Citation: Hongyu Tang, Dongming Liu, Jinfu Huang, Liang Zhang, Yang Tang, Bin Huang, Yanwei Li, Shunhua Xiao, Yiling Sun, Renheng Wang. Excellent structural stability and electrochemical properties of LiNi_0.9Co_0.05Mn_0.05O₂ material by surface Ni²⁺ anchoring and Cs⁺ doping[J]. Chinese Chemical Letters, ;2025, 36(6): 109987. doi: 10.1016/j.cclet.2024.109987 shu

Excellent structural stability and electrochemical properties of LiNi_0.9Co_0.05Mn_0.05O₂ material by surface Ni²⁺ anchoring and Cs⁺ doping

Hongyu Tang ^a ,
Dongming Liu ^b ,
Jinfu Huang ^a ,
Liang Zhang ^a ,
Yang Tang ^a ,
Bin Huang ^a ,
Yanwei Li ^a ,
Shunhua Xiao ^{a, *,} ,
Yiling Sun ^{b, *,} ,
Renheng Wang ^{b, c, *,}

a.
Guangxi Colleges and Universities Key Laboratory of Surface and Interface Electrochemistry, Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China
b.
Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, State Key Laboratory of Radio Frequency Heterogeneous Integration (Shenzhen University), College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China
c.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

1999014@glut.edu.cn

sunyl@szu.edu.cn

wangrh@szu.edu.cn

Received Date: 16 February 2024
Revised Date: 15 April 2024
Accepted Date: 9 May 2024
Available Online: 15 May 2024

Figures(5)

The ultra-high nickel cathode material has important application prospect in power lithium-ion batteries. However, the poor structural stability and serious surface/interfacial side reactions during long cycles severely hinder the material's practical application. In this paper, Cs⁺ doping and polymethyl methacrylate (PMMA) coating are used to synergistically modify the NCM955 material. The results show that the corresponding discharge specific capacity of NCMCs-2@P-2 material reaches 152.02 mAh/g at 1 C (1 C = 200 mA/g) and 125.66 mAh/g at 5 C after 300 cycles, and the capacity retention is 78.11% and 72.21%, respectively. In addition, it still maintains 156.36 mAh/g discharge specific capacity at 10 C, and these rate and cycle properties exceed those reported on ultra-high nickel cathode material. Moreover, NCMCs-2@P-2 material has higher migration energy barrier of Ni²⁺ and lower migration energy barrier of Li⁺ than that of NCM955 material. Therefore, NCMCs-2@P-2 material has excellent electrochemical properties, which has been proved by a series of structural characterization, theoretical calculation and performance test. The synergistic enhancement of Cs⁺ doping and PMMA coating accelerates lithium ion diffusion kinetics, stabilizes crystal structure, and inhabits surface/interface side reaction.
- LiNi_0.9Co_0.05Mn_0.05O₂ material,
- Cs⁺ doping,
- PMMA coating,
- Electrochemical performance,
- Electrochemical mechanism
1. [1]
  J.Q. Peng, Y.Y. Wei, D.M. Liu, et al., Rare Metals 43 (2023) 658–670.
2. [2]
  L. Wang, R. Wang, Q. Shi, et al., Appl. Surf. Sci. 605 (2022) 154684. doi: 10.1016/j.apsusc.2022.154684
3. [3]
  Q.C. Wang, Z. Xu, X.L. Li, et al., Nano Energy 119 (2024) 109019. doi: 10.1016/j.nanoen.2023.109019
4. [4]
  X. Wang, B. Zhang, Z. Xiao, et al., Chin. Chem. Lett. 34 (2023) 107772. doi: 10.1016/j.cclet.2022.107772
5. [5]
  H. Xie, H. Peng, D. Jiang, et al., Chem. Eng. J. 470 (2023) 144051. doi: 10.1016/j.cej.2023.144051
6. [6]
  H. Jiang, X. Xu, Q. Guo, et al., J. Energy Chem. 78 (2023) 277–282. doi: 10.1016/j.jechem.2022.11.059
7. [7]
  J. Liu, X. Hu, S. Qi, et al., InfoMat 6 (2024) e12507. doi: 10.1002/inf2.12507
8. [8]
  Z. Wang, H. Zhu, H. Yu, et al., Chin. Chem. Lett. 34 (2023) 107718. doi: 10.1016/j.cclet.2022.07.061
9. [9]
  L. Zhang, D. Liu, J. Huang, et al., J. Energy Storage 78 (2024) 110073. doi: 10.1016/j.est.2023.110073
10. [10]
  B. Hu, J. Peng, D. Liu, et al., ACS Appl. Energ. Mater. 6 (2023) 5318–5330. doi: 10.1021/acsaem.3c00308
11. [11]
  N. Liu, L. Chen, H. Wang, et al., Chem. Eng. J. 472 (2023) 145113. doi: 10.1016/j.cej.2023.145113
12. [12]
  H. Hyun, H. Yoon, S. Choi, et al., Energy Environ. Sci. 16 (2023) 3968–3983. doi: 10.1039/d3ee02334f
13. [13]
  S.Q. Lu, Q. Zhang, F. Meng, et al., J. Am. Chem. Soc. 145 (2023) 7397–7407. doi: 10.1021/jacs.2c13787
14. [14]
  Y.H. Luo, Q.L. Pan, H.X. Wei, et al., eScience 4 (2024) 100229. doi: 10.1016/j.esci.2024.100229
15. [15]
  S. Liu, P.J. West, H. Zhong, et al., Chem. Mater. 35 (2023) 8857–8871. doi: 10.1021/acs.chemmater.3c00924
16. [16]
  L. Ni, H. Chen, J. Gao, et al., Nano Energy. 115 (2023) 108743. doi: 10.1016/j.nanoen.2023.108743
17. [17]
  Y. Zhou, H. Zhang, Y. Wang, et al., ACS Nano. 17 (2023) 20621–20633. doi: 10.1021/acsnano.3c07655
18. [18]
  G. Mao, Y. Yang, W. Jiao, et al., J. Mater. Sci. 57 (2022) 19892–19901. doi: 10.1007/s10853-022-07763-y
19. [19]
  W. Xiao, Y. Nie, C. Miao, et al., J. Colloid Interface Sci. 607 (2022) 1071–1082. doi: 10.1016/j.jcis.2021.09.067
20. [20]
  W. Zhang, X. Tang, L. Xiao, et al., J. Solid State Electrochem. 27 (2023) 1185–1194. doi: 10.1007/s10008-023-05427-8
21. [21]
  R. Zhang, C. Wang, P. Zou, et al., Nature 610 (2022) 67–73. doi: 10.1038/s41586-022-05115-z
22. [22]
  Z. Tan, Y. Li, X. Xi, et al., Electrochim. Acta 401 (2022) 139482. doi: 10.1016/j.electacta.2021.139482
23. [23]
  Q.Q. Qiu, S.S. Yuan, J. Bao, et al., J. Energy Chem. 61 (2021) 574–581. doi: 10.1016/j.jechem.2021.02.012
24. [24]
  F. Kong, C. Liang, R.C. Longo, et al., Chem. Mater. 28 (2016) 6942–6952. doi: 10.1021/acs.chemmater.6b02627
25. [25]
  W.W. Li, X.J. Zhang, J.J. Si, et al., Rare Metals 40 (2020) 1719–1726. doi: 10.3390/ma13071719
26. [26]
  S.T. Myung, F. Maglia, K.J. Park, et al., ACS Energy Lett. 2 (2016) 196–223.
27. [27]
  X. Xiong, D. Ding, Z. Wang, et al., J. Solid State Electrochem. 18 (2014) 2619–2624. doi: 10.1007/s10008-014-2519-7
28. [28]
  S. Liu, H. Wu, L. Huang, et al., J. Alloys Compd. 674 (2016) 447–454. doi: 10.1016/j.jallcom.2016.03.060
29. [29]
  L. Ban, Y. Yin, W. Zhuang, et al., Electrochim. Acta 180 (2015) 218–226. doi: 10.1016/j.electacta.2015.08.031
30. [30]
  J.H. Sung, T.W. Kim, H.K. Kang, et al., Korean J. Chem. Eng. 38 (2021) 1059–1065. doi: 10.1007/s11814-021-0766-8
31. [31]
  B. Liu, Z. Zhang, J. Wan, et al., Ionics (Kiel) 23 (2017) 1365–1374. doi: 10.1007/s11581-016-1950-4
32. [32]
  Y. Cao, X. Qi, K. Hu, et al., ACS Appl. Mater. Interfaces 10 (2018) 18270–18280. doi: 10.1021/acsami.8b02396
33. [33]
  S.W. Doo, S. Lee, H. Kim, et al., ACS Appl. Energ. Mater. 2 (2019) 6246–6253. doi: 10.1021/acsaem.9b00786
34. [34]
  Y. Han, S. Heng, Y. Wang, et al., ACS Energy Lett. 5 (2020) 2421–2433. doi: 10.1021/acsenergylett.0c01032
35. [35]
  Z. Chen, G.T. Kim, Y. Guang, et al., J. Power Sources 402 (2018) 263–271. doi: 10.1016/j.jpowsour.2018.09.049
36. [36]
  J. Leng, J. Wang, W. Peng, et al., Small 17 (2021) 2006869. doi: 10.1002/smll.202006869
37. [37]
  H. Li, P. Zhou, F. Liu, et al., Chem. Sci. 10 (2019) 1374–1379. doi: 10.1039/c8sc03385d
38. [38]
  J. Li, X. Wang, X. Kong, et al., ACS Sustain. Chem. Eng. 9 (2021) 10547–10556. doi: 10.1021/acssuschemeng.1c02486
39. [39]
  Q. Liu, X. Su, D. Lei, et al., Nat. Energy 3 (2018) 936–943. doi: 10.1038/s41560-018-0180-6
40. [40]
  D. Hu, Y. Su, L. Chen, et al., J. Energy Chem. 58 (2021) 1–8. doi: 10.1016/j.jechem.2020.09.031
41. [41]
  Y. Mao, X. Wang, S. Xia, et al., Adv. Funct. Mater. 29 (2019) 1900247. doi: 10.1002/adfm.201900247
42. [42]
  G.T. Park, H.H. Ryu, N.Y. Park, et al., J. Power Sources 442 (2019) 227242. doi: 10.1016/j.jpowsour.2019.227242
43. [43]
  H.H. Ryu, B. Namkoong, J.H. Kim, et al., ACS Energy Lett. 6 (2021) 2726–2734. doi: 10.1021/acsenergylett.1c01089
44. [44]
  Z. Tan, Y. Li, X. Xi, et al., ACS Sustain. Chem. Eng. 10 (2022) 3532–3545. doi: 10.1021/acssuschemeng.1c07941
45. [45]
  H. Tong, Q. Zhou, B. Zhang, et al., Eng. Sci. (2020) 25–32.
46. [46]
  U.H. Kim, L.Y. Kuo, P. Kaghazchi, et al., ACS Energy Lett. 4 (2019) 576–582. doi: 10.1021/acsenergylett.8b02499
47. [47]
  Z. Ye, L. Qiu, W. Yang, et al., Chem. Eur. J. 27 (2021) 4249–4269. doi: 10.1002/chem.202003987
48. [48]
  L. Wang, R. Wang, J. Wang, et al., ACS Appl. Mater. Interfaces 13 (2021) 8324–8336. doi: 10.1021/acsami.0c20100
49. [49]
  K. Zou, M. Jiang, Z. Zhao, et al., Chem. Eng. J. 476 (2023) 146793. doi: 10.1016/j.cej.2023.146793
50. [50]
  K. Zou, S. Xie, M. Jiang, et al., Chem. Eng. J. 483 (2024) 149189. doi: 10.1016/j.cej.2024.149189
51. [51]
  T. Lai, A. Sheng, Z. Zhang, et al., J. Power Sources 590 (2024) 233811. doi: 10.1016/j.jpowsour.2023.233811
52. [52]
  X. Li, T. Lai, A. Sheng, et al., J. Energy Storage 72 (2023) 108262. doi: 10.1016/j.est.2023.108262
53. [53]
  G.T. Park, S.B. Kim, B. Namkoong, et al., Angew. Chem. 135 (2023) e202314480. doi: 10.1002/ange.202314480
54. [54]
  K.J. Park, H.G. Jung, L.Y. Kuo, et al., Adv. Energy Mater. 8 (2018) 1801202. doi: 10.1002/aenm.201801202
55. [55]
  G.L. Xu, X. Liu, A. Daali, et al., Adv. Funct. Mater. 30 (2020) 2004748. doi: 10.1002/adfm.202004748
56. [56]
  L. Zhang, S. Wang, L. Zhu, et al., Nano Energy. 97 (2022) 107119. doi: 10.1016/j.nanoen.2022.107119
57. [57]
  H. Wu, J. Dong, Y. Zhang, et al., Adv. Funct. Mater. 33 (2023) 2303707. doi: 10.1002/adfm.202303707
58. [58]
  C. Wang, L. Han, R. Zhang, et al., Matter. 4 (2021) 2013–2026. doi: 10.1016/j.matt.2021.03.012
59. [59]
  F. Wu, N. Liu, L. Chen, et al., J. Energy Chem. 62 (2021) 351–358. doi: 10.1016/j.jechem.2021.03.035
60. [60]
  K. Min, C. Jung, D.S. Ko, et al., ACS Appl. Mater. Interfaces 10 (2018) 20599–20610. doi: 10.1021/acsami.8b05648
1. [1]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
2. [2]
  Renyuan Wang , Lei Ke , Houxiang Wang , Yueheng Tao , Yujie Cui , Peipei Zhang , Minjie Shi , Xingbin Yan . Facile synthesis of phenazine-conjugated polymer material with extraordinary proton-storage redox capability. Chinese Chemical Letters, 2025, 36(5): 109920-. doi: 10.1016/j.cclet.2024.109920
3. [3]
  Liang Ming , Dan Liu , Qiyue Luo , Chaochao Wei , Chen Liu , Ziling Jiang , Zhongkai Wu , Lin Li , Long Zhang , Shijie Cheng , Chuang Yu . Si-doped Li₆PS₅I with enhanced conductivity enables superior performance for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109387-. doi: 10.1016/j.cclet.2023.109387
4. [4]
  Qiao Wang , Ziling Jiang , Chuang Yu , Liping Li , Guangshe Li . Research progress of inorganic sodium ion conductors for solid-state batteries. Chinese Chemical Letters, 2025, 36(6): 110006-. doi: 10.1016/j.cclet.2024.110006
5. [5]
  Ziling Jiang , Chen Liu , Jie Yang , Xia Li , Chaochao Wei , Qiyue Luo , Zhongkai Wu , Lin Li , Liping Li , Shijie Cheng , Chuang Yu . Designing F-doped Li₃InCl₆ electrolyte with enhanced stability for all-solid-state lithium batteries in a wide voltage window. Chinese Chemical Letters, 2025, 36(6): 109741-. doi: 10.1016/j.cclet.2024.109741
6. [6]
  Junhao Dai , Zhu He , Xinhai Li , Guochun Yan , Hui Duan , Guangchao Li , Zhixing Wang , Huajun Guo , Wenjie Peng , Jiexi Wang . Ultrafast spray pyrolysis for synthesizing uniform Mg-doped LiNi_0.9Co_0.05Mn_0.05O₂. Chinese Chemical Letters, 2025, 36(6): 110063-. doi: 10.1016/j.cclet.2024.110063
7. [7]
  Fengyu Zhang , Yali Liang , Zhangran Ye , Lei Deng , Yunna Guo , Ping Qiu , Peng Jia , Qiaobao Zhang , Liqiang Zhang . Enhanced electrochemical performance of nanoscale single crystal NMC811 modification by coating LiNbO₃. Chinese Chemical Letters, 2024, 35(5): 108655-. doi: 10.1016/j.cclet.2023.108655
8. [8]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164
9. [9]
  Bing Jiang , Gang Zou , Bi Luo , Yan Guo , Jingru Li , Wendi Zhang , Qianxiao Fan , Lehao Liu , Lihua Chu , Qiaobao Zhang , Meicheng Li . Enhanced electrochemical performance of lithium-rich layered oxide materials: Exploring advanced coating strategies. Chinese Chemical Letters, 2025, 36(4): 109801-. doi: 10.1016/j.cclet.2024.109801
10. [10]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
11. [11]
  Jie Zhou , Chuanxiang Zhang , Changchun Hu , Shuo Li , Yuan Liu , Zhu Chen , Song Li , Hui Chen , Rokayya Sami , Yan Deng . Electrochemical aptasensor based on black phosphorus-porous graphene nanocomposites for high-performance detection of Hg²⁺. Chinese Chemical Letters, 2024, 35(11): 109561-. doi: 10.1016/j.cclet.2024.109561
12. [12]
  Yi ZHANG , Guang LI , Wenxuan FAN , Qingfeng YI . Influence of bismuth trisulfide on the electrochemical performance of iron electrode. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1196-1206. doi: 10.11862/CJIC.20240445
13. [13]
  Qian-Qian Tang , Li-Fang Feng , Zhi-Peng Li , Shi-Hao Wu , Long-Shuai Zhang , Qing Sun , Mei-Feng Wu , Jian-Ping Zou . Single-atom sites regulation by the second-shell doping for efficient electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(9): 109454-. doi: 10.1016/j.cclet.2023.109454
14. [14]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
15. [15]
  Peng Zhou , Ziang Jiang , Yang Li , Peng Xiao , Feixiang Wu . Sulphur-template method for facile manufacturing porous silicon electrodes with enhanced electrochemical performance. Chinese Chemical Letters, 2024, 35(8): 109467-. doi: 10.1016/j.cclet.2023.109467
16. [16]
  Tianbo Jia , Lili Wang , Zhouhao Zhu , Baikang Zhu , Yingtang Zhou , Guoxing Zhu , Mingshan Zhu , Hengcong Tao . Modulating the degree of O vacancy defects to achieve selective control of electrochemical CO₂ reduction products. Chinese Chemical Letters, 2024, 35(5): 108692-. doi: 10.1016/j.cclet.2023.108692
17. [17]
  Hengyi ZHU , Liyun JU , Haoyue ZHANG , Jiaxin DU , Yutong XIE , Li SONG , Yachao JIN , Mingdao ZHANG . Efficient regeneration of waste LiNi_0.5Co_0.2Mn_0.3O₂ cathode toward high-performance Li-ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 625-638. doi: 10.11862/CJIC.20240358
18. [18]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
19. [19]
  Yufei Jia , Fei Li , Ke Fan . Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100255-100255. doi: 10.1016/j.cjsc.2024.100255
20. [20]
  Xueyang Zhao , Bangwei Deng , Hongtao Xie , Yizhao Li , Qingqing Ye , Fan Dong . Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(7): 109139-. doi: 10.1016/j.cclet.2023.109139

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(144)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Excellent structural stability and electrochemical properties of LiNi0.9Co0.05Mn0.05O2 material by surface Ni2+ anchoring and Cs+ doping

Metrics

通讯作者: 陈斌, bchen63@163.com

Excellent structural stability and electrochemical properties of LiNi_0.9Co_0.05Mn_0.05O₂ material by surface Ni²⁺ anchoring and Cs⁺ doping