023) 232311. doi: 10.1016/j.jpowsour.2022.232311
23. [23]
  H. Zhang, Z. Zeng, S. Wang, et al., Nano Res. 17 (2024) 2638–2645. doi: 10.1007/s12274-023-6056-5
24. [24]
  S. Tan, Z. Shadike, J. Li, et al., Nat. Energy 7 (2022) 484–494. doi: 10.1038/s41560-022-01020-x
25. [25]
  Z. Guo, H. Yang, Q. Wei, et al., Chin. Chem. Lett. 34 (2023) 108622.
26. [26]
  X. Yang, M. Lin, G. Zheng, et al., Adv. Funct. Mater. 30 (2020) 2004664. doi: 10.1002/adfm.202004664
27. [27]
  Z. Qin, B. Hong, B. Duan, et al., Electrochim. Acta 276 (2018) 412–416. doi: 10.1016/j.electacta.2018.04.193
28. [28]
  Y. Sun, J. Huang, H. Xiang, et al., J. Mater. Sci. Technol. 55 (2020) 198–202. doi: 10.1016/j.jmst.2019.11.002
29. [29]
  P. Shi, H. Zheng, X. Liang, et al., Chem. Commun. 54 (2018) 4453–4456. doi: 10.1039/C8CC00994E
30. [30]
  G. Jiang, J. Liu, Z. Wang, J. Ma, Adv. Funct. Mater. 33 (2023) 2300629. doi: 10.1002/adfm.202300629
31. [31]
  T. Zheng, B. Zhu, J. Xiong, et al., Energy Stor. Mater. 59 (2023) 102782.
32. [32]
  H. Zhao, Y. Qian, S. Hu, et al., ACS Appl. Mater. Interfaces 13 (2021) 29676–29690. doi: 10.1021/acsami.1c06890
33. [33]
  J. Tan, J. Matz, P. Dong, J. Shen, M. Ye, Adv. Energy Mater. 11 (2021) 2100046. doi: 10.1002/aenm.202100046
34. [34]
  D. Wu, J. He, J. Liu, et al., Adv. Energy Mater. 12 (2022) 2200337. doi: 10.1002/aenm.202200337
35. [35]
  C. Yang, X. Liao, X. Zhou, et al., Adv. Mater. 35 (2023) 2210966. doi: 10.1002/adma.202210966
36. [36]
  R. Qi, M. Yang, T. Zheng, et al., Small 20 (2024) 2312087. doi: 10.1002/smll.202312087
37. [37]
  J. Liu, B. Yuan, N. He, et al., Energy Environ. Sci. 16 (2023) 1024–1034. doi: 10.1039/D2EE02411J
38. [38]
  P. Bai, X. Ji, J. Zhang, et al., Angew. Chem. Int. Ed. 61 (2022) e202202731. doi: 10.1002/anie.202202731
39. [39]
  Q.K. Zhang, X.Q. Zhang, J. Wan, et al., Nat. Energy 8 (2023) 725–735. doi: 10.1038/s41560-023-01275-y
40. [40]
  X.Q. Zhang, X.B. Cheng, X. Chen, C. Yan, Q. Zhang, Adv. Funct. Mater. 27 (2017) 1605989. doi: 10.1002/adfm.201605989
41. [41]
  M.Y. Zhou, X.Q. Ding, J.F. Ding, et al., Joule 6 (2022) 2122–2137. doi: 10.1016/j.joule.2022.07.003
42. [42]
  S. Liu, J. Xia, W. Zhang, et al., Angew. Chem. Int. Ed. 61 (2022) e202210522. doi: 10.1002/anie.202210522
43. [43]
  H. Su, Z. Chen, M. Li, et al., Adv. Mater. 35 (2023) 2301171. doi: 10.1002/adma.202301171
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Additive regulating Li+ solvation structure to construct dual LiF−rich electrode electrolyte interphases for sustaining 4.6 V Li||LiCoO2 batteries

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通讯作者: 陈斌, bchen63@163.com

Additive regulating Li⁺ solvation structure to construct dual LiF−rich electrode electrolyte interphases for sustaining 4.6 V Li||LiCoO₂ batteries