Citation: Yufei Liu, Liang Xiong, Bingyang Gao, Qingyun Shi, Ying Wang, Zhiya Han, Zhenhua Zhang, Zhaowei Ma, Limin Wang, Yong Cheng. MOF-derived Cu based materials as highly active catalysts for improving hydrogen storage performance of Mg-Ni-La-Y alloys[J]. Chinese Chemical Letters, ;2024, 35(12): 109932. doi: 10.1016/j.cclet.2024.109932 shu

MOF-derived Cu based materials as highly active catalysts for improving hydrogen storage performance of Mg-Ni-La-Y alloys

Yufei Liu ^{a, b} ,
Liang Xiong ^{c, *,} ,
Bingyang Gao ^c ,
Qingyun Shi ^{a, b} ,
Ying Wang ^a ,
Zhiya Han ^c ,
Zhenhua Zhang ^c ,
Zhaowei Ma ^{d, *,} ,
Limin Wang ^{a, b} ,
Yong Cheng ^{a, *,}

a.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
School of Applied Chemistry and Engineering, University of Science and Technology of China (USTC), Hefei 230026, China
c.
Purification Equipment Research Institute of CSIC, Handan 056002, China
d.
Shengyuan (Xiamen) Hydrogen Energy Research Institute Co., Ltd., Xiamen 361000, China

xiongliang_1206@163.com

mazwfly@163.com

cyong@ciac.ac.cn

Received Date: 12 April 2024
Accepted Date: 28 April 2024
Available Online: 29 April 2024

Figures(6)

Higher initial (de)hydrogenation temperature and sluggish kinetics are the main bottlenecks to develop Mg-based hydrogen storage alloys with high hydrogen capacity. One of the effective methods of solving these problems is introducing additives to enhance (de)hydrogenation kinetics and decrease particle sizes to lower (de)hydrogenation temperatures. In this work, Mg85-Ni10-La4.5-Y0.5 alloy doped with Cu@C nanoparticles is prepared, which could enhance (de)hydrogenation kinetics via introducing Cu nanoparticles as a catalyst and reduce the alloy particle sizes via acting as a grinding agent to lower (de)hydrogenation temperature. The results indicate the dehydrogenation temperature of the modified Mg85-Ni10-La4.5-Y0.5 composite could be decreased to 308.5 ℃, absorb 4.73 wt% H₂ at 220 ℃ within 1 min and release 5.01 wt% H₂ within 4 min at 300 ℃. Moreover, the capacity retention could be maintained around 98.8% after 10 cycles at 300 ℃, superior than those of Mg85-Ni10-La4.5-Y0.5 and milled-Mg85-Ni10-La4.5-Y0.5. DFT results and characterizations suggest that in-situ formed Mg₂Cu could accelerate the dissociation of Mg-H bonds and the presence of amorphous carbon in Mg-Ni-La-Y-Cu system will further synergistically improve the (de)hydrogenation kinetics of Mg85-Ni10-La4.5-Y0.5. Reduced particle sizes under the aid of carbon frameworks also help introduce boundaries of the particles and shorten hydrogen diffusion pathways.
- Mg-Ni-La-Y alloy,
- Cu@C,
- Catalyst,
- Kinetics,
- Hydrogen storage
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