Citation: Shengyu Zhao, Xuan Yu, Yufeng Zhao. A water-stable high-voltage P3-type cathode for sodium-ion batteries[J]. Chinese Chemical Letters, ;2024, 35(9): 109933. doi: 10.1016/j.cclet.2024.109933 shu

A water-stable high-voltage P3-type cathode for sodium-ion batteries

Institute for Sustainable Energy & College of Sciences, Shanghai University, Shanghai 200444, China

yufengzhao@shu.edu.cn

Received Date: 17 March 2024
Accepted Date: 28 April 2024
Available Online: 29 April 2024

Figures(5)

The Na-deficient P3-type layered oxide cathode material usually experience complex in-plane Na⁺/vacancy ordering rearrangement and undesirable P3-O3 phase transitions in the high-voltage region, leading to inferior cycling performance. Additionally, they exhibit unsatisfactory stability when exposed to water for extended periods. To address these challenges, we propose a Cu/Ti co-doped P3-type cathode material (Na_0.67Ni_0.3Cu_0.03Mn_0.6Ti_0.07O₂), which effectively mitigates Na⁺/vacancy ordering and suppresses P3-O3 phase transitions at high voltages. As a result, the as-prepared sample exhibited outstanding cyclic performance, with 81.9% retention after 500 cycles within 2.5–4.15 V, and 75.7% retention after 300 cycles within 2.5–4.25 V. Meanwhile, it demonstrates enhanced Na⁺ transport kinetics during desodiation/sodiation and reduced growth of charge transfer impedance (R_ct) after various cycles. Furthermore, the sample showed superb stability against water, exhibiting no discernible degradation in structure, morphology, or electrochemical performance. This co-doping strategy provides new insights for innovative and prospective cathode materials.
- Sodium ion batteries,
- P3-type materials,
- Phase transition,
- Na⁺/vacancy ordering,
- Water-stable cathode
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